Method for preparing liquid hydrocarbons from syngas
    5.
    发明授权
    Method for preparing liquid hydrocarbons from syngas 有权
    从合成气制备液态烃的方法

    公开(公告)号:US09255225B2

    公开(公告)日:2016-02-09

    申请号:US14569774

    申请日:2014-12-14

    Abstract: A method for preparing a liquid hydrocarbon from syngas. The method includes: 1) mixing crude syngas from a biomass gasifier and a hydrogen-rich gas to yield a mixed gas; 2) dehydrating and decarbonizing the mixed gas for removal of moisture, carbon dioxide, and impurities, to yield a fine syngas; 3) introducing the fine syngas to a Fischer-Tropsch synthesis device in the presence of a catalyst, controlling a reaction temperature of the Fischer-Tropsch synthesis at between 150 and 300° C. and a reaction pressure of between 2 and 4 MPa (A), to yield a liquid hydrocarbon and water which is discharged out of the Fischer-Tropsch synthesis device; and 4) returning 70-95 vol. % of exhaust gases from the Fischer-Tropsch synthesis device to step 3) to mix with the fine syngas, and introducing the resulting mixed gas to the Fischer-Tropsch synthesis device.

    Abstract translation: 从合成气制备液态烃的方法。 该方法包括:1)从生物质气化炉和富氢气体混合粗合成气,得到混合气体; 2)将混合气体脱水脱碳以除去水分,二氧化碳和杂质,产生细小的合成气; 3)在催化剂存在下将细合成气引入费 - 托合成装置中,在150-300℃之间控制费 - 托合成的反应温度和2-4MPa的反应压力(A ),以产生从费 - 托合成装置排出的液体烃和水; 和4)返回70-95卷。 从费 - 托合成装置到步骤3)的废气的%)与细合成气混合,并将所得混合气体引入费 - 托合成装置。

    Method for improving Fischer-Tropsch synthesis and recycling exhaust gases therefrom
    7.
    发明授权
    Method for improving Fischer-Tropsch synthesis and recycling exhaust gases therefrom 有权
    费 - 托合成和废气再循环的方法

    公开(公告)号:US09255226B2

    公开(公告)日:2016-02-09

    申请号:US14571240

    申请日:2014-12-15

    Abstract: A method for improving Fischer-Tropsch synthesis and recycling exhaust gases therefrom. The method includes: 1) transforming raw gas for Fischer-Tropsch synthesis using a water-gas shift reaction, transporting the transformed raw gas to a Fischer-Tropsch synthesis device for Fischer-Tropsch synthesis in the presence of a Fe-based or Co-based catalyst; 2) introducing exhaust gases from the Fischer-Tropsch synthesis device to a first pressure-swing adsorber for hydrogen recovery; 3) introducing the exhaust gases from 2) to a second pressure-swing adsorber for methane recovery; 4) returning part of the hydrogen obtained from 2) to 1) to mix with the raw gas, and transforming a resulting mixed gas to adjust a hydrogen/carbon ratio of the raw gas; and 5) introducing the methane in 3) to a methane reforming device to reform the methane whereby yielding syngas having relatively high hydrogen/carbon ratio, and transporting the syngas to 1) to mix with the raw gas.

    Abstract translation: 费 - 托合成和废气再循环的方法。 该方法包括:1)使用水煤气变换反应转化费 - 托合成的原料气体,在Fe基或Co-Fe合金存在下,将转化后的原料气转移至费 - 托合成装置进行费 - 托合成, 基催化剂; 2)将来自费 - 托合成装置的废气引入第一变压吸附器进行氢回收; 3)将来自2)的废气引入用于甲烷回收的第二变压吸附器; 4)将从2)获得的部分氢气返回到1)与原料气体混合,转化所得混合气体以调节原料气体的氢/碳比; 和5)在甲烷重整装置中将甲烷引入甲烷重整装置以重整甲烷,由此产生具有相对较高氢/碳比的合成气,并将合成气输送至1)与原料气体混合。

Patent Agency Ranking