Process for making composite colorant particles
    1.
    发明授权
    Process for making composite colorant particles 有权
    制备复合着色剂颗粒的方法

    公开(公告)号:US06635693B2

    公开(公告)日:2003-10-21

    申请号:US09822096

    申请日:2001-03-30

    IPC分类号: C08K900

    摘要: A process for making composite colorant particles comprising, in order: I) suspending in an aqueous medium, under agitation, finely divided colorant particles to form an aqueous colorant mixture; II) adding to the aqueous colorant mixture an addition polymerization initiator; and III) causing the addition polymerization initiator to form a free radical while continuously introducing continuously to the aqueous colorant mixture a monomer mixture comprising: a) an addition polymerization initiator, and b) at least one ethylenically-unsaturated monomer; thereby forming the composite colorant particles having a colorant phase and a polymer phase.

    摘要翻译: 一种制备复合着色剂颗粒的方法,其包括:I)在搅拌下悬浮在含水介质中,细碎的着色剂颗粒以形成水性着色剂混合物; II)向水性着色剂混合物中加入加成聚合引发剂; 和III)使所述加成聚合引发剂形成自由基,同时连续向所述水性着色剂混合物中引入单体混合物,所述单体混合物包含:a)加成聚合引发剂,和b)至少一种烯键式不饱和单体;从而形成具有 着色剂相和聚合物相。

    Heat-sensitive compositions and imaging member containing carbon black and methods of imaging and printing
    2.
    发明授权
    Heat-sensitive compositions and imaging member containing carbon black and methods of imaging and printing 失效
    含有炭黑的热敏组合物和成像构件以及成像和印刷方法

    公开(公告)号:US06660449B2

    公开(公告)日:2003-12-09

    申请号:US10083258

    申请日:2001-10-19

    IPC分类号: G03F7038

    摘要: An imaging member, such as a negative-working printing plate or on-press cylinder, comprises latex polymer-carbon black composite particles. Such imaging members can be prepared with a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer having ionic moieties and the latex polymer-carbon black composite particles as a photothermal conversion material. The latex polymer-carbon black composite particles can be formulated in water or water-miscible solvents without agglomeration with other components such as charged polymers.

    摘要翻译: 成像构件,例如负压印版或压印滚筒,包括胶乳聚合物 - 炭黑复合颗粒。 这样的成像构件可以由具有离子部分的热敏亲水性聚合物和胶乳聚合物 - 炭黑复合颗粒作为光热转化材料的亲水成像层制备。 胶乳聚合物 - 炭黑复合颗粒可以配制成水或水混溶性溶剂,而不与其它组分例如带电聚合物结合。

    Polymer latexes with core-shell morphology
    5.
    发明授权
    Polymer latexes with core-shell morphology 失效
    具有核 - 壳形态的聚合物胶乳

    公开(公告)号:US06203973B1

    公开(公告)日:2001-03-20

    申请号:US09276074

    申请日:1999-03-25

    IPC分类号: G03C1053

    摘要: The present invention is a polymer latex that includes polymer particles having a core portion and a shell portion. The core portion contains polymerized hydrophobic ethylenically unsaturated monomers with a water solubility less than 1% at room temperature. The shell portion contains polymerized monomers defined by formula (I) wherein X is O or NH, or NCH3, R1 and R2 are H, CH3, C2H5, C3H7, or C4H9, R3 and R4 are H or CH3, n1 and n2 are integers, n1 is from 1 to 4, n2 is from 1 to 20. The polymer particles having a size of less than 50 nm.

    摘要翻译: 本发明是包含具有芯部和壳部的聚合物粒子的聚合物胶乳。 核心部分含有在室温下水溶解度小于1%的聚合的疏水烯属不饱和单体。 壳部分包含由式(I)定义的聚合单体,其中X是O或NH,或NCH 3,R 1和R 2是H,CH 3,C 2 H 5,C 3 H 7或C 4 H 9,R 3和R 4是H或CH 3,n1和n2是整数 ,n1为1〜4,n2为1〜20。聚合物粒子的尺寸小于50nm。

    Photographic coupler compositions containing ballasted alcohols and
methods
    6.
    发明授权
    Photographic coupler compositions containing ballasted alcohols and methods 失效
    含有镇流醇的摄影成色剂组合物及方法

    公开(公告)号:US5429913A

    公开(公告)日:1995-07-04

    申请号:US113012

    申请日:1993-08-30

    IPC分类号: G03C7/38 G03C7/388 G03C7/392

    CPC分类号: G03C7/3885 G03C7/39232

    摘要: Photographic coupler compositions comprise a magenta dye-forming coupler and an alcohol in an amount sufficient to increase the activity of the dye-forming coupler. The alcohol is of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of (a) unsubstituted alkyl and alkenyl groups, (b) alkyl groups containing one or more substitutents selected from the group consisting of aryl groups, alkenyl groups, halogen atoms, alkoxy groups, alkoxy carbonyl groups and acyloxy groups, (c) unsubstituted aryl groups and (d) aryl groups containing one or more substituents selected from the group consisting of alkyl groups, alkoxy groups, alkoxy carbonyl groups and acyloxy groups; and R.sub.2 and R.sub.3 are individually selected from hydrogen and the group of moieties from which R is selected, provided that the total number of carbon atoms contained in R.sub.1, R.sub.2 and R.sub.3 is at least 10.

    摘要翻译: 摄影成色剂组合物包含洋红染料形成成色剂和醇,其量足以增加染料形成成色剂的活性。 醇是具有式(Ia)的式子,其中R 1选自(a)未取代的烷基和烯基,(b)含有一个或多个选自芳基,烯基,卤素 原子,烷氧基,烷氧基羰基和酰氧基,(c)未取代的芳基和(d)含有一个或多个选自烷基,烷氧基,烷氧基羰基和酰氧基的取代基的芳基; 并且R 2和R 3各自独立地选自氢和选自R的部分基团,条件是R1,R2和R3中所含的碳原子总数至少为10。

    Photographic coupler compositions and methods for reducing continued
coupling
    7.
    发明授权
    Photographic coupler compositions and methods for reducing continued coupling 失效
    摄影耦合器组合物和减少连续耦合的方法

    公开(公告)号:US5298368A

    公开(公告)日:1994-03-29

    申请号:US689436

    申请日:1991-04-23

    摘要: Photographic coupler compositions comprise (a) a pyrazolone magenta dye-forming coupler compound, and (b) a sulfoxide compound in an amount sufficient to reduce continued coupling of the coupler compound during the bleach step of a color photographic process. The sulfoxide compound is of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of straight and branched chain alkyl groups, alkenyl groups and alkylene groups; straight and branched chain alkyl groups, alkenyl groups and alkylene groups containing at least one substituent selected from the group consisting of alkoxy, aryloxy, aryl, alkoxycarbonyl, aryloxycarbonyl, acyloxy, carbonamido and carbamoyl groups and halogen atoms; a phenyl group; and a phenyl group containing at least one substituent selected from the group consisting of alkyl, alkoxy, aryloxy, aryl, alkoxycarbonyl, aryloxycarbonyl, acyloxy, carbonamido and carbamoyl groups and halogen atoms. Additionally, R.sub.1 and R.sub.2 combined contain at least 12 carbon atoms. Preferably, the coupler composition is substantially free of phenol compounds when R.sub.1 and R.sub.2 are other than unsubstituted alkyl, alkenyl or alkylene groups.

    摘要翻译: 摄影成色剂组合物包含(a)形成吡唑啉酮品红色染料的成色剂化合物,和(b)足够量的亚砜化合物,其量可以在彩色照相法漂白步骤期间减少偶合剂化合物的持续偶联。 亚砜化合物具有式(*化学结构*),其中R 1和R 2分别选自直链和支链烷基,烯基和亚烷基; 直链和支链烷基,烯基和含有至少一个选自烷氧基,芳氧基,芳基,烷氧基羰基,芳氧基羰基,酰氧基,碳酰氨基和氨基甲酰基和卤素原子的取代基的亚烷基; 苯基; 和含有至少一个选自烷基,烷氧基,芳氧基,芳基,烷氧基羰基,芳氧基羰基,酰氧基,碳酰氨基和氨基甲酰基和卤素原子的取代基的苯基。 另外,R 1和R 2组合​​含有至少12个碳原子。 当R 1和R 2不是未取代的烷基,烯基或亚烷基时,优选地,所述成色剂组合物基本上不含酚化合物。

    Method of preparing photographic elements incorporating polymeric
ultraviolet absorbers
    8.
    发明授权
    Method of preparing photographic elements incorporating polymeric ultraviolet absorbers 失效
    制备含有聚合物紫外线吸收剂的照相元件的方法

    公开(公告)号:US5372922A

    公开(公告)日:1994-12-13

    申请号:US175081

    申请日:1993-12-29

    IPC分类号: G03C1/005 G03C1/815

    摘要: A method of preparing a photographic element containing a UV filter composition. In the method a UV absorbing polymer latex is prepared by emulsion polymerization, then loaded with a high boiling point organic solvent. The high boiling poing organic solvent has a boiling point at atmospheric pressure of at least 200.degree. C. The loaded polymer latex is then incorporated into a photographic element. Photographic elements containing UV polymer latexes particularly of a UV absorbing polymer containing benzotriazole monomers loaded with high boiling point organic solvents, are also provided.

    摘要翻译: 一种制备含有UV滤光片组合物的照相元件的方法。 在该方法中,通过乳液聚合制备UV吸收聚合物胶乳,然后装载高沸点有机溶剂。 高沸点有机溶剂的沸点在大气压至少为200℃。然后将负载的聚合物胶乳并入照相元件中。 还提供了含有UV聚合物胶乳,特别是含有负载高沸点有机溶剂的苯并三唑单体的UV吸收聚合物的照相元件。