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公开(公告)号：US10363550B2
公开(公告)日：2019-07-30
申请号：US15331925
申请日：2016-10-24
发明人： Shasha Rao , Dechen Song , Qianqian Liu , Shenke Zheng
IPC分类号： B01J21/08 , B01J23/75 , B01J21/06 , B01J31/02 , B01J33/00 , B01J35/10 , C10G2/00 , B01J35/00 , B01J35/02 , B01J37/00 , B01J37/02 , B01J37/08
摘要： A catalyst including cobalt, a carrier including silica, and a selective promoter including zirconium. The cobalt and the selective promoter are disposed on the surface of the carrier, and the outer surfaces of the active component cobalt and the selective promoter zirconium are coated with a shell layer including a mesoporous material. A method for preparing the catalyst, including: 1) soaking the carrier including silica into an aqueous solution including a zirconium salt, aging, drying, and calcining a resulting mixture to yield a zirconium-loaded carrier including silica; 2) soaking the zirconium-loaded carrier including silica into an aqueous solution including a cobalt salt, aging, drying, calcining a resulting mixture to yield a primary cobalt-based catalyst; 3) preparing a precursor solution of a mesoporous material; and 4) soaking the primary cobalt-based catalyst into the precursor solution of the mesoporous material; and crystalizing, washing, drying, and calcining a resulting mixture.
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公开(公告)号：US10220375B2
公开(公告)日：2019-03-05
申请号：US14923404
申请日：2015-10-26
发明人： Weiguang Yang , Qianqian Liu , Dechen Song , Changyuan Li , Xiaodong Zhan , Jiaqi Jin , Yanfeng Zhang
IPC分类号： B01J29/06 , B01J29/85 , B01J29/00 , B01J29/035 , B01J29/072 , B01J29/76 , B01J29/70 , B01J29/78 , B01J29/46 , B01J37/30 , B01J23/889 , B01J29/40 , B01J29/48 , C10G2/00 , C07C1/04 , B01J37/02 , B01J37/08
摘要： A catalyst, including a molecular sieve carrier and an active component. The active component includes: iron, manganese, copper, and a basic promoter potassium. The molecular sieve carrier is a cerium salt and/or praseodymium salt modified-aluminosilicate molecular sieve carrier and/or silica-rich molecular sieve carrier. A method for preparing a catalyst for Fischer-Tropsch synthesis, includes: 1) fully dissolving a ferric salt, a manganese salt, a copper salt, and an alkali or a salt containing potassium element in water to yield an aqueous solution, stirring and adding sodium lauryl sulfate to the aqueous solution, and continuing stirring to yield a uniform solution; and impregnating a modified molecular sieve in the uniform solution to yield a mixed solution; and 2) drying and calcining the mixed solution to yield the catalyst.
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公开(公告)号：US09795950B2
公开(公告)日：2017-10-24
申请号：US15350132
申请日：2016-11-14
发明人： Wanwan Wang , Dechen Song , Li Xu
IPC分类号： B01J21/04 , B01J23/28 , B01J23/755 , B01J23/883 , B01J29/48 , B01J29/78 , B01J35/02 , B01J37/00 , B01J37/02 , B01J37/04 , B01J37/06 , B01J37/08 , C10G49/04 , C10G49/08
CPC分类号： B01J29/7884 , B01J29/076 , B01J29/48 , B01J35/002 , B01J35/026 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0018 , B01J37/009 , B01J37/02 , B01J37/0201 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/343 , B01J2229/16 , B01J2229/20 , B01J2229/36 , B01J2229/40 , B01J2229/42 , B01J2523/00 , C10G49/04 , C10G49/08 , C10G2300/1022 , C10G2300/1081 , B01J2523/68 , B01J2523/847
摘要： A catalyst for preparing aviation fuel from synthetic oil obtained by Fischer-Tropsch process, including: between 20 and 50 percent by weight of an amorphous aluminum silicate, between 5 and 20 percent by weight of alumina, between 20 and 60 percent by weight of a hydrothermally modified zeolite, between 0.5 and 1.0 percent by weight of a Sesbania powder, between 0.5 and 5 percent by weight of nickel oxide, and between 5 and 15 percent by weight of molybdenum oxide. The invention also provides a method for preparing the catalyst.
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公开(公告)号：US10266776B2
公开(公告)日：2019-04-23
申请号：US15299441
申请日：2016-10-20
发明人： Yilong Chen , Yanfeng Zhang , Jiangang Chen , Dechen Song , Juan Zhang , Taomei Sun
IPC分类号： C10G2/00 , B01J23/889 , B01J23/745 , B01J23/75 , B01J23/78 , B01J23/72 , B01J23/80 , B01J21/08 , B01J23/83 , B01J23/86 , B01J23/89 , B01J35/00 , B01J35/08 , B01J37/00 , B01J37/02 , B01J37/04 , B01J37/08
摘要： A catalyst including between 50.0 and 99.8 percent by weight of iron, between 0 and 5.0 percent by weight of a first additive, between 0 and 10 percent by weight of a second additive, and a carrier. The first additive is ruthenium, platinum, copper, cobalt, zinc, or a metal oxide thereof. The second additive is lanthanum oxide, cerium oxide, magnesium oxide, aluminum oxide, silicon dioxide, potassium oxide, manganese oxide, or zirconium oxide.
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公开(公告)号：US10189013B2
公开(公告)日：2019-01-29
申请号：US15186583
申请日：2016-06-20
发明人： Changyuan Li , Qianqian Liu , Dechen Song , Weiguang Yang , Xiaodong Zhan , Jiaqi Jin , Yanfeng Zhang
IPC分类号： B01J23/00 , B01J23/89 , C10G2/00 , B01J37/02 , B01J29/03 , B01J35/04 , B01J29/70 , B01J37/06 , B01J37/34 , B01J35/02
摘要： A monolithic catalyst, including cobalt, a metal matrix, a molecular sieve membrane, and an additive. The metal matrix is silver, gold, copper, platinum, titanium, molybdenum, iron, tin, or an alloy thereof. The molecular sieve membrane is mesoporous silica SBA-16 which is disposed on the surface of the metal matrix and is a carrier of the active component and the additive. The thickness of the carrier is between 26 and 67 μm. The additive is lanthanum, zirconium, cerium, rhodium, platinum, rhenium, ruthenium, titanium, magnesium, calcium, strontium, or a mixture thereof. A method for preparing the monolithic catalyst is also provided.
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公开(公告)号：US10005966B2
公开(公告)日：2018-06-26
申请号：US14935429
申请日：2015-11-08
发明人： Dashan Wang , Dechen Song , Qianqian Liu , Shenke Zheng , Xiaodong Zhan , Jiaqi Jin , Yanfeng Zhang
CPC分类号： C10G3/49 , B01D17/047 , B01J29/088 , B01J29/405 , B01J2229/186 , B01J2229/36 , B01J2229/42 , C10B53/02 , C10G11/18 , C10G33/04 , C10G2300/1011 , C10L1/02 , Y02E50/14 , Y02P30/20
摘要： A method for modifying bio-oil derived from biomass pyrolysis, the method including: 1) adding an inorganic salt and an organic demulsifier to a bio-oil; oscillating or stirring the resulting mixture, and resting the resulting mixture, to yield a lower layer being an aqueous solution and an upper layer being the bio-oil, and collecting the bio-oil; 2) employing a zeolite molecular sieve-loaded clay as a catalyst, and aging the catalyst using pure steam, to yield a modified catalyst; and 3) adding the modified catalyst obtained in 2) to a conventional catalytic cracking reactor, injecting the bio-oil obtained in 1) to the conventional catalytic cracking reactor using a piston pump, and allowing the bio-oil to react under a weight hourly space velocity (WHSV) of between 6 and 15 h−1, a temperature of between 380 and 700° C., and a pressure between 0.1 and 0.8 megapascal.
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7.发明授权公开(公告)号：US09758844B2
公开(公告)日：2017-09-12
申请号：US14479268
申请日：2014-09-05
发明人： Bo Lai , Li Xu , Yiming Han , Qianqian Liu , Dechen Song
CPC分类号： C22B11/06 , C22B11/026 , C22B11/048 , Y02P10/214
摘要： A method for recovering ruthenium from a spent ruthenium-based catalyst carried on aluminum oxide includes: drying, calcining, and cooling a spent catalyst; grinding the spent catalyst into black powder; placing the black powder in a fluidized bed reactor, purging the reactor with hydrogen and heating the black powder to obtain ruthenium metal, then heating the black powder in a mixed atmosphere of oxygen and ozone to obtain RuO4 gas; absorbing the RuO4 gas with a sufficient amount of hydrochloric acid to obtain a H3RuCl6 solution; adding an excess oxidant to the H3RuCl6 solution to oxidize the H3RuCl6 into H2RuCl6; adding excess NH4Cl to the H2RuCl6 and then filtering, and washing the filter cake to obtain solid (NH4)2RuCl6; and reducing the solid (NH4)2RuCl6 by hydrogen to obtain ruthenium metal.
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8.发明授权Method for preparation of high purity, crystalline cobalt nitrate from spent cobalt/silica catalyst 有权从废钴/二氧化硅催化剂制备高纯度结晶硝酸钴的方法公开(公告)号：US08986644B2
公开(公告)日：2015-03-24
申请号：US14477909
申请日：2014-09-05
发明人： Yiming Han , Qianqian Liu , Bo Lai , Li Xu , Dechen Song
CPC分类号： C22B23/0438 , C01G51/00 , C01G51/04 , C01P2006/80 , C07C51/412 , C22B1/005 , C22B3/0025 , C22B7/009 , Y02P10/214 , Y02P10/234 , C07C55/07
摘要： A method for preparing crystalline cobalt nitrate. The method includes: 1) calcining a spent Co/SiO2 catalyst, cooling the calcined material to room temperature, and grinding it to yield a powder; 2) heating the powder in a fluidized bed reactor; 3) adding the heated powder into excess dilute nitric acid solution and filtering to obtain a cobalt nitrate solution; 4) adjusting the pH value of the cobalt nitrate solution to 1.5, adding a preheated oxalic acid solution, adjusting a pH value of the resulting solution to 1.5, immediately filtering the resulting solution to yield a precipitate of cobalt oxalate, washing the precipitate of cobalt oxalate to yield a neutral filtrate; 5) drying the precipitate and calcining to yield cobalt oxide; 6) dissolving the cobalt oxide in nitric acid to yield a second cobalt nitrate solution; and 7) evaporating the second cobalt nitrate solution to obtain crystalline cobalt nitrate.
摘要翻译： 制备结晶硝酸钴的方法。 该方法包括：1）煅烧废弃的Co / SiO 2催化剂，将煅烧后的材料冷却至室温，并研磨，得到粉末; 2）在流化床反应器中加热粉末; 3）将加热的粉末加入过量的稀硝酸溶液中并过滤得到硝酸钴溶液; 4）将硝酸钴溶液的pH调节至1.5，加入预热的草酸溶液，将所得溶液的pH值调节至1.5，立即过滤所得溶液，得到草酸钴沉淀物，洗涤钴沉淀物 草酸盐，得到中性滤液; 5）干燥沉淀并煅烧产生氧化钴; 6）将氧化钴溶解在硝酸中以产生第二硝酸钴溶液; 和7）蒸发第二硝酸钴溶液以获得结晶硝酸钴。
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