摘要:
A method of selecting a material for the construction of a multipole mass filter that is temperature stable or in other words, the R.sub.o parameter remains invariant with change in temperature. The coefficients of thermal expansion of the quadrupole rods and mounting structure are chosen so that a constant ratio of the two is provided which in turn is determined by the geometrical construction of the filter.
摘要:
Apparatus and method for programming the ion energy of ions being analyzed by a quadruple mass spectrometer where the axis potential applied to the quadruple rods is caused to vary in synchronism with a mass scan in order that the ions of each mass being analyzed may transit the quadruple with the most advantageous energy for proper analysis (that is, with substantially equal velocities) and the application of the ion scan voltage will not distort the fringing field at the entrance to the quadrupole.
摘要:
An unbalanced radio frequency voltage is supplied between two pairs of conductive rods of a quadrupole mass filter of a mass spectrometer system. Means are provided for d.c. voltage polarity reversal for monitoring positive and negative ions. The d.c. voltage is derived by rectification of the radio frequency voltage.
摘要:
An external ion source assembly in which ion are formed in an ion volume by the interaction of energetic electrons and gas molecules. The effective energy of the electrons entering the ion volume is controlled by changing the voltage between the electron source (filament) and the ionization volume whereby ions having sufficient energy for ionizing atoms and molecules leave the electron source and enter the ionization volume only during an ionization period. The ion source assembly can be used both for electron impact ionization (EI) and for chemical ionization (CI).