摘要:
A process for the manufacture of wear-resistant magnetic recording media comprising a dimensionally stable base, a thin ferromagnetic metal layer, containing cobalt and/or nickel, firmly bonded thereto and a thin protective layer applied thereon. The protective layer is produced by treating the recording medium in a liquid basic medium, containing gaseous oxygen, for from 1 to 60 minutes at from 5.degree. to 70.degree. C., washing and drying the treated recording medium and then heating it in air at from 170.degree. to 300.degree. C. This method offers a particularly simple way of providing the ferromagnetic layer of the recording medium with a thin but uniform, mechanically stable and wear-resistant protective layer.
摘要:
A process for metallizing substrates by activation of the substrate by deposition of palladium from a palladium complex, followed by electroless metallization. The palladium is deposited on the substrate by dipping the substrate into a solution of a palladium(O) complex and decomposing this complex at from 100.degree. to 300.degree. C.With this method it is possible to effectively activate substrates which are attacked by acid or alkali or swollen by organic solvents.
摘要:
A process for the manufacture of rigid magnetic recording media by depositing a cobalt-containing ferromagnetic metal layer on a non-magnetic metallic base disc provided with a cured layer of binder which does not dissolve or swell in organic solvents and contains non-magnetic pigments, and which has been activated, before deposition of the ferromagnetic layer, by treatment with a solution of a palladium (O) complex in an organic solvent, followed by decomposition of this complex, to prepare it to receive the ferromagnetic metal layer which is produced by electroless deposition.
摘要:
A process for the manufacture of magnetic materials containing a phase A with a ferromagnetic spin system, of composition Co.sub.x Ni.sub.1.sub.-x and a phase B with an antiferromagnetic spin system of composition (CoO).sub.x (NiO).sub.1.sub.-x , with values of x from 0.05 to 0.96, the phases A and B showing exchange interaction. The materials are manufactured by surface oxidation of starting materials having a ferromagnetic layer, at least on the surface but optionally extending deeper, of composition A, to produce the antiferromagnetic phase B, nitrous oxide being used as the oxidant. Magnetic materials thus obtained have an asymmetrical hysteresis loop, which manifests itself at different temperatures, namely the particular Neel temperature of the phase B, which depends on the composition of the phases which varies in accordance with the values of x.
摘要:
Magnetic materials which essentially consist of a phase A with a ferromagnetic spin system and a phase B with an anti-ferromagnetic spin system, phases A and B interacting by exchange coupling, and the manufacture of such materials. The materials consist essentially of two-phase magnetic single-domain particles, with the alloy [Co.sub.x Ni.sub.1.sub.-x ] as the ferromagnetic phase A and its oxidized form [(CoO).sub.x (NiO).sub.1.sub.-x ] as the anti-ferromagnetic phase B, with values of x of 0.04 to 0.96. They are manufactured by surface oxidation of a pigment layer, which at least covers the surface but may extend deeper, having the composition of phase A, to form an oxide layer, at least 40 A thick, of the phase B, followed by heating in an inert gas atmosphere, or by reduction of a corresponding layer of phase B to a layer of phase A. Magnetic single-domain particles of this composition have a Neel temperature which varies with X. As a result, materials are obtained which have an asymmetrical hysteresis loop, attributable to exchange anisotropy, at temperatures which can be varied within wide limits in accordance with the intended use of the material.
摘要:
A process for the manufacture of acicular ferromagnetic metal pigments containing iron, having a reduced field strength distribution and a steeper residual magnetization curve, by applying an alkaline earth metal cation and an organic compound having at least one group capable of forming a chelate to appropriate acicular iron oxides and then reducing the treated oxides.
摘要:
An accumulator having an acid electrolyte and possessing two electrodes of the first kind mounted on base electrodes. The active material on the positive side contains manganese dioxide. The base electrode on the negative side consists of powdered graphite embedded in a binder which is resistant to the electrolyte. The base electrode on the positive side has a coarse porous structure and consists of graphite or titanium coated with titanium nitride or titanium carbide. The average pore diameters are from 0.1 to 2 mm and the pore volume is from 20 to 70%.
摘要:
An anode for electrochemical processes consists of an electrode base plate of a metal which can be passivated electrochemically, a protective layer deposited thereon, and a further layer, consisting of manganese dioxide. The protective layer consists of the nitride of the metal of the electrode base plate.
摘要:
In an electrode suitable for electrolysis of aqueous sodium chloride or potassium chloride solutions, at least the outer layer contains spinels, specifically a mixture of the individual spinels of iron and of cobalt, the weight ratio of iron spinels: cobalt spinels being from 30:70 to 90:10.The electrodes are produced by applying a powder mixture of iron spinel and cobalt spinel to a substrate by a plasma spraying process wherein argon is used as the plasma gas and the spraying energy is from 6 to 30 kW.
摘要:
In a process for the manufacture of sodium dithionite by reacting sulfur dioxide with sodium formate and aqueous sodium hydroxide solution in the presence of methanol, an aqueous methanolic solution of sodium formate is first produced by reacting carbon monoxide with sodium hydroxide solution in an aqueous medium, containing from 1 to 50% by weight of methanol, based on the amount of water, at from 80 to 120.degree. C. under a pressure of from 10 to 40 bars. The resulting aqueous methanolic solution can be reacted directly, in the conventional manner, with sulfur dioxide and aqueous sodium hydroxide solution to give sodium dithionite.