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    Water-soluble complex dye, recording fluid and recording method
    2.
    发明申请
    Water-soluble complex dye, recording fluid and recording method 有权
    水溶性复合染料，记录液和记录方法

    公开(公告)号：US20050081747A1

    公开(公告)日：2005-04-21

    申请号：US11005021

    申请日：2004-12-07

    申请人： Wataru Shimizu ,  Mio Ishida ,  Hideo Sano ,  Yukichi Murata

    发明人： Wataru Shimizu ,  Mio Ishida ,  Hideo Sano ,  Yukichi Murata

    IPC分类号： C09B45/18 ,  C09B45/22 ,  C09B45/24 ,  C09B45/34 ,  C09B67/44 ,  C09D11/00 ,  C09B45/00

    CPC分类号： C09D11/32 ,  C09B45/18 ,  C09B45/22 ,  C09B45/24 ,  C09B45/34 ,  C09B67/0083 ,  C09D11/328 ,  C09D11/40

    摘要： A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented. A water-soluble complex dye comprising an azo compound represented by the following formula (1) or its tautomer, and transition metal ions; a water-based recording fluid, particularly an ink jet recording fluid, containing such a dye; and an ink jet recording method employing such a recording fluid. In the formula (1), A1 is a 5- to 7-membered hetero monocyclic group or a fused polycyclic group containing such a hetero monocyclic group and may have an optional substituent, but it represents a group which does not have a hydroxyl group at a position adjacent to the carbon bonded to the azo group; ring X1 represents a monocyclic hetero ring constituted by six atoms, bonded to the azo group and may have an optional substituent; and each of R1 and R2 which are independent of each other, is a hydrogen atom or a monovalent substituent.

    摘要翻译： 能够形成具有耐光性，耐臭氧性和高饱和度的图像的水溶性复合染料; 使用这种染料的水性记录液，特别是喷墨记录液; 使用这种记录液的油墨组; 和喷墨记录方法。 包含由下式（1）表示的偶氮化合物或其互变异构体和过渡金属离子的水溶性复合染料; 含有这种染料的水性记录液，特别是喷墨记录液; 以及采用这种记录液的喷墨记录方法。 在式（1）中，A 1是5至7元杂单环基团或含有这种杂单环基团的稠合多环基团，并且可以具有任选的取代基，但它代表基团 在与偶氮基结合的碳相邻的位置上不具有羟基; 环X 1表示由六个原子构成的单环杂环，键合到偶氮基并且可以具有任选的取代基; 且彼此独立的R 1和R 2各自为氢原子或一价取代基。

    Thermal transfer recording material and thermal transfer recording method using same
    5.
    发明授权
    Thermal transfer recording material and thermal transfer recording method using same 失效
    热转印记录材料和热转印记录方法使用相同

    公开(公告)号：US5935901A

    公开(公告)日：1999-08-10

    申请号：US614135

    申请日：1996-03-11

    申请人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida ,  Miyuki Kuromiya

    发明人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida ,  Miyuki Kuromiya

    IPC分类号： B41M5/035 ,  B41M5/382 ,  B41M5/385 ,  B41M5/38

    CPC分类号： B41M5/38207 ,  B41M5/3852 ,  Y10S428/913 ,  Y10S428/914

    摘要： A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation by heating, and then transferred to a recording medium disposed in an opposed relation to the transfer section, comprising:a dye represented by the general formula (I): ##STR1## where R.sup.1 and R.sup.2 are individually a substituted or unsubstituted alkyl or alkenyl group, or a cycloalkyl group, and when both R.sup.1 and R.sup.2 are unsubstituted alkyl groups, at least one of R.sup.1 and R.sup.2 is a branched alkyl group.

    摘要翻译： 一种用于记录装置的热转印记录材料，其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中，通过加热进行状态变换，然后转印到设置的记录介质上 与所述转移部分相对，包括：由通式（I）表示的染料：其中R 1和R 2各自为取代或未取代的烷基或烯基或环烷基，并且当R 1和R 2均未被取代时 烷基，R 1和R 2中的至少一个是支链烷基。

    Thermal transfer recording material and thermal transfer recording method using same
    6.
    发明授权
    Thermal transfer recording material and thermal transfer recording method using same 失效
    热转印记录材料和热转印记录方法使用相同

    公开(公告)号：US5618337A

    公开(公告)日：1997-04-08

    申请号：US614136

    申请日：1996-03-11

    申请人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida

    发明人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida

    IPC分类号： B41M5/385 ,  B41J2/05 ,  B41M5/388 ,  B41M5/39 ,  C09D11/02

    CPC分类号： B41M5/3854

    摘要： A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation such as vaporization or droplet formation by heating, and then transferred to a recording medium disposed opposed to the transfer section, comprising:a dye having a melting point of 115.degree. C. or lower and represented by the general formula (I): ##STR1## where A is a substituted or unsubstituted p-phenylene group, R.sup.1 and R.sup.2 are individually a hydrogen atom, a substituted or unsubstituted alkyl or alkenyl group, a cycloalkyl group or a substituted or unsubstituted phenyl group; and R.sup.1 may constitute a heterocyclic group composed of a five- or six-member ring in combination with said p-phenylene group A and a nitrogen atom adjacent to the p-phenytene group A, or another heterocyclic group composed of a five- or six-member ring in combination with R.sup.2 and the nitrogen atom adjacent to the p-phenylene group A.

    摘要翻译： 一种用于记录装置的热转印记录材料，其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中，经受诸如通过加热蒸发或液滴形成的状态转变，然后 转移到与转印部分相对设置的记录介质中，包括：熔点为115℃或更低并由通式（I）表示的染料：其中A是取代或未取代的 对亚苯基，R1和R2分别为氢原子，取代或未取代的烷基或链烯基，环烷基或取代或未取代的苯基; 并且R 1可以构成由与所述对亚苯基A和毗邻对苯基A相邻的氮原子组合的五元或六元环的杂环基或由五或六元组成的另一杂环基 - 与R2和与对亚苯基A相邻的氮原子的组合环。

    Thermal transfer recording material and thermal transfer recording method using same
    7.
    发明授权
    Thermal transfer recording material and thermal transfer recording method using same 失效
    热转印记录材料和热转印记录方法使用相同

    公开(公告)号：US5630870A

    公开(公告)日：1997-05-20

    申请号：US613344

    申请日：1996-03-11

    申请人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida

    发明人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida

    IPC分类号： B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  C09D11/02

    CPC分类号： B41M5/385

    摘要： A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation such as vaporization or droplet formation by heating, and then transferred to a recording medium disposed opposed to the transfer section, comprising:a dye having a molecular weight of 400 or less and represented by the general formula (I): ##STR1## where A is a substituted or unsubstituted p-phenylene group, R.sup.1 and R.sup.2 are individually a hydrogen atom, a substituted or unsubstituted alkyl or alkenyl group, a cycloalkyl group or a substituted or unsubstituted phenyl group; and R.sup.1 may constitute a heterocyclic group composed of a five- or six-member ring in combination with the p-phenylene group A and a nitrogen atom adjacent to the p-phenylene group A, or another heterocyclic group composed of a five- or six-member ring in combination with R.sup.2 and the nitrogen atom adjacent to the p-phenylene group A.

    摘要翻译： 一种用于记录装置的热转印记录材料，其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中，经受诸如通过加热蒸发或液滴形成的状态转变，然后 转移到与转印部相对设置的记录介质中，包括：分子量为400以下的由通式（I）表示的染料：其中A是取代或未取代的对亚苯基 基团，R 1和R 2分别为氢原子，取代或未取代的烷基或烯基，环烷基或取代或未取代的苯基; 并且R 1可以构成由与对亚苯基A和邻 - 对亚苯基A相邻的氮原子与五元或六元环组成的五元或六元环的杂环基， - 与R2和与对亚苯基A相邻的氮原子的组合环。

    Thermal transfer recording material
    8.
    发明授权
    Thermal transfer recording material 失效
    热转印记录材料

    公开(公告)号：US5944882A

    公开(公告)日：1999-08-31

    申请号：US922379

    申请日：1997-09-03

    申请人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida

    发明人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida

    IPC分类号： B41M5/382 ,  B41M5/385 ,  C09B57/00

    CPC分类号： B41M5/38221 ,  B41M5/3854

    摘要： A thermal transfer recording material for use in a recording apparatus in which said thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation by heating, and then transferred to a recording medium disposed opposed to said transfer section, comprising:a dye having a melting point of 160.degree. C. or lower, selected from the group consisting of a dye represented by the general formula (I): ##STR1## wherein A.sup.1, R.sup.1 and R.sup.2 are as defined, and a dye represented by the general formula (II): ##STR2## wherein A.sup.2, R.sup.3 and R.sup.4 are as defined.

    摘要翻译： 一种用于记录装置的热转印记录材料，其中所述热转印记录材料通过毛细管作用被引入具有多孔结构的转印部分中，经过加热进行状态变换，然后转印到设置的记录介质上 与所述转印部相对，包括：熔点为160℃以下的染料，选自由通式（I）表示的染料：其中A1，R1和R2如上所定义，和 由通式（II）表示的染料：其中A2，R3和R4如上所定义。

    Pyrazole disazo dye and ink containing the dye
    10.
    发明授权
    Pyrazole disazo dye and ink containing the dye 有权
    吡唑双偶氮染料和含有染料的油墨

    公开(公告)号：US08143382B2

    公开(公告)日：2012-03-27

    申请号：US12742506

    申请日：2008-11-11

    申请人： Yasushi Shiga ,  Mio Ishida

    发明人： Yasushi Shiga ,  Mio Ishida

    IPC分类号： C09B31/147 ,  C09D11/00

    CPC分类号： C09B31/147 ,  C09D11/037 ,  C09D11/328

    摘要： The invention provides a specific pyrazole disazo dye which is a yellow dye having excellent solubility in nonpolar solvents, in particular, hydrocarbon solvents, and having a high extinction coefficient. The dye preferably is preferably a pyrazole disazo dye represented by the following general formula (I): (wherein R1 represents a C2-C10 alkyl group; R2 represents a C3-C10 alkyl group; the six-membered ring A represents a phenyl group which may have a substituent; and the six-membered ring B represents a phenylene group which may have a substituent).

    摘要翻译： 本发明提供了一种特定的吡唑双偶氮染料，其是在非极性溶剂，特别是烃溶剂中具有优异的溶解性并且具有高消光系数的黄色染料。 染料优选为由以下通式（I）表示的吡唑双偶氮染料：（其中R1表示C2-C10烷基; R2表示C3-C10烷基;六元环A表示苯基， 可以具有取代基;六元环B表示可以具有取代基的亚苯基）。