METHODS OF TREATING TEXTILE FIBRES
    1.
    发明申请
    METHODS OF TREATING TEXTILE FIBRES 有权
    处理纺织纤维的方法

    公开(公告)号:US20140315022A1

    公开(公告)日:2014-10-23

    申请号:US13814177

    申请日:2011-08-02

    IPC分类号: D06P1/52 D06M15/59

    摘要: According to the invention there is provided a method of treating textile fibres including the steps of: providing a polymeric precursor which includes a group of sub-formula (I) where R2 and R3 are independently selected from (CR7R8)n, or a group CR9R10, CR7R8CR9R10 or CR9R10CR7R8 where n is 0, 1 or 2, R7 and R8 are independently selected from hydrogen, halo or hydrocarbyl, and either one of R9 or R10 is hydrogen and the other is an electron withdrawing group, or R9 and R10 together form an electron withdrawing group, and R4 and R5 are independently selected from CH or CR11 where R11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X1 is a group CX2X3 where the dotted line bond to which it is attached is absent and a group CX2 where the dotted line bond to which it is attached is present, Y1 is a group CY2Y3 where the dotted line bond to which it is attached is absent and a group CY2 where the dotted line bond to which it is attached is present, and X2, X3, Y2 and Y3 are independently selected from hydrogen, fluorine or other substituents, R1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or —R3-R5≡Y1, and R13 is C(O) or S(0)2; coating the textile fibres with the polymeric precursor; and polymerising the polymeric precursor so as to produce a polymeric coating on the textile fibres.

    摘要翻译: 根据本发明,提供了一种处理纺织纤维的方法,包括以下步骤:提供聚合物前体,其包含其中R2和R3独立地选自(CR7R8)n,或CR9R10基团的一个子式(I) ,CR 7 R 8 CR 9 R 10或CR 9 R 10 CR 7 R 8,其中n为0,1或2,R 7和R 8独立地选自氢,卤素或烃基,R 9或R 10中的任一个为氢,另一个为吸电子​​基团,或者R 9和R 10一起形成 吸电子基团,R4和R5独立地选自CH或CR11,其中R11是吸电子基团,虚线表示存在或不存在键,X1是基团的虚线键 不存在,并且存在与其连接的虚线键的基团CX2,Y1是不存在与其连接的虚线键的基团CY2Y3,并且其中虚线键合的基团CY2 附属的是 并且X 2,X 3,Y 2和Y 3独立地选自氢,氟或其它取代基,R 1选自氢,卤素,硝基,烃基,任选取代或插入有官能团,或-R 3 -R 5 = Y 1,以及 R 13为C(O)或S(O)2; 用聚合物前体涂覆纺织纤维; 并聚合聚合物前体以便在纺织纤维上产生聚合物涂层。

    Methods of treating textile fibres

    公开(公告)号:US09797088B2

    公开(公告)日:2017-10-24

    申请号:US13814177

    申请日:2011-08-02

    摘要: According to the invention there is provided a method of treating textile fibers including the steps of: providing a polymeric precursor which includes a group of sub-formula (I) where R2 and R3 are independently selected from (CR7R8)n, or a group CR9R10, CR7R8CR9R10 or CR9R10CR7R8 where n is 0, 1 or 2, R7 and R8 are independently selected from hydrogen, halo or hydrocarbyl, and either one of R9 or R10 is hydrogen and the other is an electron withdrawing group, or R9 and R10 together form an electron withdrawing group, and R4 and R5 are independently selected from CH or CR11 where R11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X1 is a group CX2X3 where the dotted line bond to which it is attached is absent and a group CX2 where the dotted line bond to which it is attached is present, Y1 is a group CY2Y3 where the dotted line bond to which it is attached is absent and a group CY2 where the dotted line bond to which it is attached is present, and X2, X3, Y2 and Y3 are independently selected from hydrogen, fluorine or other substituents, R1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or —R3-R5≡Y1, and R13 is C(O) or S(O)2; coating the textile fibers with the polymeric precursor; and polymerizing the polymeric precursor so as to produce a polymeric coating on the textile fibers.

    METHODS OF COATING A LOW SURFACE ENERGY SUBSTRATE

    公开(公告)号:US20140370279A1

    公开(公告)日:2014-12-18

    申请号:US13814167

    申请日:2011-08-02

    摘要: According to the invention there is provided a method of coating a low surface energy substrate including the steps of: a) providing a polymeric precursor which includes a group of sub-formula (I) where R1 is i) CRa, where Ra is hydrogen or alkyl, ii) a group S(0)pR13, or SiR14 where R13 and R14 are independently selected from hydrogen or hydrocarbyl, p is 0, 1 or 2 and q is 1 or 2, iii) C(0)N, S(0)2N, C(0)ON, CH2ON, or CH═CHRCN where Rc is an electron withdrawing group, or iv) OC(0)CH, C(0)OCH or S(0)2CH; in which R12 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or formula (II) R2 and R3 are independently selected from (CR7R8)n, or a group CR9R10, CR7R8CR9R10 or CR9R10CR7R8 where n is 0, 1 or 2, R7 and R8 are independently selected from hydrogen or alkyl, and either one of R9 or R10 is hydrogen and the other is an electron withdrawing group, or R9 and R10 together form an electron withdrawing group; R4 and R5 are independently selected from CH or CR11 where CR11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X1 is a group CX2X3 where the dotted line bond to which it is attached is absent and a group CX2 where the dotted line to which it is attached is present, Y1 is a group CY2Y3 where the dotted line to which it is attached is absent and a group CY2 where the dotted line to which it is attached is present, and X2, X3, Y2 and Y3 are independently selected from hydrogen, fluorine or other substituents; and b) either (i) coating the low surface energy substrate with the polymeric precursor and polymerising the polymeric precursor to form a polymeric coating, or (ii) polymerising the polymeric precursor and contacting the polymerised polymeric precursor with a low surface energy substrate to form a polymeric coating on the low surface energy substrate.