公开(公告)号：US5301693A

公开(公告)日：1994-04-12

申请号：US911274

申请日：1992-07-09

申请人： W. Geoffrey Chan ,  William B. Edwards, III ,  Harvey J. Grubbs ,  Yoram Houminer ,  Charles R. Howe ,  John D. Naworal ,  John B. Paine, III ,  Kenneth F. Podraza ,  Edward B. Sanders ,  Jeffrey I. Seeman ,  Everett W. Southwick

发明人： W. Geoffrey Chan ,  William B. Edwards, III ,  Harvey J. Grubbs ,  Yoram Houminer ,  Charles R. Howe ,  John D. Naworal ,  John B. Paine, III ,  Kenneth F. Podraza ,  Edward B. Sanders ,  Jeffrey I. Seeman ,  Everett W. Southwick

IPC分类号： A24B3/12 ,  A24B15/28 ,  A24B15/30 ,  C07C59/00 ,  C07C59/48 ,  C07C65/00 ,  C07C57/03

CPC分类号： C07C59/48 ,  A24B15/281 ,  A24B15/282 ,  A24B15/301

摘要： This invention provides smoking compositions which contain a novel .beta.-hydroxycarboxylate flavorant-release additive. Under cigarette smoking conditions, a combustible filler and/or paper wrapper additive such as calcium bis(2,2-diethyl-3-hydroxy-4-phenylmethylenedecanoate) pyrolyzes and releases .alpha.-hexylcinnamaldehyde as a volatile flavorant component of the cigarette smoke.

摘要翻译： 本发明提供含有新型（β-）羟基羧酸盐调味剂释放添加剂的吸烟组合物。 在吸烟条件下，可燃填料和/或纸包装添加剂如双（2,2-二乙基-3-羟基-4-苯基亚甲基癸二酸钙）热解并释放（α） - 己基肉桂醛作为香烟烟雾的挥发性香料组分 。

公开(公告)号：US5172704A

公开(公告)日：1992-12-22

申请号：US688436

申请日：1991-04-22

申请人： W. Geoffrey Chan ,  Harvey J. Grubbs ,  Yoram Houminer ,  Kenneth F. Podraza ,  Edward B. Sanders

发明人： W. Geoffrey Chan ,  Harvey J. Grubbs ,  Yoram Houminer ,  Kenneth F. Podraza ,  Edward B. Sanders

IPC分类号： A24B3/12 ,  A23L27/00 ,  A24B15/30 ,  C07C69/96 ,  C11B9/00

CPC分类号： C07C69/96 ,  A23L27/75 ,  A24B15/301

摘要： This invention provides smoking compositions which contain a novel vanillin flavorant-release additive.Under cigarette smoking conditions, a combustible filler and/or paper wrapper additive such as ethyl 3-(4'-butoxycarbonyloxy-3'-methoxyphenyl)-3-hydroxy-2-phenylpropanoate pyrolyzes into vanillin and ethyl phenylacetate flavorants as volatile components of the cigarette smoke.A present invention flavorant-release additive is represented by the formula: ##STR1## where R is methyl or ethyl; R.sup.1 is hydrogen or a C.sub.1 -C.sub.4 alkyl substituent; R.sup.2 is hydrogen or a C.sub.1 -C.sub.4 alkyl or C.sub.6 -C.sub.10 aromatic substituent; and R.sup.3 is a C.sub.1 -C.sub.4 alkyl or C.sub.6 -C.sub.10 aromatic substituent.

公开(公告)号：US5228461A

公开(公告)日：1993-07-20

申请号：US946519

申请日：1992-09-16

申请人： W. Geoffrey Chan ,  Harvey J. Grubbs ,  Yoram Houminer ,  Kenneth F. Podraza ,  Edward B. Sanders

发明人： W. Geoffrey Chan ,  Harvey J. Grubbs ,  Yoram Houminer ,  Kenneth F. Podraza ,  Edward B. Sanders

IPC分类号： A23L27/00 ,  A24B15/30 ,  C07C69/96

CPC分类号： A24B15/301 ,  A23L27/75 ,  C07C69/96

摘要： This invention provides smoking compositions which contain a novel vanillin flavorant-release additive.A cigarette smoking product comprising (1) a combustible filler selected from natural tobacco, reconstituted tobacco and tobacco substitutes, and (2) a paper wrapper which has incorporated therein a flavorant-release additive corresponding to the formula: ##STR1## where R is methyl or ethyl.

摘要翻译： 本发明提供含有新型香草醛香料释放添加剂的吸烟组合物。 一种吸烟产品，其包括（1）选自天然烟草，再生烟草和烟草替代品的可燃填料，和（2）包含对应于下式的其中R为甲基的调味剂释放添加剂的纸包装物 或乙基。

公开(公告)号：US5129954A

公开(公告)日：1992-07-14

申请号：US537775

申请日：1990-06-13

申请人： W. Geoffrey Chan ,  Yoram Houminer ,  John B. Paine, III ,  Kenneth F. Podraza

发明人： W. Geoffrey Chan ,  Yoram Houminer ,  John B. Paine, III ,  Kenneth F. Podraza

IPC分类号： A24B3/12 ,  A24B15/30 ,  C07C69/734 ,  C07F7/18

CPC分类号： C07F7/1852 ,  A24B15/301 ,  C07C69/734

摘要： This invention provides novel .beta.-hydroxyesters which have utility as a flavorant-release additive in smoking compositions.Under cigarette smoking conditions, a combustible filler and/or paper wrapper additive such as ethyl 3-hydroxy-3-(4'-hydroxy-3'-methoxyphenyl)-2-phenylpropanoate pyrolyzes into vanillin and ethyl phenylacetate flavorants as volatile components of the cigarette smoke.

公开(公告)号：US5120368A

公开(公告)日：1992-06-09

申请号：US565127

申请日：1990-08-10

申请人： Yoram Houminer ,  Kenneth F. Podraza ,  Everett W. Southwick

发明人： Yoram Houminer ,  Kenneth F. Podraza ,  Everett W. Southwick

IPC分类号： A24B3/12 ,  A24B3/14 ,  A24B15/30 ,  A24B15/34 ,  C07C69/017

CPC分类号： C07C69/017 ,  A24B15/301

摘要： This invention provides novel vanillyl 5-hydroxyesters, and smoking compositions which contain a vanillyl 5-hydroxyester as a flavorant-release additive.Under cigarette smoking conditions, a combustible filler and/or paper wrapper additive such as 4'-formyl-2'-methoxyphenyl 5-hydroxy-2-isopropylhexanoate pyrolyzes into vanillin and 2-isopropyl-5-hydroxyhexanoic acid delta lactone flavorants as volatile components of the cigarette smoke.

公开(公告)号：US4872918A

公开(公告)日：1989-10-10

申请号：US861945

申请日：1986-05-12

申请人： Kenneth F. Podraza ,  Yoram Houminer

发明人： Kenneth F. Podraza ,  Yoram Houminer

IPC分类号： A24B15/28 ,  A24B15/36 ,  A24B15/38 ,  A24B15/40 ,  C07D241/12

CPC分类号： C07D241/12 ,  A24B15/281 ,  A24B15/365 ,  A24B15/38 ,  A24B15/406

摘要： This invention provides novel heterocyclic ester compounds. This invention further provides smoking compositions which contain an invention heterocyclic ester as a flavorant-release additive, as illustrated by the following structure: ##STR1## Under normal cigarette smoking conditions, tetramethylpyrazine and an olefin are released as pyrolysis products, and they enhance the flavor and aroma of the mainstream and sidestream smoke.

摘要翻译： 本发明提供新的杂环酯化合物。 本发明还提供含有发明杂环酯作为调味剂释放添加剂的吸烟组合物，如以下结构所示：在正常吸烟条件下，四甲基吡嗪和烯烃作为热解产物释放，并且它们增强风味 和主流和侧流烟雾的香气。

公开(公告)号：US4540004A

公开(公告)日：1985-09-10

申请号：US519424

申请日：1983-08-01

申请人： Kenneth F. Podraza ,  Yoram Houminer

发明人： Kenneth F. Podraza ,  Yoram Houminer

IPC分类号： A24B15/40 ,  C07D319/12 ,  A24B3/12

CPC分类号： A24B15/403 ,  C07D319/12

摘要： This invention provides smoking compositions which contain a tetracarbonate ester compound as a flavorant additive.In one of its embodiments, this invention provides tobacco compositions which contain a tetracarbonate ester flavorant additive such as 2,5-bis(menthoxycarbonyloxymethylene)-3,6-bis(menthoxycarbonyloxy)-1,4-dioxane: ##STR1## Under cigarette smoking conditions the above illustrated tetracarbonate ester pyrolyzes into menthol and other products which enhance the flavor of the mainstream smoke and the aroma of sidestream smoke.

摘要翻译： 本发明提供含有四碳酸酯化合物作为调味剂添加剂的吸烟组合物。 在其一个实施方案中，本发明提供了含有四碳酸酯调味剂添加剂如2,5-双（薄荷氧基羰基氧基亚甲基）-3,6-双（薄荷氧基羰基氧基）-1,4-二恶烷的烟草组合物：在吸烟下 条件是上述四碳酸酯热解成薄荷醇和其他增加主流烟味和香气的副产烟气的产品。

公开(公告)号：US4509537A

公开(公告)日：1985-04-09

申请号：US482100

申请日：1983-04-04

申请人： Yoram Houminer ,  Kenneth F. Podraza

发明人： Yoram Houminer ,  Kenneth F. Podraza

IPC分类号： A23L27/20 ,  A24B15/30 ,  A24B3/14

CPC分类号： A24B15/301 ,  A23L27/204

摘要： This invention provides smoking compositions which contain a monocarbonate ester compound as a flavorant additive.In one of its embodiments, this invention provides tobacco compositions which contain a monocarbonate ester flavorant additive such as 1-phenoxycarbonyloxy-3-propanol. ##STR1## Under cigarette smoking conditions the above illustrated monocarbonate ester pyrolyzes into phenol and other products which flavor the mainstream and sidestream smoke.

摘要翻译： 本发明提供含有单碳酸酯化合物作为调味剂添加剂的吸烟组合物。 在其一个实施方案中，本发明提供含有单碳酸酯调味剂添加剂如1-苯氧基羰基氧基-3-丙醇的烟草组合物。 在吸烟条件下，上述单碳酸酯热解成苯酚和其他产生主流和侧流烟味的产品。

公开(公告)号：US5651917A

公开(公告)日：1997-07-29

申请号：US513554

申请日：1995-08-10

申请人： Charles T. Bridges ,  Charles R. Howe ,  John B. Paine, III ,  Kenneth F. Podraza

发明人： Charles T. Bridges ,  Charles R. Howe ,  John B. Paine, III ,  Kenneth F. Podraza

IPC分类号： B01D53/46 ,  B01D53/52 ,  B01D53/86 ,  B01J23/50 ,  C01B15/01 ,  B01D53/78

CPC分类号： B01D53/46 ,  B01D53/52 ,  B01D53/8612 ,  B01D53/8671 ,  B01J23/50 ,  B01D2257/20 ,  B01D2257/204 ,  B01D2257/304 ,  B01D2257/406

摘要： An acidic aqueous medium for contacting and purifying a gas-phase stream by oxidation of a contaminant contained therein. The medium comprises an aqueous medium which contains redox-effective quantities of (1) silver(I) oxidation catalyst, (2) hydrogen peroxide oxidant, (3) silver metal-reoxidation co-catalyst ingredient which forms a cyclic complex with the hydrogen peroxide oxidant, and (4) oxidation-resistant acid. The acidic aqueous medium provides an integrated functionality of components (1) through (4) for the efficient cascade oxidation of a contaminant containing gas stream, and the continuous regeneration of the reduced silver metal catalyst back to the silver(I) oxidation state.

摘要翻译： 一种酸性水介质，用于通过氧化其中所含的污染物来接触和纯化气相物流。 介质包含含有氧化还原有效量的（1）银（I）氧化催化剂的水性介质，（2）过氧化氢氧化剂，（3）与过氧化氢形成环状络合物的银金属 - 再氧化助催化剂成分 氧化剂和（4）抗氧化酸。 酸性水性介质提供组分（1）至（4）的集成功能，用于有效地级联氧化含污染物气流，并将还原的银金属催化剂连续再生回银（I）氧化态。

公开(公告)号：US4532944A

公开(公告)日：1985-08-06

申请号：US603035

申请日：1984-04-23

申请人： Kenneth F. Podraza

发明人： Kenneth F. Podraza

IPC分类号： A24B15/30 ,  A24B15/40 ,  C07D319/12 ,  A24B3/12

CPC分类号： C07D319/12 ,  A24B15/301 ,  A24B15/403

摘要： This invention provides smoking compositions which contain a dicarbonate ester compound as a flavorant additive.In one of its embodiments, this invention provides tobacco compositions which contain a dicarbonate ester flavorant additive such as 2,5-bis(2-methoxyphenoxycarbonyloxy)-1,4-dioxane: ##STR1## Under cigarette smoking conditions the above illustrated dicarbonate ester pyrolyzes into guaiacol and other products which enhance the flavor of the mainstream smoke and the aroma of sidestream smoke.

摘要翻译： 本发明提供含有二碳酸酯化合物作为调味剂添加剂的吸烟组合物。 在其一个实施方案中，本发明提供了含有二碳酸酯调味剂添加剂如2,5-双（2-甲氧基苯氧羰基氧基）-1,4-二恶烷的烟草组合物：在吸烟条件下，上述二碳酸酯热解 成为愈创木酚等产品，增强主流烟味和侧流烟雾的香气。