公开(公告)号：US06380127B1

公开(公告)日：2002-04-30

申请号：US09423450

申请日：2000-01-05

申请人： Yasuhiro Aoyama ,  Takehisa Dewa ,  Tomoya Sawaki

发明人： Yasuhiro Aoyama ,  Takehisa Dewa ,  Tomoya Sawaki

IPC分类号： B01J3100

CPC分类号： B01J31/0214 ,  B01J31/02 ,  B01J2231/326 ,  Y10S502/513

摘要： A novel metal composite is provided which is useful as a catalyst or the like by the control of a structure of an apohost and the modification thereof and in which an organic apohost capable of forming a porous structure by a hydrogen bond is compounded with at least one type of transition metallic elements or compounds thereof.

摘要翻译： 提供了一种新颖的金属复合材料，其可以通过控制末梢结构的结构及其修饰而用作催化剂等，并且其中能够通过氢键形成多孔结构的有机载脂蛋白复合物与至少一种 过渡金属元素或其化合物的类型。

公开(公告)号：US07557059B2

公开(公告)日：2009-07-07

申请号：US10581537

申请日：2004-11-24

申请人： Yoji Hori ,  Junji Nakamura ,  Tomoya Sawaki ,  Shigeru Tanaka

发明人： Yoji Hori ,  Junji Nakamura ,  Tomoya Sawaki ,  Shigeru Tanaka

IPC分类号： B01J31/00 ,  C07D301/12

CPC分类号： B01J23/30 ,  B01J27/053 ,  B01J27/188 ,  B01J31/0239 ,  B01J2231/72 ,  C07D301/12 ,  C07D303/14 ,  C07D495/08

摘要： A novel multicomponent oxidation catalyst that can be effectively used in, for example, an epoxidation reaction of olefins, etc., being inexpensive and high in versatility and that exhibits high catalytic activity; and a process for producing an epoxy compound through hydrogen peroxide oxidation of an olefin with the use of the multicomponent oxidation catalyst. There is provided a multicomponent oxidation catalyst comprising a tungsten compound, a quaternary ammonium salt, any of phosphoric acids and/or boric acids and a hydrogen sulfate salt. Further, there is provided a process for producing an epoxy compound, characterized in that an olefin is oxidized with hydrogen peroxide in the presence of the above multicomponent oxidation catalyst. The epoxy compound obtained by this process is useful as an intermediate of agricultural chemicals, medicines or the like, a raw material of various polymers, etc.

摘要翻译： 可有效用于例如烯烃等的环氧化反应的新颖的多组分氧化催化剂成本低廉，通用性高，催化活性高; 以及通过使用多组分氧化催化剂通过烯烃的过氧化氢氧化生产环氧化合物的方法。 提供了包含钨化合物，季铵盐，磷酸和/或硼酸中的任一种和硫酸氢盐的多组分氧化催化剂。 此外，提供了一种制备环氧化合物的方法，其特征在于在上述多组分氧化催化剂存在下，用过氧化氢氧化烯烃。 通过该方法获得的环氧化合物可用作农药，药物等的中间体，各种聚合物的原料等。

公开(公告)号：US20050059830A1

公开(公告)日：2005-03-17

申请号：US10899965

申请日：2004-07-26

申请人： Tomoya Sawaki ,  Hiroyuki Kenmochi ,  Yoji Hori

发明人： Tomoya Sawaki ,  Hiroyuki Kenmochi ,  Yoji Hori

IPC分类号： C07D307/93 ,  C07D307/00

CPC分类号： C07D307/00

摘要： An object of the present invention is to provide a novel monomer compound having a lactone structure which gives polymers having more excellent feature as resist material, etc. The present invention relates to a compound represented by the following formula [1]: wherein R1 and R2 are an alkyl group; R3 and R4 are each independently hydrogen atom or an alkyl group; R5 is hydrogen atom, acryloyl group or methacryloyl group; and X is a methylene group which may have an alkyl group or an ethylene group which may have an alkyl group. The present invention provides a compound having a lactone structure which gives a polymer having more excellent feature particularly as a resist material and also provides a hydroxy lactone being useful as a material, etc. therefor.

摘要翻译： 本发明的目的是提供一种具有内酯结构的新单体化合物，其具有作为抗蚀剂材料等具有更优异特征的聚合物。本发明涉及由下式[1]表示的化合物：其中R 1 且R 2为烷基; R 3和R 4各自独立地为氢原子或烷基; R 5是氢原子，丙烯酰基或甲基丙烯酰基; X为可以具有烷基的亚甲基或可具有烷基的亚乙基。 本发明提供了具有内酯结构的化合物，其特别是作为抗蚀剂材料得到具有更优异特征的聚合物，并且还提供可用作材料的羟基内酯等。

公开(公告)号：US20070117993A1

公开(公告)日：2007-05-24

申请号：US10581537

申请日：2004-11-24

申请人： Yoji Hori ,  Junji Nakamura ,  Tomoya Sawaki ,  Shigeru Tanaka

发明人： Yoji Hori ,  Junji Nakamura ,  Tomoya Sawaki ,  Shigeru Tanaka

IPC分类号： C07D301/12

CPC分类号： B01J23/30 ,  B01J27/053 ,  B01J27/188 ,  B01J31/0239 ,  B01J2231/72 ,  C07D301/12 ,  C07D303/14 ,  C07D495/08

摘要： A novel multicomponent oxidation catalyst that can be effectively used in, for example, an epoxidation reaction of olefins, etc., being inexpensive and high in versatility and that exhibits high catalytic activity; and a process for producing an epoxy compound through hydrogen peroxide oxidation of an olefin with the use of the multicomponent oxidation catalyst. There is provided a multicomponent oxidation catalyst comprising a tungsten compound, a quaternary ammonium salt, any of phosphoric acids and/or boric acids and a hydrogen sulfate salt. Further, there is provided a process for producing an epoxy compound, characterized in that an olefin is oxidized with hydrogen peroxide in the presence of the above multicomponent oxidation catalyst. The epoxy compound obtained by this process is useful as an intermediate of agricultural chemicals, medicines or the like, a raw material of various polymers, etc.

摘要翻译： 可有效用于例如烯烃等的环氧化反应的新颖的多组分氧化催化剂成本低廉，通用性高，催化活性高; 以及通过使用多组分氧化催化剂通过烯烃的过氧化氢氧化生产环氧化合物的方法。 提供了包含钨化合物，季铵盐，磷酸和/或硼酸中的任一种和硫酸氢盐的多组分氧化催化剂。 此外，提供了一种制备环氧化合物的方法，其特征在于在上述多组分氧化催化剂存在下，用过氧化氢氧化烯烃。 通过该方法获得的环氧化合物可用作农药，药物等的中间体，各种聚合物的原料等。

公开(公告)号：US07105684B2

公开(公告)日：2006-09-12

申请号：US10899965

申请日：2004-07-26

申请人： Tomoya Sawaki ,  Hiroyuki Kenmochi ,  Yoji Hori

发明人： Tomoya Sawaki ,  Hiroyuki Kenmochi ,  Yoji Hori

IPC分类号： C07D313/00 ,  C07D493/08 ,  C07D307/77 ,  C07C69/74

CPC分类号： C07D307/00

摘要： An object of the present invention is to provide a novel monomer compound having a lactone structure which gives polymers having more excellent feature as resist material, etc.The present invention relates to a compound represented by the following formula [1]: wherein R1 and R2 are an alkyl group; R3 and R4 are each independently hydrogen atom or an alkyl group; R5 is hydrogen atom, acryloyl group or methacryloyl group; and X is a methylene group which may have an alkyl group or an ethylene group which may have an alkyl group. The present invention provides a compound having a lactone structure which gives a polymer having more excellent feature particularly as a resist material and also provides a hydroxy lactone being useful as a material, etc. therefor.

摘要翻译： 本发明的目的是提供一种具有内酯结构的新型单体化合物，其具有赋予作为抗蚀剂材料等优异特性的聚合物等。本发明涉及由下式[1]表示的化合物：其中R ^{1 和R 2是烷基; R 3和R 4各自独立地为氢原子或烷基; R 5是氢原子，丙烯酰基或甲基丙烯酰基; X为可以具有烷基的亚甲基或可具有烷基的亚乙基。 本发明提供了具有内酯结构的化合物，其特别是作为抗蚀剂材料得到具有更优异特征的聚合物，并且还提供可用作材料的羟基内酯等。}