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    Preparation of copolymers of monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids
    2.
    发明授权
    Preparation of copolymers of monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids 失效
    单烯属不饱和一元羧酸和二羧酸的共聚物的制备

    公开(公告)号：US5175361A

    公开(公告)日：1992-12-29

    申请号：US625621

    申请日：1990-11-30

    申请人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    发明人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    IPC分类号： C08F220/04 ,  C08F222/02

    CPC分类号： C08F222/02 ,  C08F220/04

    摘要： A process for the preparation of copolymers which contain monoethylenically unsaturated monocarboxylic acids and dicarboxylic acids as copolymerized monomer units, which comprises copolymerizinga) 10 to 60% by weight, based on the sum of the monomers, of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, -or an alkali metal salt thereof or, an anhydride thereof,b) 90 to 40% by weight of a monoethylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms or an alkali metal salt thereof andc) 0 to 20% by weight of another monoethylenically unsaturated monomer, not having carboxyl groups and which is copolymerizable with a) and b);in an aqueous medium in the presence of from 0.5 to 5% by weight, based on monomers, of a water-soluble initiator.

    摘要翻译： 一种制备包含单烯属不饱和一元羧酸和二羧酸作为共聚单体单元的共聚物的方法，其包括将基于单体总量的10-60重量％的单烯属不饱和二羧酸与4- 6个碳原子，或其碱金属盐或其酸酐，b）90〜40重量％的3〜10个碳原子的单烯属不饱和一元羧酸或其碱金属盐，c）0〜20重量％ 重量的不具有羧基且可与a）和b）共聚的另一单烯属不饱和单体; 在水介质中，以0.5至5重量％的单体为基础，存在水溶性引发剂。

    Preparation of copolymers of monoethylenically unsaturated mono- and dicarboxylic acids and anhydrides
    3.
    发明授权
    Preparation of copolymers of monoethylenically unsaturated mono- and dicarboxylic acids and anhydrides 失效

    公开(公告)号：US4725655A

    公开(公告)日：1988-02-16

    申请号：US919583

    申请日：1986-10-16

    申请人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    发明人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    IPC分类号： C08F2/00 ,  C08F2/10 ,  C08F8/00 ,  C08F8/12 ,  C08F8/44 ,  C08F20/00 ,  C08F20/02 ,  C08F120/04 ,  C08F220/04 ,  C08F222/02 ,  C08F220/06 ,  C08F222/04

    CPC分类号： C08F220/04 ,  C08F222/02

    摘要： Copolymers which contain, as copolymerized monomer units, monoethylenically unsaturated mono- and dicarboxylic acids are prepared by a process in which(a) from 10 to 60% by weight of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, its salt and/or, if appropriate, its anhydride,(b) from 90 to 40% by weight of a monothylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms and/or its salt and(c) from 0 to 20% by weight of another, carboxyl-free monoethylenically unsaturated monomer which is copolymerizable with (a) and (b),the percentages being based on the sum of the monomers, are polymerized in the presence of from 0.5 to 5% by weight of a water-soluble free-radical-forming initiator in an aqueous medium at from 60.degree. to 150.degree. C., and, if appropriate, their anhydride groups are hydrolyzed, the monomers (a) and (b) being employed in a form such that from 20 to 80% of their amount is neutralized during the polymerization reaction, wherein the copolymerization is carried out continuously in a reactor cascade comprising several reactors, and an aqueous solution of a pre-prepared copolymer of (a), (b) and, if appropriate, (c) is initially introduced into all the reactors and heated to the required reaction temperature, the total amount of unneutralized or partially neutralized (a), not less than 40% by weight of unneutralized or partially neutralized (b), where relevant, all or some of (c), and some or all of the amount of initiator required for polymerization, with or without the amount of neutralizing agent required for the neutralization according to the definition, are metered into the first reactor, the remaining amount of unneutralized or neutralized (b) and, where relevant, (c), and any remaining amount of initiator and neutralizing agent which may be required are introduced into the second reactor or are distributed over the second reactor and the downstream reactors, and the reactants are allowed to react together during a residence time of from 0.5 to 8 hours. The above copolymers can be used as incrustation inhibitors or for scaling inhibition.

    Washing agents containing, as additives, carboxyl-containing copolymers which are neutralized or amidated with amines
    4.
    发明授权
    Washing agents containing, as additives, carboxyl-containing copolymers which are neutralized or amidated with amines 失效
    作为添加剂含有用胺中和或酰胺化的含羧基共聚物的洗涤剂

    公开(公告)号：US4702858A

    公开(公告)日：1987-10-27

    申请号：US888957

    申请日：1986-07-24

    申请人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Erhard Klahr ,  Albert Hettche

    发明人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Erhard Klahr ,  Albert Hettche

    IPC分类号： C08F8/32 ,  C08F8/44 ,  C11D3/37

    CPC分类号： C11D3/3761 ,  C11D3/3769

    摘要： Washing agents contain, as additives for inhibiting redeposition and promoting the primary washing action, homopolymers of acrylic acid and of methacrylic acid, copolymers of acrylic acid and methacrylic acid and copolymers which contain, as essential components,(a) an ethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms and(b) acrylic acid, methacrylic acid and/or hydroxy-C.sub.2 -C.sub.6 -alkyl esters of ethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids as copolymerized units,where the homo- and copolymers in the form of the free acids have a weight average molecular weight of from 5000 to 500,000 in the neutralized or amidated form, the carboxyl groups of the homo- and copolymers in each case being partially or completely neutralized with amines of the formula ##STR1## where R is C.sub.8 -C.sub.18 -alkyl or R.sup.1 --O--CH.sub.2 --(CH.sub.2).sub.n --, n is from 1 to 3, R.sup.1 is C.sub.1 -C.sub.18 -alkyl, R.sup.2 and R.sup.3 are each H or C.sub.1 -C.sub.18 -alkyl and/or from 5 to 50% of the said carboxyl groups being in the form of amides derived from primary and secondary amines of the formula I.

    摘要翻译： 洗涤剂含有作为抑制再沉积和促进初次洗涤作用的添加剂，丙烯酸和甲基丙烯酸的均聚物，丙烯酸和甲基丙烯酸的共聚物以及含有作为必要成分的（a）烯属不饱和二羧酸 4至6个碳原子，和（b）丙烯酸，甲基丙烯酸和/或烯属不饱和C 3 -C 6 - 羧酸的羟基-C 2 -C 6烷基酯作为共聚单元，其中以自由基形式存在的均聚物和共聚物 酸的中和或酰胺化形式的重均分子量为5000至500,000，每种情况下的均聚物和共聚物的羧基用式“IMAGE”的胺部分或完全中和，其中R为C8-C18 - 烷基或R 1 -O-CH 2 - （CH 2）n - ，n为1至3，R 1为C 1 -C 18烷基，R 2和R 3各自为H或C 1 -C 18 - 烷基和/或5至50％ 的所述羧基为衍生自原料的酰胺形式 芳胺和仲胺。

    Additives for detergents and cleaning agents
    5.
    发明授权
    Additives for detergents and cleaning agents 失效
    洗涤剂和清洁剂的添加剂

    公开(公告)号：US4698174A

    公开(公告)日：1987-10-06

    申请号：US822610

    申请日：1986-01-27

    申请人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    发明人： Walter Denzinger ,  Heinrich Hartmann ,  Wolfgang Trieselt ,  Albert Hettche ,  Rolf Schneider ,  Hans-Juergen Raubenheimer

    IPC分类号： C11D3/33 ,  C11D3/37

    CPC分类号： C11D3/33 ,  C11D3/3761

    摘要： Pulverulent and/or granular additives for pulverulent detergents and cleaning agents, consisting of(a) from 80 to 20% by weight of one or more copolymers comprising from 40 to 90% by weight of (meth)acrylic acid and from 60 to 10% by weight of maleic acid and/or one or more copolymers comprising from 10 to 45% by weight of (meth)acrylic acid, from 10 to 45% by weight of maleic acid and from 10 to 60% by weight of one or more hydroxyalkyl (meth)acrylates where hydroxyalkyl is of 2 to 6 carbon atoms, if appropriate in the form of a partially or completely neutralized water-soluble salt,(b) from 20 to 80% by weight of nitrilotriacetic acid or its mono-, di- or trisodium or mono-, di- or tripotassium salt and(c) from 0 to 20% by weight of one or more additives conventionally used for detergent and cleaning agent formulations, the use of these pulverulent and/or granular mixtures as additives for pulverulent and/or granular detergents and cleaning agents, and processes for the preparation of the said additives.

    摘要翻译： 用于粉状洗涤剂和清洁剂的粉末和/或颗粒添加剂由（a）80至20重量％的一种或多种共聚物组成，所述共聚物包含40至90重量％的（甲基）丙烯酸和60至10重量％ 的马来酸和/或一种或多种共聚物，其包含10至45重量％的（甲基）丙烯酸，10至45重量％的马来酸和10至60重量％的一种或多种羟烷基 （甲基）丙烯酸酯，其中羟基烷基为2至6个碳原子，如果合适的话以部分或完全中和的水溶性盐的形式，（b）20至80重量％的次氮基三乙酸或其单 - 或三钠或单，二或三钾盐和（c）0至20重量％的常规用于洗涤剂和清洁剂配方的一种或多种添加剂，使用这些粉状和/或颗粒状混合物作为粉末状添加剂 和/或颗粒状洗涤剂和清洁剂，以及制备方法 n的所述添加剂。

    Detergents containing water-soluble copolymers containing as copolymerized units monomers having two or more ethylenically unsaturated double bonds
    8.
    发明授权
    Detergents containing water-soluble copolymers containing as copolymerized units monomers having two or more ethylenically unsaturated double bonds 失效
    含有含有共聚单元的含有两个或更多个烯属不饱和双键的单体的水溶性共聚物的洗涤剂

    公开(公告)号：US4897220A

    公开(公告)日：1990-01-30

    申请号：US191979

    申请日：1988-05-10

    申请人： Wolfgang Trieselt ,  Richard Baur ,  Ekhard Winkler ,  Paul Diessel ,  Hans-Peter Seelmann-Eggebert ,  Dieter Boeckh ,  Heinrich Hartmann

    发明人： Wolfgang Trieselt ,  Richard Baur ,  Ekhard Winkler ,  Paul Diessel ,  Hans-Peter Seelmann-Eggebert ,  Dieter Boeckh ,  Heinrich Hartmann

    IPC分类号： C08L33/02 ,  C08F20/10 ,  C08F220/04 ,  C08F220/06 ,  C08F222/16 ,  C11D3/37

    CPC分类号： C11D3/3761

    摘要： A surfactant-based detergent contains water-soluble copolymers which contain(a) from 99.5 to 15 mol % of one or more monoethylenically unsaturated C.sub.3 - to C.sub.6 -monocarboxylic acids,(b) from 0.5 to 20 mol % of one or more comonomers which contain two or more ethylenically unsaturated nonconjugated double bonds and have one or more --CO--OX groups where X is hydrogen, an alkali metal, one equivalent of an alkaline earth metal or ammonium,(c) from 0 to 84.5 mol % of one or more monoethylenically unsaturated C.sub.4 - to C.sub.6 -dicarboxylic acids,(d) from 0 to 20 mol % of one or more hydroxyalkyl esters of monoethylenically unsaturated C.sub.3 - to C.sub.6 -carboxylic acids and(e) from 0 to 30 mol % of other water-soluble monoethylenically unsaturated monomers copolymerizable with (a) to (d)as copolymerized units, with the proviso that the sum of the mol % ages (a) to (e) is always 100 and which have a Finkentscher K value of from 8 to 120.

    摘要翻译： 基于表面活性剂的洗涤剂含有水溶性共聚物，其含有（a）99.5〜15摩尔％的一种或多种单烯属不饱和C3〜C6-一元羧酸，（b）0.5〜20摩尔％的一种或多种共聚单体， 含有两个或多个烯键式不饱和非共轭双键，并且具有一个或多个-CO-OX基团，其中X为氢，碱金属，1当量碱土金属或铵，（c）0至84.5摩尔％ 更多的单烯属不饱和C 4 -C 6 - 二羧酸，（d）0至20摩尔％的一种或多种单烯属不饱和C 3 -C 6羧酸的羟烷基酯和（e）0至30摩尔％ 可与（a）至（d）共聚的可溶性单烯属不饱和单体作为共聚单元，条件是mol％年龄（a）至（e）的总和始终为100，Finkentscher K值为8至120 。