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公开(公告)号:US10189013B2
公开(公告)日:2019-01-29
申请号:US15186583
申请日:2016-06-20
Inventor: Changyuan Li , Qianqian Liu , Dechen Song , Weiguang Yang , Xiaodong Zhan , Jiaqi Jin , Yanfeng Zhang
IPC: B01J23/00 , B01J23/89 , C10G2/00 , B01J37/02 , B01J29/03 , B01J35/04 , B01J29/70 , B01J37/06 , B01J37/34 , B01J35/02
Abstract: A monolithic catalyst, including cobalt, a metal matrix, a molecular sieve membrane, and an additive. The metal matrix is silver, gold, copper, platinum, titanium, molybdenum, iron, tin, or an alloy thereof. The molecular sieve membrane is mesoporous silica SBA-16 which is disposed on the surface of the metal matrix and is a carrier of the active component and the additive. The thickness of the carrier is between 26 and 67 μm. The additive is lanthanum, zirconium, cerium, rhodium, platinum, rhenium, ruthenium, titanium, magnesium, calcium, strontium, or a mixture thereof. A method for preparing the monolithic catalyst is also provided.
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公开(公告)号:US10450519B2
公开(公告)日:2019-10-22
申请号:US15693467
申请日:2017-08-31
Inventor: Weiguang Yang , Youliang Shi
Abstract: A method for hydrofining of middle distillates of Fischer-Tropsch synthetic full-range distillates, the method including: 1) separating middle distillates of Fischer-Tropsch synthetic full-range distillates to yield light distillates, heavy distillates and intermediate distillates; 2) metering the light distillates, the heavy distillates and the intermediate distillates; providing a hydrogenation reactor filled with a hydrofining catalyst and including a first feed inlet, a second feed inlet and a third feed inlet from the top down; mixing hydrogen and the light distillates, the heavy distillates and the intermediate distillates, respectively, and introducing resulting mixtures to the hydrogenation reactor via the first feed inlet, the second feed inlet and the third feed inlet, respectively; and 3) introducing products from 2) to a gas-liquid separator to yield hydrogen and liquid products, returning the hydrogen to the hydrogenation reactor, and introducing the liquid products to a fractionating column for further separation.
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公开(公告)号:US10220375B2
公开(公告)日:2019-03-05
申请号:US14923404
申请日:2015-10-26
Inventor: Weiguang Yang , Qianqian Liu , Dechen Song , Changyuan Li , Xiaodong Zhan , Jiaqi Jin , Yanfeng Zhang
IPC: B01J29/06 , B01J29/85 , B01J29/00 , B01J29/035 , B01J29/072 , B01J29/76 , B01J29/70 , B01J29/78 , B01J29/46 , B01J37/30 , B01J23/889 , B01J29/40 , B01J29/48 , C10G2/00 , C07C1/04 , B01J37/02 , B01J37/08
Abstract: A catalyst, including a molecular sieve carrier and an active component. The active component includes: iron, manganese, copper, and a basic promoter potassium. The molecular sieve carrier is a cerium salt and/or praseodymium salt modified-aluminosilicate molecular sieve carrier and/or silica-rich molecular sieve carrier. A method for preparing a catalyst for Fischer-Tropsch synthesis, includes: 1) fully dissolving a ferric salt, a manganese salt, a copper salt, and an alkali or a salt containing potassium element in water to yield an aqueous solution, stirring and adding sodium lauryl sulfate to the aqueous solution, and continuing stirring to yield a uniform solution; and impregnating a modified molecular sieve in the uniform solution to yield a mixed solution; and 2) drying and calcining the mixed solution to yield the catalyst.
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4.
公开(公告)号:US10370602B2
公开(公告)日:2019-08-06
申请号:US15694878
申请日:2017-09-04
Inventor: Tao Zhao , Bo Lai , Weiguang Yang , Dawei Wang , Xuewen Hao , Yanjie Zhou , Li Xu
Abstract: An apparatus for producing diesel fuel and jet fuel using Fischer-Tropsch synthetic oil, the apparatus including a hydrofining reactor, a hot separator, a first rectifying column, a hydrocracking reactor, a hydroisomerization reactor, a second rectifying column, a first mixing chamber and a second mixing chamber. The hydrofining reactor includes a raw material inlet and a hydrofining product outlet. The hot separator includes a separated oil outlet and a hydrofining product inlet which is connected to the hydrofining product outlet. The first rectifying column includes a tail oil fraction outlet, a diesel fraction outlet and a separated oil inlet which is connected to the separated oil outlet. The first mixing chamber includes a circulating hydrogen inlet, a first mixture outlet and a tail oil fraction inlet which is connected to the tail oil fraction outlet.
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