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公开(公告)号：US4657874A
公开(公告)日：1987-04-14
申请号：US819074
申请日：1986-01-15
申请人： William S. Borghard , Tracy J. Huang , Sharon B. McCullen , Hans J. Schoennagel , Ying-Yen P. Tsao , Stephen S. Wong
发明人： William S. Borghard , Tracy J. Huang , Sharon B. McCullen , Hans J. Schoennagel , Ying-Yen P. Tsao , Stephen S. Wong
IPC分类号： B01J29/90 , B01J38/42 , C10G35/095 , B01J29/38 , B01J38/44
CPC分类号： C10G35/095 , B01J29/90 , B01J38/42
摘要： A process is described for rejuvenation of a deactivated highly siliceous noble metal-containing zeolite catalyst having a framework silica to alumina ratio of at least about 20 which contains agglomerated noble metal in its deactivated state. The process comprises redispersing the noble metals associated with the deactivated catalyst by contacting the catalyst with a stream of inert gas containing molecular chlorine, water and optionally, oxygen, a temperatures ranging from about 150.degree. to about 450.degree. C., a partial pressure of chlorine of from about 6 to about 15 Torr and a ratio of partial pressure of water to partial pressure of chlorine of from about 0.01 to about 2 for a period of time sufficient to achieve redispersion; purging said catalyst with an inert gas; and reducing said purged catalyst in a stream of hydrogen at a temperature ranging from about 140.degree. C. to 550.degree. C.
摘要翻译： 描述了一种用于使具有至少约20的骨架二氧化硅与氧化铝比的失活的高含硅含贵金属的沸石催化剂再生的方法，其含有处于其失活状态的附聚的贵金属。 该方法包括通过使催化剂与含有分子氯，水和任选的氧的惰性气体流接触来将与失活的催化剂相关联的贵金属再分散，温度范围为约150℃至约450℃， 约6至约15托的氯，水的分压与氯的分压的比例为约0.01至约2，持续足以实现再分散的时间; 用惰性气体吹扫所述催化剂; 并在约140℃至550℃的温度范围内将氢气流中的所述吹扫的催化剂还原。
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2.发明授权Apparatus and method for adsorption and desorption studies, particularly for characterization of catalysts 失效用于吸附和解吸研究的装置和方法，特别是催化剂的表征
公开(公告)号：US4762010A
公开(公告)日：1988-08-09
申请号：US33150
申请日：1987-04-02
IPC分类号： G01N15/08
CPC分类号： G01N15/0893 , G01N2015/0833 , G01N2015/0866
摘要： A sample is disposed in a sample chamber and is connected by a flow restrictor or "leak" to a bulb of known volume. In adsorption studies, an on/off valve is opened, allowing gas to flow from the bulb into the sample chamber. The leak controls the rate of flow to be less than the equilibrium rate of adsorption/desorption of gas with respect to the sample, such that the pressure in the sample chamber at all times is an equilibrium value. The pressure in the bulb and in the sample chamber are both measured repetitively. The change in pressure in the bulb provides an indication of the net amount of gas admitted to the sample chamber. This quantity together with the change in pressure in the sample chamber can be used to provide an indication of the amount of gas which is adsorbed onto the sample. In desorption studies the bulb is evacuated relative to the sample chamber. The on/off valve is opened to allow gas to flow from the sample chamber into the bulb at a rate controlled by the leak to be less than the equilibrium rate of adsorption/desorption such that the pressure within the sample chamber is at all times an equilibrium value. Points on the adsorption and desorption isotherms can thus be determined continually.
摘要翻译： 样品设置在样品室中，并通过限流器或“泄漏”连接到已知体积的灯泡。 在吸附研究中，打开/关闭阀，允许气体从灯泡流入样品室。 泄漏控制流速小于气体相对于样品的平衡吸附/解吸速率，使得样品室中的压力始终为平衡值。 灯泡和样品室中的压力都被重复测量。 灯泡中的压力变化提供了进入样品室的净气量的指示。 该量与样品室中的压力变化一起可用于提供吸附到样品上的气体量的指示。 在解吸研究中，灯泡相对于样品室抽真空。 开/关阀打开以允许气体以由泄漏控制的速率从样品室流入灯泡以小于平衡吸附/解吸速率，使得样品室内的压力始终为 平衡值。 因此可以连续地确定吸附和解吸等温线上的点。
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公开(公告)号：US4261810A
公开(公告)日：1981-04-14
申请号：US130802
申请日：1980-03-17
IPC分类号： C10G35/22
CPC分类号： C10G35/22 , Y10S585/906 , Y10S585/951
摘要： Process for reforming a hydrocarbon charge under reforming conditions in a reforming zone containing a sulfur-sensitive metal containing reforming catalyst wherein over-cracking of the charge stock and excessive temperature rise in the reforming zone is suppressed by pre-conditioning the catalyst, prior to contact with the charge, with a reformate of specified octane number and aromatics content.
摘要翻译： 在包含含硫敏感金属的重整催化剂的重整区中，在重整条件下重整烃装料的方法，其中通过在接触之前预处理催化剂来抑制电荷原料的过度裂化和重整区的过度温度升高 负责重组指定的辛烷值和芳烃含量。
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公开(公告)号：USRE31647E
公开(公告)日：1984-08-14
申请号：US382515
申请日：1982-05-27
IPC分类号： C10G35/22
CPC分类号： C10G35/22
摘要： Process for reforming a hydrocarbon charge under reforming conditions in a reforming zone containing a sulfur-sensitive metal containing reforming catalyst wherein over-cracking of the charge stock and excessive temperature rise in the reforming zone is suppressed by pre-conditioning the catalyst, prior to contact with the charge, with a reformate of specified octane number and aromatics content.
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公开(公告)号：US4349433A
公开(公告)日：1982-09-14
申请号：US247483
申请日：1981-03-25
申请人： Hans J. Schoennagel
发明人： Hans J. Schoennagel
IPC分类号： B01J23/46 , B01J23/656 , B01J37/04 , C10G35/09 , C10G35/06
CPC分类号： C10G35/09 , B01J23/468 , B01J23/6567 , B01J37/04
摘要： There is provided, in accordance with the present invention, a catalyst composition made up of a mixture of two components, one component comprising a minor proportion of platinum and rhenium on a support and the second component comprising a minor proportion of iridium on a separate support. A process for reforming a charge stock, such as naphtha, utilizing such catalyst is also provided.
摘要翻译： 根据本发明，提供了由两种组分的混合物组成的催化剂组合物，一种在载体上包含少量铂和铼的组分，第二组分在分开的载体上包含较小比例的铱 。 还提供了利用这种催化剂重整电荷原料如石脑油的方法。
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公开(公告)号：US5395597A
公开(公告)日：1995-03-07
申请号：US148300
申请日：1993-11-08
CPC分类号： B01J8/002
摘要： An apparatus for fluidized transport of solids, e.g., catalyst to a pilot plant FCC unit. Carrier gas flow is generated by compressing a sealed bellows to displace gas and an exit tube attached to the bellows into a solids reservoir. A confinement baffle in the solids reservoir controls solids flow and aids refilling. An auxiliary breather tube with an outlet in the solids reservoir can fluidize solids as the bellows expands.
摘要翻译： 用于将固体例如催化剂流化输送到中试工厂FCC单元的装置。 通过压缩密封的波纹管以将气体和连接到波纹管的出口管移动到固体储存器中来产生载气流。 固体储存器中的限制挡板控制固体流动并辅助再填充。 在固体储存器中具有出口的辅助通气管可随波纹管膨胀而使固体流体化。
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公开(公告)号：US4359400A
公开(公告)日：1982-11-16
申请号：US228855
申请日：1981-01-27
摘要： Supported multi-metallic platinum-containing hydrocarbon conversion catalysts which are at least partially deactivated due to the deposition of carbonaceous residues thereon during contact with hydrocarbons are regenerated by (1) contacting the catalyst with oxygen to burn at least a portion of the carbonaceous residues from the catalyst, (2) contacting the carbonaceous residue depleted catalyst with hydrogen at an elevated temperature to convert a substantial portion of the non-platinum component present in the catalyst to its metallic form, (3) contacting the reduced catalyst with dry hydrogen chloride in the absence of oxygen, (4) treatment of the hydrogen chloride treated catalyst with chlorine, and (5) reduction of the chlorine treated catalyst with a reducing agent, such as hydrogen.
摘要翻译： 由于在与烃接触期间由于其上的碳质残渣沉积而至少部分失活的支持的多金属含铂烃转化催化剂通过（1）使催化剂与氧接触以将至少一部分碳质残渣从 催化剂，（2）在高温下将含碳残余物贫化催化剂与氢气接触以将存在于催化剂中的大部分非铂组分转化为其金属形式，（3）使还原的催化剂与干氯化氢接触 无氧，（4）用氯处理氯化氢处理的催化剂，和（5）用还原剂如氢气还原氯处理的催化剂。
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8.发明授权
公开(公告)号：US4263134A
公开(公告)日：1981-04-21
申请号：US112756
申请日：1980-01-17
申请人： Hans J. Schoennagel
发明人： Hans J. Schoennagel
CPC分类号： C10G35/09 , B01J23/468 , B01J37/04
摘要： Catalyst compositions are provided comprising a refractory support, about 0.1 to about 2 percent by weight of platinum, about 0.1 to about 2 percent by weight of iridium and about 0.1 to about 5 weight percent of halogen where the platinum and iridium are contained on separate particles of said support. The relative weight ratio of the particles containing platinum and those containing iridium is between about 10:1 to about 1:10. The compositions are useful as hydrocarbon conversion catalysts and are especially applicable for use in catalyzing the reforming of naphtha petroleum fractions. There is also disclosed a reforming process conducted in the presence of hydrogen, under reforming conditions, in the presence of the above catalyst.
摘要翻译： 提供催化剂组合物，其包含耐火载体，约0.1至约2重量％的铂，约0.1至约2重量％的铱和约0.1至约5重量％的卤素，其中铂和铱包含在分开的颗粒上 的支持。 含有铂的颗粒和含有铱的颗粒的相对重量比在约10:1至约1:10之间。 该组合物可用作烃转化催化剂，特别适用于催化石脑油石油馏分的重整。 还公开了在上述催化剂存在下，在重整条件下，在氢的存在下进行的重整过程。
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公开(公告)号：US4547613A
公开(公告)日：1985-10-15
申请号：US629371
申请日：1984-07-10
摘要： Hydrocarbon streams containing primarily olefins such as ethylene up to and inclusive of C.sub.16 olefins are converted at elevated pressures to high viscosity index lube oil base stock by contacting them with a ZSM-5 type zeolite catalyst which has been conditioned by previous contact with a light olefin preferably of 3-6 carbon atoms per molecule under suitable conditions of temperature and pressure.
摘要翻译： 主要包含烯烃如乙烯直到并包括C16烯烃的烃流在升高的压力下转化为高粘度指数润滑油基础油料，通过使其与ZSM-5型沸石催化剂接触，ZSM-5型沸石催化剂通过先前接触轻烯烃 在适当的温度和压力条件下，每分子优选3-6个碳原子。
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公开(公告)号：US4316794A
公开(公告)日：1982-02-23
申请号：US127612
申请日：1980-03-06
申请人： Hans J. Schoennagel
发明人： Hans J. Schoennagel
CPC分类号： C10G47/28 , C10G2300/107
摘要： A process for the direct catalytic conversion of petroleum residual oils is disclosed wherein said oils, hydrogen and hot solid catalyst particles are contacted to form a suspension in a riser reactor thereby producing lower boiling components with the concomitant removal of impurities, e.g., metals, sulfur and nitrogen,, from the oils. Furthermore, the catalyst particles are regenerated in a partial oxidation mode, i.e. with oxygen and steam present to generate a synthesis gas comprising CO, CO.sub.2 and H.sub.2. Such synthesis gas can be subsequently shifted to produce a H.sub.2 --CO.sub.2 rich gas which could then serve as the hydrogen source in the riser reactor.
摘要翻译： 公开了用于直接催化转化石油残油的方法，其中所述油，氢和热固体催化剂颗粒接触以在提升管反应器中形成悬浮液，从而产生较低沸点的组分，同时除去杂质，例如金属，硫 和氮气。 此外，催化剂颗粒以部分氧化模式再生，即存在氧和蒸汽以产生包含CO，CO 2和H 2的合成气。 随后可以将这种合成气转移以产生富含H 2 - CO 2的气体，然后可将其作为提升管反应器中的氢源。
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