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公开(公告)号：US20050081747A1
公开(公告)日：2005-04-21
申请号：US11005021
申请日：2004-12-07
Applicant: Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
Inventor： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
CPC classification number: C09D11/32 , C09B45/18 , C09B45/22 , C09B45/24 , C09B45/34 , C09B67/0083 , C09D11/328 , C09D11/40
Abstract: A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented. A water-soluble complex dye comprising an azo compound represented by the following formula (1) or its tautomer, and transition metal ions; a water-based recording fluid, particularly an ink jet recording fluid, containing such a dye; and an ink jet recording method employing such a recording fluid. In the formula (1), A1 is a 5- to 7-membered hetero monocyclic group or a fused polycyclic group containing such a hetero monocyclic group and may have an optional substituent, but it represents a group which does not have a hydroxyl group at a position adjacent to the carbon bonded to the azo group; ring X1 represents a monocyclic hetero ring constituted by six atoms, bonded to the azo group and may have an optional substituent; and each of R1 and R2 which are independent of each other, is a hydrogen atom or a monovalent substituent.
Abstract translation: 能够形成具有耐光性，耐臭氧性和高饱和度的图像的水溶性复合染料; 使用这种染料的水性记录液，特别是喷墨记录液; 使用这种记录液的油墨组; 和喷墨记录方法。 包含由下式（1）表示的偶氮化合物或其互变异构体和过渡金属离子的水溶性复合染料; 含有这种染料的水性记录液，特别是喷墨记录液; 以及采用这种记录液的喷墨记录方法。 在式（1）中，A 1是5至7元杂单环基团或含有这种杂单环基团的稠合多环基团，并且可以具有任选的取代基，但它代表基团 在与偶氮基结合的碳相邻的位置上不具有羟基; 环X 1表示由六个原子构成的单环杂环，键合到偶氮基并且可以具有任选的取代基; 且彼此独立的R 1和R 2各自为氢原子或一价取代基。
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2.发明授权Ink for thermal transfer, sheet for thermal transfer, and thermal transfer recording method using the same 有权用于热转印的油墨，用于热转印的纸和使用其的热转印记录方法公开(公告)号：US06866706B2
公开(公告)日：2005-03-15
申请号：US10287487
申请日：2002-11-05
Applicant: Mio Ishida , Yukichi Murata
Inventor： Mio Ishida , Yukichi Murata
IPC: B41M5/34 , B41M5/382 , B41M5/385 , B41M5/388 , B41M5/39 , C09B23/00 , C09B25/00 , C09B29/48 , C09B67/22 , C09D11/02 , C09D11/033 , C09D11/00 , B05D1/26 , B32B27/14
CPC classification number: B41M5/385 , B41M5/345 , B41M5/3852 , B41M5/3854 , B41M5/3858 , B41M5/388 , B41M5/39
Abstract: A thermal transfer ink is provided, which includes: at least one dye (a); at least one dye selected from the group including dye (b), dye (c) and a mixture thereof; and a medium; wherein (a) is a dye having a pyrazolone methine skeleton, (b) is a dye having a quinophthalone skeleton, and (c) is a dye having an aminopyrazole azo skeleton.
Abstract translation: 提供一种热转印油墨，其包括：至少一种染料（a）;选自染料（b），染料（c）及其混合物的至少一种染料; 和中等; 其中（a）是具有吡唑啉酮次甲骨架的染料，（b）是具有喹酞酮骨架的染料，（c）是具有氨基吡唑偶氮骨架的染料。
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3.发明授权Thermal transfer recording material and thermal transfer recording method using same 失效热转印记录材料和热转印记录方法使用相同
公开(公告)号：US5935901A
公开(公告)日：1999-08-10
申请号：US614135
申请日：1996-03-11
Applicant: Kenji Shinozaki , Hideki Hirano , Yukichi Murata , Mio Ishida , Miyuki Kuromiya
Inventor： Kenji Shinozaki , Hideki Hirano , Yukichi Murata , Mio Ishida , Miyuki Kuromiya
CPC classification number: B41M5/38207 , B41M5/3852 , Y10S428/913 , Y10S428/914
Abstract: A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation by heating, and then transferred to a recording medium disposed in an opposed relation to the transfer section, comprising:a dye represented by the general formula (I): ##STR1## where R.sup.1 and R.sup.2 are individually a substituted or unsubstituted alkyl or alkenyl group, or a cycloalkyl group, and when both R.sup.1 and R.sup.2 are unsubstituted alkyl groups, at least one of R.sup.1 and R.sup.2 is a branched alkyl group.
Abstract translation: 一种用于记录装置的热转印记录材料，其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中，通过加热进行状态变换，然后转印到设置的记录介质上 与所述转移部分相对，包括：由通式（I）表示的染料：其中R 1和R 2各自为取代或未取代的烷基或烯基或环烷基，并且当R 1和R 2均未被取代时 烷基，R 1和R 2中的至少一个是支链烷基。
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4.发明授权Thermal transfer recording material and thermal transfer recording method using same 失效热转印记录材料和热转印记录方法使用相同
公开(公告)号：US5618337A
公开(公告)日：1997-04-08
申请号：US614136
申请日：1996-03-11
Applicant: Kenji Shinozaki , Hideki Hirano , Yukichi Murata , Mio Ishida
Inventor： Kenji Shinozaki , Hideki Hirano , Yukichi Murata , Mio Ishida
CPC classification number: B41M5/3854
Abstract: A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation such as vaporization or droplet formation by heating, and then transferred to a recording medium disposed opposed to the transfer section, comprising:a dye having a melting point of 115.degree. C. or lower and represented by the general formula (I): ##STR1## where A is a substituted or unsubstituted p-phenylene group, R.sup.1 and R.sup.2 are individually a hydrogen atom, a substituted or unsubstituted alkyl or alkenyl group, a cycloalkyl group or a substituted or unsubstituted phenyl group; and R.sup.1 may constitute a heterocyclic group composed of a five- or six-member ring in combination with said p-phenylene group A and a nitrogen atom adjacent to the p-phenytene group A, or another heterocyclic group composed of a five- or six-member ring in combination with R.sup.2 and the nitrogen atom adjacent to the p-phenylene group A.
Abstract translation: 一种用于记录装置的热转印记录材料，其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中，经受诸如通过加热蒸发或液滴形成的状态转变，然后 转移到与转印部分相对设置的记录介质中，包括：熔点为115℃或更低并由通式（I）表示的染料：其中A是取代或未取代的 对亚苯基，R1和R2分别为氢原子，取代或未取代的烷基或链烯基，环烷基或取代或未取代的苯基; 并且R 1可以构成由与所述对亚苯基A和毗邻对苯基A相邻的氮原子组合的五元或六元环的杂环基或由五或六元组成的另一杂环基 - 与R2和与对亚苯基A相邻的氮原子的组合环。
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公开(公告)号：US5480478A
公开(公告)日：1996-01-02
申请号：US350077
申请日：1994-11-29
Applicant: Hideo Sano , Yukichi Murata , Toru Nishimura , Masahiro Yamada , Hiroshi Takimoto , Nobuyoshi Satoh
Inventor： Hideo Sano , Yukichi Murata , Toru Nishimura , Masahiro Yamada , Hiroshi Takimoto , Nobuyoshi Satoh
CPC classification number: C09D11/328
Abstract: A recording liquid comprising an aqueous medium and at least one dye selected from dyes, a free acid form of which is represented by formula (I), (II), (III) or (VI), the symbols in the formulae being defined in the specification: ##STR1##
Abstract translation: 一种包含水性介质和选自染料的至少一种染料的记录液体，其游离酸形式由式（I），（II），（III）或（VI）表示，式中的符号定义在 规格：
（I） （II） -
Patent Agency Ranking6.发明授权Image receiving sheet for thermal transfer recording and thermal transfer recording method 失效用于热转印记录和热转印记录方法的图像接收片
公开(公告)号：US5139995A
公开(公告)日：1992-08-18
申请号：US561329
申请日：1990-08-01
Applicant: Tsutomu Taki , Yukichi Murata , Katsuhiko Kuroda
Inventor： Tsutomu Taki , Yukichi Murata , Katsuhiko Kuroda
IPC: B41M5/52
CPC classification number: B41M5/5254 , Y10S428/913 , Y10S428/914 , Y10T428/265 , Y10T428/31786 , Y10T428/31855
Abstract: An image receiving sheet for thermal transfer recording, which comprises a substrate and an image receiving layer formed on the substrate, wherein the image receiving layer comprises, as the main component, a polyvinyl acetal resin of the following formula (I): ##STR1## wherein k, l, m and n represent percentages of the respective structural units in the formula within ranges of 50
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公开(公告)号：US07025815B2
公开(公告)日：2006-04-11
申请号：US11005021
申请日：2004-12-07
Applicant: Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
Inventor： Wataru Shimizu , Mio Ishida , Hideo Sano , Yukichi Murata
CPC classification number: C09D11/32 , C09B45/18 , C09B45/22 , C09B45/24 , C09B45/34 , C09B67/0083 , C09D11/328 , C09D11/40
Abstract: A water-soluble complex dye capable of forming an image having light resistance, ozone resistance and high saturation; a water-based recording fluid, particularly an ink jet recording fluid, employing such a dye; an ink set employing such a recording fluid; and an ink jet recording method, are presented.
Abstract translation: 能够形成具有耐光性，耐臭氧性和高饱和度的图像的水溶性复合染料; 使用这种染料的水性记录液，特别是喷墨记录液; 使用这种记录液的油墨组; 和喷墨记录方法。
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公开(公告)号：US4816435A
公开(公告)日：1989-03-28
申请号：US54606
申请日：1987-05-27
Applicant: Yukichi Murata , Shuichi Maeda
Inventor： Yukichi Murata , Shuichi Maeda
CPC classification number: B41M5/3858 , B41M5/3854 , B41M5/39 , Y10S428/913 , Y10S428/914 , Y10T428/24975 , Y10T428/264 , Y10T428/265 , Y10T428/31721 , Y10T428/31786
Abstract: A transfer sheet for thermal transfer recording system having a color material layer containing sublimable dyes on one surface of a base film, and said color material layer is a black color material layer containing sublimable dyes represented by following formulae (I), (II) and (III); ##STR1## in the above formulae, X and Y represent a hydrogen atom or a methyl group; --A-- represents --CO--, --COO--, or --SO.sub.2 --; and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, and R.sup.7 represent a hydrogen atom or a substituted or unsubstituted alkyl group.
Abstract translation: 一种用于热转印记录系统的转印片，其具有在基膜的一个表面上含有可升华的染料的着色材料层，并且所述着色层是含有下式（I），（II）和 （三）; （I）
（II）在上式中，X和Y表示氢原子或甲基; -A-表示-CO-，-COO-或-SO 2 - ; 并且R 1，R 2，R 3，R 4，R 5，R 6和R 7表示氢原子或取代或未取代的烷基。 -
9.发明授权Disazo dye for thermal transfer recording and thermal transfer sheet and ink for thermal transfer recording, employing it 有权用于热转印记录和热转印纸的双偶氮染料和用于热转印记录的油墨公开(公告)号：US06309807B1
公开(公告)日：2001-10-30
申请号：US09466792
申请日：1999-12-20
Applicant: Mio Ishida , Koji Maeda , Yukichi Murata
Inventor： Mio Ishida , Koji Maeda , Yukichi Murata
IPC: G03C173
CPC classification number: B41M5/388 , C09B31/062
Abstract: A disazo dye for thermal transfer recording of the following formula (I): wherein each of rings A and B which are independent of each other, is a benzene ring which may have a substituent, R1 is a C1-4 substituted or unsubstituted alkyl group, and R2 is a group selected from the group consisting of a hydrogen atom and a C1-4 substituted or unsubstituted alkyl group.
Abstract translation: 用于下式（I）的热转印记录的双偶氮染料：其中彼此独立的环A和B各自是可以具有取代基的苯环，R 1是C 1-4取代或未取代的烷基 R2为选自氢原子和C1-4取代或未取代的烷基的基团。
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公开(公告)号：US5713992A
公开(公告)日：1998-02-03
申请号：US732451
申请日：1997-01-13
Applicant: Nobuyoshi Satoh , Takashi Hirasa , Yukichi Murata
Inventor： Nobuyoshi Satoh , Takashi Hirasa , Yukichi Murata
CPC classification number: C09D11/32 , C09B29/30 , C09B43/16 , C09D11/17 , C09D11/328
Abstract: The present invention relates to a recording liquid characterized by comprising an aqueous medium and at least one monoazo dye selected from dyes, the free acid forms of which are represented by general formula {I}: ##STR1## (wherein R.sub.1, R.sub.2, and R.sub.3 each independently represents a substituted or unsubstituted alkyl group having 1 to 9 carbon atoms, an alkoxy group having 1 to 9 carbon atoms, a halogen atom, a hydrogen atom, a hydroxyl group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group, a substituted or unsubstituted amino group, a nitro group, a sulfonic ester group, a sulfonyl group, a COOH group, or a carboxylic ester group; m represents a number of 0, 1, or 2; and R.sub.4, R.sub.5, R.sub.6, and R.sub.7 each independently represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 1 to 18 carbon atoms, an aryl group, an aralkyl group, an alicyclic group, or a heterocyclic group, and each may have a substituent when not representing a hydrogen atom, provided that at least one of R.sub.4, R.sub.5, R.sub.6, and R.sub.7 represents a group having a COOH group as a substituent).
Abstract translation: PCT No.PCT / JP95 / 00336 Sec。 371日期1997年1月13日 102（e）日期1997年1月13日PCT提交1995年3月2日PCT公布。 公开号WO96 / 26985 PCT 日本1996年9月6日本发明涉及一种记录液，其特征在于包含水性介质和选自染料的至少一种单偶氮染料，其游离酸形式由通式{I}表示： （其中R 1，R 2和R 3各自独立地表示取代或未取代的碳原子数1〜9的烷基，碳原子数1〜9的烷氧基，卤素原子，氢原子，羟基，取代或未取代的 氨基甲酰基，取代或未取代的氨磺酰基，取代或未取代的氨基，硝基，磺酸酯基，磺酰基，COOH基或羧酸酯基; m表示0,1或 2; R 4，R 5，R 6和R 7各自独立地表示氢原子，碳原子数1〜18的烷基，碳原子数1〜18的烯基，芳基，芳烷基，脂环族基， 或杂环基，并且各自可以具有 当不表示氢原子时，取代基，只要R4，R5，R6和R7中的至少一个表示具有COOH基作为取代基的基团）。
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