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公开(公告)号：US4990701A
公开(公告)日：1991-02-05
申请号：US497067
申请日：1990-03-20
CPC分类号： C07C17/208
摘要： A process for halogen exchange fluorination by contacting a halocarbon having a replaceable halogen other than fluorine with KF.nHF wherein n is 0.5-3 to provide a fluorinated hydrocarbon having at least one more fluorine than the starting halocarbon and, optionally, regenerating the KF.nHF with additional HF, or in a continuous process, with excess HF in the feed.
摘要翻译： 通过将具有氟以外的可替换的卤素的卤代烃与KF.nHF接触进行卤素交换氟化的方法，其中n为0.5-3，以提供具有比起始卤化碳至少多一个氟的氟化烃，并且任选地再生KF。 具有额外HF的nHF，或连续过程中，饲料中含有过量的HF。
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公开(公告)号：US4990702A
公开(公告)日：1991-02-05
申请号：US480605
申请日：1990-02-15
CPC分类号： C07C17/208
摘要： A process for halogen exchange fluorination by contacting a halocarbon having a replaceable halogen other than fluorine with CsF or RbF.multidot.nHF wherein n is 0.5-3 to provide a fluorinated hydrocarbon having at least one more fluorine than the starting halocarbon and, optionally, regenerating the MF.multidot.nHF with additional HF, or in a continuous process, with excess HF in the feed.
摘要翻译： 通过将具有氟以外的可替换的卤素的卤代烃与CsF或RbFxnHF接触来进行卤素交换氟化的方法，其中n为0.5-3，以提供具有比起始卤化碳至少多一个氟的氟化烃，并且任选地使MFxnHF与 额外的HF或连续过程中，饲料中含有过量的HF。
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公开(公告)号：US5449845A
公开(公告)日：1995-09-12
申请号：US591221
申请日：1990-10-02
CPC分类号： C07C17/38 , C07C17/395
摘要： A process for reducing the content of unsaturated impurities in saturated fluorohalocarbons and fluorohalohydrocarbons by contacting the impure saturated fluorohalocarbon and/or fluorohalohydrocarbon in a substantially dry fluid state with a substantially dry amorphous solid metal oxide composition consisting essentially of cupric oxide, cobaltic oxide, silver oxide, manganese dioxide, or a mixture of any two or more thereof, at an effective temperature up to about 300.degree. C.
摘要翻译： 通过使基本上干燥的流体状态的不纯的饱和氟代卤代烃和/或氟代卤代烃与基本上干燥的无定形固体金属氧化物组合物接触，所述组合物基本上由氧化铜，氧化钴，氧化银组成的方式使饱和氟代卤代烃和氟代卤代烃中的不饱和杂质含量降低 ，二氧化锰或其任何两种或更多种的混合物，在高达约300℃的有效温度下
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公开(公告)号：US5449846A
公开(公告)日：1995-09-12
申请号：US591222
申请日：1990-10-02
申请人： Richard E. Fernandez
发明人： Richard E. Fernandez
CPC分类号： C07C17/38 , C07C17/395
摘要： A process for reducing the content of unsaturated impurities in saturated fluorohalocarbons and fluorohalohydrocarbons by contacting the impure saturated fluorohalocarbon and/or fluorohalohydrocarbon in a substantially dry fluid state with a substantially dry amorphous solid metal oxide composition consisting essentially of cupric oxide, cobaltic oxide, silver oxide, manganese dioxide, or a mixture of any two or more thereof, at an effective temperature up to about 300.degree. C.
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公开(公告)号：US5393438A
公开(公告)日：1995-02-28
申请号：US899282
申请日：1992-06-16
申请人： Richard E. Fernandez
发明人： Richard E. Fernandez
CPC分类号： A62D1/0057
摘要： A process for extinguishing, preventing and controlling fires using a composition containing at least one fluoro-substituted propane selected from the group of 2,2-dichloro-1,1,1-trifluoroethane (CHCl.sub.2 CF.sub.3), 2-chloro-1,1,1,2-tetrafluoroethane (CHClFCF.sub.3), and 1,1,1,2-tetrafluoroethane (CH.sub.2 FCF.sub.3), and mixtures thereof is disclosed. The fluoropropanes can be used in open or enclosed areas with little or no effect on the ozone in the stratosphere and with little effect on the global warming process.
摘要翻译： 一种使用含有至少一种选自2,2-二氯-1,1,1-三氟乙烷（CHCl 2 CF 3），2-氯-1,1,1-二氯-1,1,1-三氟乙烷的氟代取代丙烷的组合物灭火，防止和控制火灾的方法， 公开了1,2-四氟乙烷（CHClFCF 3）和1,1,1,2-四氟乙烷（CH 2 FCF 3）及其混合物。 氟丙烷可用于开放或封闭的区域，对同温层臭氧几乎没有影响，也不影响全球变暖过程。
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公开(公告)号：US07531689B2
公开(公告)日：2009-05-12
申请号：US11726488
申请日：2007-03-22
申请人： Victor Filippovich Cherstkov , Nina Ivanova Delyagina , Richard E. Fernandez , Viacheslav A. Petrov , Weiming Qiu , Paul R. Resnick
发明人： Victor Filippovich Cherstkov , Nina Ivanova Delyagina , Richard E. Fernandez , Viacheslav A. Petrov , Weiming Qiu , Paul R. Resnick
IPC分类号： C07C309/00
CPC分类号： C07C303/22 , C07C17/093 , C07C21/18 , C07C43/17 , C07C253/16 , C07C255/10 , C07C305/26 , C08F14/28 , C08F214/18 , C07C309/82
摘要： Hexafluoroisobutylene and its higher homologs are easily reacted with SO3 to give fluorosulfates of the formula CH2═C(R)CF2OSO2F, wherein R is a linear branched or cyclic fluoroalkyl group comprised of 1 to 10 carbon atoms and may contain ether oxygen. These compounds react under mild conditions with many nucleophiles to give CH2═C(R)CF2X, where X is derived from the nucleophile. This reaction provides a route to many substituted hexafluoroisobutylenes, which copolymerize easily with other fluoro- and hydrocarbon monomers such as vinylidene fluoride and ethylene.
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公开(公告)号：US5315043A
公开(公告)日：1994-05-24
申请号：US831782
申请日：1992-02-05
IPC分类号： C07B39/00 , C07C17/093 , C07C17/20 , C07C51/363 , C07C51/62 , C07C205/12 , C07C209/74 , C07D213/61
CPC分类号： C07D213/61 , C07B39/00 , C07C17/093 , C07C17/208 , C07C201/12 , C07C209/74 , C07C51/363 , C07C51/62
摘要： A process for halogen exchange fluorination or fluoro-denitration of aromatic compounds having at least one replaceable non-fluorine halogen or nitro substituent with an anhydrous substantially molten alkali metal acid fluoride composition wherein the alkali metal is potassium, rubidium or cesium.
摘要翻译： 卤素交换氟化或氟脱硝芳族化合物的方法，其具有至少一个可替代的非氟卤素或硝基取代基与无水基本上熔融的碱金属氟化物组合物，其中碱金属是钾，铷或铯。
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公开(公告)号：US5115868A
公开(公告)日：1992-05-26
申请号：US671432
申请日：1991-03-20
IPC分类号： A62D1/00
CPC分类号： A62D1/0057
摘要： A process for extinguishing, preventing and/or controlling fires using a composition containing CHF.sub.3 is disclosed. CHF.sub.3 can be used in volume percentages with air as high as 80% without adversely affecting mammalian habitation, with no effect on the ozone in the stratosphere and with little effect on the global warming process.
摘要翻译： 公开了使用含有CHF 3的组合物灭火，防止和/或控制火灾的方法。 CHF3可以空气高达80％的体积百分比使用，不会对哺乳动物的居住环境造成不利影响，对平流层的臭氧没有影响，对全球变暖过程几乎没有影响。
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公开(公告)号：US5084190A
公开(公告)日：1992-01-28
申请号：US436464
申请日：1989-11-14
申请人： Richard E. Fernandez
发明人： Richard E. Fernandez
CPC分类号： A62D1/0057
摘要： A process for extinguishing, preventing and controlling fires using a composition containing at least one fluoro-substituted propane selected from the group of CF.sub.3 --CHF--CF.sub.3, CF.sub.3 --CF.sub.2 --CHF.sub.2, CF.sub.3 --CFH--CF.sub.2 H, CF.sub.3 --CH.sub.2 --CF.sub.3, CF.sub.3 --CF.sub.2 --CH.sub.2 F, CHF.sub.2 --CF.sub.2 --CHF.sub.2, CF.sub.3 --CF.sub.2 --CHCl.sub.2, CHFCl--CF.sub.2 --CClF.sub.2, CHF.sub.2 --CCl.sub.2 --CF.sub.3, CF.sub.3 --CHCl--CClF.sub.2, CHF.sub.2 --CF.sub.2 --CHClF, CF.sub.3 --CR.sub.2 --CH.sub.2 Cl, CClF.sub.2 --CF.sub.2 --CH.sub.2 F, CF.sub.3 --CH.sub.2 --CClF.sub.2, CHClF--CR.sub.2 --CF.sub.3, CHF.sub.2 --CF.sub.2 --CF.sub.2 Cl, CF.sub.3 --CHCl--CF.sub.3, CF.sub.3 --CHF--CF.sub.2 Cl, and CHF.sub.2 --CFCl--CF.sub.3 is disclosed. The fluoropropanes can be used in open or enclosed areas with little or no effect on the ozone in the stratosphere and with little effect on the global warming process.
摘要翻译： 使用含有选自CF 3 -CHF-CF 3，CF 3-CF 2 -CHF 2，CF 3-CFH-CF 2 H，CF 3 -CH 2 CF 3，CF 3中的至少一种氟取代丙烷的组合物来扑灭，预防和控制火灾的方法 -CF 2 -CH 2 F，CHF 2-CF 2 -CHF 2，CF 3 -CF 2 -CHCl 2，CHFCl-CF 2 -CClF 2，CHF 2 -CCl 2 -CCl 3，CF 3 -CHCl-CClF 2，CHF 2 -CF 2 -CHClF，CF 3 CR 2 -CH 2 Cl，CClF 2 -CF 2 公开了-CH2F，CF3-CH2-CClF2，CHClF-CR2-CF3，CHF2-CF2-CF2Cl，CF3-CHCl-CF3，CF3-CHF-CF2Cl和CHF2-CFCl-CF3。 氟丙烷可用于开放或封闭的区域，对同温层臭氧几乎没有影响，也不影响全球变暖过程。
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公开(公告)号：US5180860A
公开(公告)日：1993-01-19
申请号：US545246
申请日：1990-06-28
IPC分类号： C07C17/25
CPC分类号： C07C17/25
摘要： A process for the dehydrohalogenation of saturated hydrogen-containing polyhalocarbons using liquid alkali metal acid fluoride and/or alkali metal fluoride compositions to form haloolefins.
摘要翻译： 使用液态碱金属氟化物和/或碱金属氟化物组合物使饱和含氢多卤代烃脱卤化氢以形成卤代烯烃的方法。
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