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    METHODS OF TREATING TEXTILE FIBRES
    1.
    发明申请
    METHODS OF TREATING TEXTILE FIBRES 有权
    处理纺织纤维的方法

    公开(公告)号：US20140315022A1

    公开(公告)日：2014-10-23

    申请号：US13814177

    申请日：2011-08-02

    申请人： Warrick James David Allen ,  Andrea Duffy ,  Nicholas Horrocks

    发明人： Warrick James David Allen ,  James Leonard Rolfe ,  Andrea Duffy ,  Nicholas Horrocks

    IPC分类号： D06P1/52 ,  D06M15/59

    CPC分类号： D06P1/52 ,  C09D139/02 ,  D06M15/3562 ,  D06M15/3566 ,  D06M15/59 ,  D06P1/39 ,  D06P1/41 ,  D06P1/5242 ,  D06P1/525 ,  D06P3/241 ,  D06P3/242 ,  D06P3/521 ,  D06P3/522 ,  Y10T428/2969

    摘要： According to the invention there is provided a method of treating textile fibres including the steps of: providing a polymeric precursor which includes a group of sub-formula (I) where R2 and R3 are independently selected from (CR7R8)n, or a group CR9R10, CR7R8CR9R10 or CR9R10CR7R8 where n is 0, 1 or 2, R7 and R8 are independently selected from hydrogen, halo or hydrocarbyl, and either one of R9 or R10 is hydrogen and the other is an electron withdrawing group, or R9 and R10 together form an electron withdrawing group, and R4 and R5 are independently selected from CH or CR11 where R11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X1 is a group CX2X3 where the dotted line bond to which it is attached is absent and a group CX2 where the dotted line bond to which it is attached is present, Y1 is a group CY2Y3 where the dotted line bond to which it is attached is absent and a group CY2 where the dotted line bond to which it is attached is present, and X2, X3, Y2 and Y3 are independently selected from hydrogen, fluorine or other substituents, R1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or —R3-R5≡Y1, and R13 is C(O) or S(0)2; coating the textile fibres with the polymeric precursor; and polymerising the polymeric precursor so as to produce a polymeric coating on the textile fibres.

    摘要翻译： 根据本发明，提供了一种处理纺织纤维的方法，包括以下步骤：提供聚合物前体，其包含其中R2和R3独立地选自（CR7R8）n，或CR9R10基团的一个子式（I） ，CR 7 R 8 CR 9 R 10或CR 9 R 10 CR 7 R 8，其中n为0,1或2，R 7和R 8独立地选自氢，卤素或烃基，R 9或R 10中的任一个为氢，另一个为吸电子​​基团，或者R 9和R 10一起形成 吸电子基团，R4和R5独立地选自CH或CR11，其中R11是吸电子基团，虚线表示存在或不存在键，X1是基团的虚线键 不存在，并且存在与其连接的虚线键的基团CX2，Y1是不存在与其连接的虚线键的基团CY2Y3，并且其中虚线键合的基团CY2 附属的是 并且X 2，X 3，Y 2和Y 3独立地选自氢，氟或其它取代基，R 1选自氢，卤素，硝基，烃基，任选取代或插入有官能团，或-R 3 -R 5 = Y 1，以及 R 13为C（O）或S（O）2; 用聚合物前体涂覆纺织纤维; 并聚合聚合物前体以便在纺织纤维上产生聚合物涂层。

    Methods and Systems for Providing Dyed, Stretchable Flame Resistant Fabrics and Garments
    4.
    发明申请
    Methods and Systems for Providing Dyed, Stretchable Flame Resistant Fabrics and Garments 审中-公开
    提供染色，拉伸耐火织物和服装的方法和系统

    公开(公告)号：US20080152888A1

    公开(公告)日：2008-06-26

    申请号：US11852755

    申请日：2007-09-10

    申请人： D. Craig Tutterow ,  Rembert Joseph Truesdale

    发明人： D. Craig Tutterow ,  Rembert Joseph Truesdale

    IPC分类号： D06P3/85 ,  B32B27/34

    CPC分类号： D06P1/0008 ,  D02G3/32 ,  D02G3/328 ,  D02G3/443 ,  D03D15/08 ,  D03D15/12 ,  D06P1/6429 ,  D06P1/6498 ,  D06P1/65118 ,  D06P1/65125 ,  D06P1/6515 ,  D06P1/65156 ,  D06P1/65162 ,  D06P3/24 ,  D06P3/241 ,  D06P3/242 ,  D06P3/26 ,  D06P3/82 ,  D06P3/8209 ,  D06P3/8271 ,  D10B2331/021 ,  Y10T428/249921

    摘要： Flame resistant stretch fabrics made from aramid fibers and elastomeric fibers and methods and systems for dyeing such fabrics while significantly retaining the stretch properties of the fabrics. Such methods and systems include the use of certain dye carriers not conventionally used in the aramid dyeing process that enable the fabric to be dyed under normal aramid dyeing conditions without eliminating or significantly impacting the stretch properties of the fabric. Such suitable dye carriers for use in the process include, but are not limited to, benzyl alcohol, butyl benzoate, n-butyl phthalimide, isopropyl phthalimide, dimethyl phthalate, biphenyl, monochlorotoluene, and combinations thereof. Phthalimides, and more particularly blends of n-butyl phthalimide and isopropyl phthalimide, have proven particularly effective at dyeing the aramid fibers at high temperatures while retaining the elastomeric properties of the fabric. The dyed flame resistant stretch fabrics of this invention can be used to construct, among other things, the entirety or various portions of, a variety of protective garments for protecting the wearer against electrical arc flash and flames, including, but not limited to, coveralls, jumpsuits, shirts, jackets, vests, and trousers.

    摘要翻译： 由芳族聚酰胺纤维和弹性体纤维制成的阻燃弹力织物以及用于染色这种织物的方法和系统，同时显着地保持织物的拉伸性能。 这些方法和系统包括在芳族聚酰胺染色过程中不常用的某些染料载体的使用，使织物能够在正常芳族聚酰胺染色条件下染色，而不会消除或显着影响织物的拉伸性能。 用于该方法的这种合适的染料载体包括但不限于苄醇，苯甲酸丁酯，邻苯二甲酰苯胺，邻苯二甲酰亚胺异丙酯，邻苯二甲酸二甲酯，联苯，一氯甲苯及其组合。 邻苯二酰亚胺，更特别是邻苯二甲酰亚胺和邻苯二甲酰亚胺异丙酯的共混物已被证明在高温下染色芳族聚酰胺纤维特别有效，同时保持织物的弹性体性能。 本发明的经染色的耐火弹力织物可用于构成各种防护服的全部或各部分，以保护佩戴者避免电弧闪光和火焰，包括但不限于工作服 连身裤，衬衫，夹克，背心和裤子。

    Biscationic disazo dyes for acid-modified nylons
    10.
    发明授权
    Biscationic disazo dyes for acid-modified nylons 失效
    用于酸改性尼龙的无色染料双偶氮染料

    公开(公告)号：US3910876A

    公开(公告)日：1975-10-07

    申请号：US35690973

    申请日：1973-05-03

    申请人： DU PONT

    发明人： JAMES DANIEL SHAW

    IPC分类号： C09B44/04 ,  D06P1/66 ,  D06P3/24 ,  D06P3/82 ,  C09B31/02 ,  D06P3/26

    CPC分类号： D06P3/8209 ,  C09B44/04 ,  D06P1/66 ,  D06P3/241 ,  D06P3/242

    摘要： Y N R9R2R3 or NHCOCH2N R9R2R3, where R9 R1 or H m 0 or 1 N 0 OR 1 Z H when n 0 and OH when n 1 A anion AND WHERE ALKYL GROUPS CONTAIN 1-4 CARBON ATOMS, ARE PARTICULARLY WELL SUITED FOR DYEING OF BULK CONTINUOUS FILAMENT (BCF) nylon styling carpet, and have good exhaust and lightfastness on acid-modified nylon and excellent reserve on unmodified nylons, at the preferred dyeing pH range of 6-6.5. The dyes are prepared by coupling p-aminophenacylammonium or p-(paminophenylazo)phenacylammonium salts to N,N-disubstituted anilines containing a pendant tertiary amine or quaternary ammonium group attached to the nitrogen atom.
    Orange to violet biscationic azo dyes having the formula

    where R1 alkyl R2 alkyl or hydroxyalkyl R3 alkyl, hydroxyalkyl or benzyl OR R2 and R3 together alicyclic ring OR R1, R2, and R3 together pyridinium ring R4 H or Cl W 1,4-naphthylene or
    R5 and R6 H, alkyl, alkoxy or Cl R7 H, alkyl, alkoxy, Cl, NHCO alkyl or NHCOC6H5 R8 H, Cl, alkyl or alkoxy

    摘要翻译： 其中R1 =烷基R2 =烷基或羟基烷基R3 =烷基，羟基烷基或苄基ORR2和R3一起=脂环族环OR = R1，R2和R3一起=吡啶鎓环R4 = H或ClW = 1,4-亚萘基或R5和R6 = H，烷基，烷氧基或C1 R7 = H，烷基，烷氧基，C1，NHCO烷基或NHCOC6H5 R8 = H，Cl，烷基或烷氧基+烷基烷基X + = - NN ANGLE或-N ANGLE烷基CH2CH（CH2）nY + | ZY + = N + R9R2R3或NHCOCH2N + R9R2R3，其中 当n = 0时，R9 = R1或H m = 0或1 N = 0或1 Z = H，当n = 1时，OH是OH，阴离子和含1-4个碳原子的烷基，特别是 染色连续纤维（BCF）尼龙造型地毯，在酸改性尼龙上具有良好的排气和耐光性，在未改性尼龙上具有优良的储备，优选的染色pH范围为6-6.5。 通过将对氨基苯甲酰基铵或对 - （对氨基苯基偶氮）苯甲酰甲基铵盐偶联到含有与氮原子连接的叔胺或季铵基团的N，N-二取代的苯胺来制备染料。