公开(公告)号：US20220325378A1

公开(公告)日：2022-10-13

申请号：US17719080

申请日：2022-04-12

Applicant: Worcester Polytechnic Institute

Inventor： Yan Wang ,  Jiahui Hou ,  Xiaotu MA ,  Jinzhao Fu

IPC: C22B26/12 ,  C22B3/06 ,  H01M10/54 ,  C01D15/08

Abstract: Lithium recycling from expended Li-Ion batteries occurs thought selective recovery of lithium charge materials from a recycling stream including transition metals used for the charge material. Li recovery includes dissolving the lithium based charge material in an organic acid having a resistance or lack of affinity to dissolution of transition metals, and distilling a leach solution formed from the dissolved charge material for generating a powder including lithium and trace impurities of the transition metals. Sintering of the generated powder forms lithium carbonate and carbonates of the trace impurities that eluded the selective leach, however, since the trace impurities are insoluble in water, the lithium carbonate is recoverable by water washing.

公开(公告)号：US11827998B2

公开(公告)日：2023-11-28

申请号：US17330922

申请日：2021-05-26

Applicant: Worcester Polytechnic Institute

Inventor： Yan Wang ,  Xiaotu Ma ,  Eric Gratz ,  Jinzhao Fu ,  Panawan Vanaphuti

IPC: C30B1/02 ,  C30B1/12 ,  C30B29/22 ,  H01M4/525 ,  H01M10/54 ,  H01M4/505 ,  H01M4/02

CPC classification number: C30B1/02 ,  C30B1/12 ,  C30B29/22 ,  H01M4/505 ,  H01M4/525 ,  H01M10/54 ,  H01M2004/028

Abstract: A recycling and synthesis of charge material for secondary batteries generates single-crystal charge materials for producing batteries with greater charge cycle longevity. Charge material particles undergo a heating for fusing or enhancing grain boundaries between polycrystalline particles. The resulting, more well-defined grain boundaries are easily etched by a relatively weak mineral acid solution. The acid solution removes material at the grain boundaries to separate secondary particles into primary particles along the grain boundaries. The resulting single crystal (monocrystalline) charge material particles are washed and filtered, and typically re-sintered to accommodate any needed lithium (lithium carbonate), and result in a charge material with larger surface area, higher lithium diffusivity and lower cation ordering.

公开(公告)号：US20210372001A1

公开(公告)日：2021-12-02

申请号：US17330922

申请日：2021-05-26

Applicant: Worcester Polytechnic Institute

Inventor： Yan Wang ,  Xiaotu MA ,  Eric Gratz ,  Jinzhao Fu ,  Panawan Vanaphuti

IPC: C30B1/02 ,  C30B1/12 ,  C30B29/22 ,  H01M4/505 ,  H01M4/525 ,  H01M10/54

Abstract: A recycling and synthesis of charge material for secondary batteries generates single-crystal charge materials for producing batteries with greater charge cycle longevity. Charge material particles undergo a heating for fusing or enhancing grain boundaries between polycrystalline particles. The resulting, more well-defined grain boundaries are easily etched by a relatively weak mineral acid solution. The acid solution removes material at the grain boundaries to separate secondary particles into primary particles along the grain boundaries. The resulting single crystal (monocrystalline) charge material particles are washed and filtered, and typically re-sintered to accommodate any needed lithium (lithium carbonate), and result in a charge material with larger surface area, higher lithium diffusivity and lower cation ordering.