摘要:
A current interrupt mechanism for electrochemical cells is disclosed. A thermally activated current interrupt mechanism is integrated into an end cap assembly for an electrochemical cell. The thermally responsive mechanism preferably includes a free floating bimetallic disk which deforms when exposed to elevated temperature causing a break in an electrical pathway within the end cap assembly. This prevents current from flowing through the cell and effectively shuts down an operating cell. Alternatively, the thermally responsive mechanism may include a meltable mass of material which melts when exposed to elevated temperature to break an electrical pathway within the end cap assembly. The end cap assembly may also include integrated therein a pressure responsive current interrupt mechanism. If the internal gas pressure within an operating cell exceeds a predetermined value, the pressure responsive mechanism activates to sever an electrical pathway within the end cap assembly to prevent current from passing through the cell. The pressure responsive mechanism may include a diaphragm which ruptures when there is extreme gas pressure buildup. Gas is allowed to escape from the cell interior to the external environment through a series of vent apertures within the end cap assembly.
摘要:
A current interrupt mechanism for electrochemical cells is disclosed. A thermally activated current interrupt mechanism is integrated into an end cap assembly for an electrochemical cell. The thermally responsive mechanism preferably includes a free floating bimetallic disk which deforms when exposed to elevated temperature causing a break in an electrical pathway within the end cap assembly. This prevents current from flowing through the cell and effectively shuts down an operating cell. Alternatively, the thermally responsive mechanism may include a meltable mass of material which melts when exposed to elevated temperature to break an electrical pathway within the end cap assembly. The end cap assembly may also include integrated therein a pressure responsive current interrupt mechanism. If the internal gas pressure within an operating cell exceeds a predetermined value, the pressure responsive mechanism activates to sever an electrical pathway within the end cap assembly to prevent current from passing through the cell. The pressure responsive mechanism may include a diaphragm which ruptures when there is extreme gas pressure buildup. Gas is allowed to escape from the cell interior to the external environment through a series of vent apertures within the end cap assembly.
摘要:
A current interrupt mechanism for electrochemical cells is disclosed. A thermally activated current interrupt mechanism is integrated into an end cap assembly for an electrochemical cell. The thermally responsive mechanism preferably includes a free floating bimetallic disk or shape memory alloy member which deforms when exposed to elevated temperature causing a break in an electrical pathway within the end cap assembly. This prevents current from flowing through the cell and effectively shuts down an operating cell. The end cap assembly may include a pressure responsive mechanism which ruptures when there is extreme gas pressure buildup. Gas is allowed to escape from the cell interior to the external environment through a series of vent apertures within the end cap assembly.
摘要:
A current interrupt assembly for electrochemical cells is disclosed. The current interrupter assembly may be a self-contained, sealed unit which may be separately inserted into the cell during cell construction. Several current interrupt assemblies may be inserted in the cell. The current interrupter assembly has particular utility for thin rechargeable cells and when inserted in the cell forms a portion of the electrical pathway between a cell electrode and corresponding terminal. The current interrupt mechanism comprises a thin thermally responsive member preferably comprising a disk of a shape memory metal alloy having a curved surface. When cell temperature exceeds a predetermined value the disk deflects to cause a break in the electrical pathway within the assembly. The assembly may include therein a flexible electrically conductive member which forms a part of the electrical pathway within the assembly and which is physically responsive to deflection of the thermally responsive member. The assembly may also include a pressure actuated diaphragm which may form a portion of the assembly housing. When the cell internal pressure exceeds a predetermined level the diaphragm deflects causing a break in the electrical pathway within the assembly, thereby shutting down the cell.
摘要:
An electrochemical cell is disclosed, having a sealed prismatic housing with two opposing, internal side surfaces defining therebetween an internal cavity having width and length. One of the side surfaces defines a convex arc, and the other of the side surfaces has a center portion opposing the convex arc of the one side surface, and features extending toward the one side surface and straddling the convex arc. An electrode stack is contained within the internal cavity of the housing, having positive and negative electrode sheets arranged in face-to-face relation. The electrode stack is arranged between the side surfaces of the housing such that the stack is retained between the one side surface and the extending features of the other side surface, and deflected to follow the convex arc to maintain contact pressure between the positive and negative electrode sheets. The stack is thus stretched across an inwardly crowned surface of the housing. The invention can, by maintaining good intersheet contact pressure within the stack, provide good overall active material utilization (for high cell capacity) and can help to inhibit housing distension of cells with broad sides. Methods of construction are also disclosed.
摘要:
A cathode for an air recovery alkaline battery is disclosed. The cathode contains at least about 60% by weight MnO2 and at least about 2% by weight of a hydrophobic polymer; the MnO2 consists essentially of electrochemically synthesized MnO2.
摘要:
A sulfonic acid type organic surfactant is incorporated into the gelled anode mixture of an alkaline electrochemical cell, optionally with an organic phosphate ester surfactant. Zinc fines may also be incorporated into the anode. The electrolyte included in the anode mixture may have a reduced hydroxide concentration. When a cell is provided whose anode mixture includes the two surfactants and zinc fines alone or in combination with a lowered hydroxide concentration in the electrolyte, discharge leakage is reduced and gel gassing is suppressed relative to that of gels lacking both surfactants. Additionally, cell discharge performance is improved relative to that of cells lacking both the zinc fines and lowered hydroxide concentration.
摘要:
An air recovery battery is disclosed along with a method of assembling a battery including (a) inserting a cathode assembly in a can having a wall, the wall having at least one air access opening; (b) placing anode material in the can; (c) inserting a seal assembly into the can, the seal assembly having a current collector; and (d) sealing the can.
摘要:
The present invention relates to a copper-manganese mixed oxide cathode material, which is suitable for use in a cathode of an electrochemical cell, and which has the formula MnxCuyOz.nH2O, wherein the oxidation state of Cu is between about +1 and about +3, the oxidation state of Mn is between about +2 and about +7, x is equal to about 3-y, y is less than about 3, z is calculated or experimentally determined, using means known in the art, based on the values of x and y, as well as the oxidation states of Mn and Cu, and nH2O represents the surface and structural water present in the mixed oxide material. The present invention further relates to an electrochemical cell comprising the noted cathode material.
摘要翻译:本发明涉及一种铜锰混合氧化物阴极材料,其适用于电化学电池的阴极,其具有式Mn x Cu y O z·nH 2 O,其中Cu的氧化态在约+1和约+ 如图3所示,Mn的氧化态在约+2和约+7之间,x等于约3-y,y小于约3,z使用本领域已知的方法计算或实验测定,基于 x和y的值,以及Mn和Cu的氧化态,nH2O表示混合氧化物材料中存在的表面和结构水。 本发明还涉及包含所述阴极材料的电化学电池。