公开(公告)号：US5556916A

公开(公告)日：1996-09-17

申请号：US336200

申请日：1994-11-04

申请人： Yasuo Matoba ,  Yasumi Shimizu ,  Katsuhito Miura ,  Sojiro Kitano ,  Takahiro Sakashita ,  Hidekazu Tanaka

发明人： Yasuo Matoba ,  Yasumi Shimizu ,  Katsuhito Miura ,  Sojiro Kitano ,  Takahiro Sakashita ,  Hidekazu Tanaka

IPC分类号： C08L55/02 ,  C08L71/02 ,  C08L71/03

CPC分类号： C08L55/02 ,  C08L71/02 ,  Y10S524/91 ,  Y10S525/932

摘要： A resin composition is provided which comprises a mixture of A) 100 parts by weight of an ABS graft copolymer comprising as component monomers an acrylonitrile compound and a vinyl aromatic compound in a weight ratio of 10:90 to 50:50, and B) 5 to 30 parts by weight of an ethylene oxide copolymer comprising ethylene oxide as a first monomer and a second monomer and containing at least 50 wt. % of ethylene oxide, the ethylene oxide copolymer having a refractive index (n.sub.D.sup.20) of at least 1.50, wherein said second monomer has a refractive index of at least 1.54 and is 2-phenylphenyl glycidyl ether or 1-naphthyl glycidyl ether, and wherein the molecular weight of the ethylene oxide copolymer is 1 to 5 in terms of a reduced viscosity as measured at 80.degree. C. using 0.1 g/dl monochlorobenzene solution thereof.

摘要翻译： 提供一种树脂组合物，其包含A）100重量份的ABS接枝共聚物的混合物，所述ABS接枝共聚物以10:90至50:50的重量比包含丙烯腈化合物和乙烯基芳族化合物作为组分单体，B）5 至30重量份的环氧乙烷共聚物，其包含环氧乙烷作为第一单体和第二单体，并含有至少50重量％ ％的环氧乙烷，折射率（nD20）为至少1.50的环氧乙烷共聚物，其中所述第二单体的折射率为至少1.54，为2-苯基苯基缩水甘油醚或1-萘基缩水甘油醚，其中 环氧乙烷共聚物的分子量在80℃下使用0.1g / dl一氯苯溶液测定的比浓粘度为1〜5。

公开(公告)号：US6162563A

公开(公告)日：2000-12-19

申请号：US51776

申请日：1999-03-11

申请人： Katsuhito Miura ,  Shigeru Shoji ,  Takahiro Sakashita ,  Yasuo Matoba

发明人： Katsuhito Miura ,  Shigeru Shoji ,  Takahiro Sakashita ,  Yasuo Matoba

IPC分类号： C08G65/22 ,  H01B1/12 ,  H01M4/52 ,  H01M4/525 ,  H01M6/18 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/36

CPC分类号： H01M10/0568 ,  C08G65/22 ,  H01B1/122 ,  H01G11/56 ,  H01M4/525 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0565 ,  Y02E60/13

摘要： A polymer solid electrolyte obtained by blending (1) a polyether copolymer having a main chain derived form ethylene oxide and an oligooxyethylene side chain, (2) an electrolyte salt compound, and (3) a plasticizer of an aprotic organic solvent or a derivative or metal salt of a polyalkylene glycol having a number-average molecular weight of 200 to 5,000 or a metal salt of the derivative is superior in ionic conductivity and also superior in processability, moldability and mechanical strength to a conventional solid electrolyte. A secondary battery is constructed by using the polymer solid electrolyte in combination with a lithium metal negative electrode and a lithium cobaltate positive electrode.

摘要翻译： PCT No.PCT / JP97 / 02854 Sec。 371 1999年3月11日 102（e）1999年3月11日PCT PCT 1997年8月19日PCT公布。 公开号WO98 / 07772 日本特开1998日2月26日公开了一种聚合物固体电解质，其通过共混（1）具有衍生自环氧乙烷的主链和低聚氧乙烯侧链的聚醚共聚物，（2）电解质盐化合物和（3）非质子性有机物的增塑剂 溶剂或数均分子量为200〜5000的聚亚烷基二醇的衍生物或金属盐或该衍生物的金属盐的离子导电性优异，并且与常规固体电解质相比，加工性，成型性和机械强度也优异。 通过使用聚合物固体电解质与锂金属负极和钴酸锂正极组合来构造二次电池。

公开(公告)号：US06239204B1

公开(公告)日：2001-05-29

申请号：US09147159

申请日：1998-10-21

申请人： Katsuhito Miura ,  Shigeru Shoji ,  Takahiro Sakashita ,  Yasuo Matoba

发明人： Katsuhito Miura ,  Shigeru Shoji ,  Takahiro Sakashita ,  Yasuo Matoba

IPC分类号： C08K330

CPC分类号： H01M10/0565 ,  C08G65/14 ,  C08G65/22 ,  C08G65/24 ,  H01M6/181 ,  H01M10/052

摘要： A crosslinked material of a polyether copolymer comprising: (A) 1 to 98% by mol of a repeating unit derived from a monomer represented by the formula (I): (B) 95 to 1% by mol of a repeating unit derived from a monomer represented by the formula (II): (C) 0.005 to 15% by mol of a repeating unit derived from a monomer having one epoxy group and at least one reactive functional group; provides a polymer solid electrolyte which is superior in ionic conductivity and also superior in processability, moldability, mechanical strength and flexibility, furthermore thermal resistance.

摘要翻译： 一种聚醚共聚物的交联材料，其包含：（A）1〜98摩尔％的由式（I）:( B）表示的单体衍生的重复单元：95〜1摩尔％ 由式（II）表示的单体:( C）0.005〜15摩尔％的来自具有一个环氧基和至少一个反应性官能团的单体的重复单元; 提供了离子导电性优异且加工性，成型性，机械强度和柔软性以及耐热性优异的聚合物固体电解质。

公开(公告)号：US5837157A

公开(公告)日：1998-11-17

申请号：US959707

申请日：1997-10-27

申请人： Shinzo Kohjiya ,  Yuko Ikeda ,  Katsuhito Miura ,  Shigeru Shoji ,  Yasuo Matoba ,  Masayoshi Watanabe ,  Takahiro Sakashita

发明人： Shinzo Kohjiya ,  Yuko Ikeda ,  Katsuhito Miura ,  Shigeru Shoji ,  Yasuo Matoba ,  Masayoshi Watanabe ,  Takahiro Sakashita

IPC分类号： C08G65/08 ,  C08G65/22 ,  G01N27/407 ,  H01B1/12 ,  H01G9/02 ,  H01G9/025 ,  H01M6/18 ,  H01M10/052 ,  H01M10/0565

CPC分类号： H01G9/025 ,  C08G65/08 ,  C08G65/22 ,  G01N27/4074 ,  H01B1/122 ,  H01M10/052 ,  H01M10/0565 ,  H01M6/181

摘要： A polymer solid electrolyte which is superior to a conventional solid electrolyte in ion conductivity and also superior in processing characteristics, molding characteristics, mechanical strength and flexibility. The polymer solid electrolyte produced by formulating a soluble electrolyte salt compound to a polyether copolymer having an oligooxyethylene side chain and an electrolyte salt compound which is soluble in the polyether copolymer, the polyether polymer being a solid random copolymer having a main chain structure consisting of 5 to 30 molar % of a structural unit of the following formula (1) and 95 to 70 molar % of a structural unit of the following formula (2), and the polyether polymer having a polymerization degree n of an oxyethylene unit of the side chain part of the formula (1) of 1 to 12, a number-average molecular weight of 100,000 to 2,000,000, a glass transition point measured by a differential scanning calorimeter (DSC) of not more than -60.degree. C. and a melting calorie of not more than 70 J/g. ##STR1##

摘要翻译： 一种聚合物固体电解质，其离子传导性优于常规固体电解质，并且加工特性，成型特性，机械强度和柔韧性也优异。 通过将可溶性电解质盐化合物配制成具有低聚氧乙烯侧链的聚醚共聚物和可溶于所述聚醚共聚物的电解质盐化合物而制备的聚合物固体电解质，所述聚醚聚合物为具有主链结构的固体无规共聚物，所述主链结构为5 至30摩尔％的下式（1）的结构单元和95至70摩尔％的下式（2）的结构单元，并且具有侧链的氧亚乙基单元的聚合度n的聚醚聚合物 式（1）的1〜12的一部分，数均分子量为100,000〜200万，通过差示扫描量热计（DSC）测定的玻璃化转变温度为-60℃以下，熔融卡路里 不超过70 J / g。 （1）（CH2CH2O）（2）

公开(公告)号：US5519079A

公开(公告)日：1996-05-21

申请号：US352884

申请日：1994-12-09

申请人： Yoshihiro Tomoshige ,  Yoshikazu Nishi ,  Hidekazu Tanaka ,  Kohji Ohnuki ,  Yasuo Matoba

发明人： Yoshihiro Tomoshige ,  Yoshikazu Nishi ,  Hidekazu Tanaka ,  Kohji Ohnuki ,  Yasuo Matoba

IPC分类号： C08K3/26 ,  C08K5/45 ,  C08K13/02

CPC分类号： C08K5/45 ,  C08K13/02 ,  C08K3/26 ,  C08L71/03

摘要： A vulcanizable composition which contains(a) 100 parts by weight of an epichlorohydrin polymer;(b) 0.1 to 10 parts by weight of a 2,3-dimercaptopyrazine derivative or a 2,3-dimercaptoquinoxaline derivative; and(c) 1 to 10 parts by weight of a hydrotalcite compound, has the high vulcanization rate and the excellent long time storage stability.

摘要翻译： 一种可硫化组合物，其含有（a）100重量份表氯醇聚合物; （b）0.1〜10重量份的2,3-二巯基吡嗪衍生物或2,3-二巯基喹喔啉衍生物; 和（c）1至10重量份的水滑石化合物，具有高硫化速率和优异的长时间保存稳定性。

公开(公告)号：US4342851A

公开(公告)日：1982-08-03

申请号：US239036

申请日：1981-02-27

申请人： Akio Suzui ,  Yasuo Matoba

发明人： Akio Suzui ,  Yasuo Matoba

IPC分类号： C08K5/3445 ,  C08K5/36 ,  C08K13/02 ,  C08G65/24 ,  C08B11/22 ,  C08F8/34

CPC分类号： C08K5/36 ,  C08K13/02 ,  C08K5/3445

摘要： A curable composition of halogen-containing polymer composed of(1) 100 parts by weight of a halogen-containing polymer,(2) as a crosslinking agent, about 0.1 to about 10 parts by weight of a 2,4-dithiohydantoin having the formula ##STR1## wherein R.sub.1 and R.sub.2 are identical or different and represent a member selected from the class consisting of a hydrogen atom, C.sub.1 -C.sub.8 alkyl groups, C.sub.6 -C.sub.8 cycloalkyl groups, C.sub.2 -C.sub.8 alkenyl groups, C.sub.6 -C.sub.8 aryl groups and C.sub.7 -C.sub.8 aralkyl groups, or R.sub.1 and R.sub.2 are bonded together to form a 5- or 7-membered hydrocarbon ring which may contain a nitrogen atom and have at least one lower alkyl group as a substituent,or a metal salt thereof, and(3) as an acid acceptor, about 0.5 to about 50 parts by weight of a compound of a metal of Group II of IVa of the periodic table.

摘要翻译： 含有卤素的聚合物的可固化组合物由（1）100重量份的含卤聚合物，（2）作为交联剂组成，约0.1至约10重量份的2,4-二硫乙内酰脲，其具有式 （I）其中R 1和R 2相同或不同，并且表示选自氢原子，C 1 -C 8烷基，C 6 -C 8环烷基，C 2 -C 8烯基，C 6 -C 8芳基 基团和C7-C8芳烷基，或R1和R2键合在一起形成可含有氮原子并具有至少一个低级烷基作为取代基的5-或7-元烃环或其金属盐， 和（3）作为酸受体，约0.5至约50重量份的周期表IVa族II族金属的化合物。

公开(公告)号：US4511698A

公开(公告)日：1985-04-16

申请号：US452736

申请日：1982-12-23

申请人： Yasuo Matoba ,  Isao Ishimori

发明人： Yasuo Matoba ,  Isao Ishimori

IPC分类号： C08L71/00 ,  C08K5/378 ,  C08K13/02 ,  C08L33/00 ,  C08L33/02 ,  C08L33/04 ,  C08L33/06 ,  C08L33/14 ,  C08L63/00 ,  C08L71/02 ,  C08L71/03

CPC分类号： C08L33/14 ,  C08K5/378 ,  C08L71/03 ,  C08L33/068 ,  C08L63/00 ,  Y10S525/913

摘要： A curable composition of an epichlorohydrin rubber and an acrylic rubber composed of(1) 100 parts by weight of (a) 10-97% by weight of an epichlorohydrin rubber and (b) 3-90% by weight of an epoxy-containing acrylic rubber,(2) as a crosslinking agent, about 0.1 to about 10 parts by weight of a 2,3-dimercapto-pyrazine or -quinoxaline compound having the following formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as defined in claim 1 and(3) as an acid acceptor, about 0.1 to about 50 parts by weight of a compound of a metal of Group II or IVa of the periodic table.

摘要翻译： 一种表氯醇橡胶和丙烯酸橡胶的可固化组合物，由（1）100重量份（a）10-97重量％的表氯醇橡胶和（b）3-90重量％的含环氧丙烯酸酯组成 橡胶，（2）作为交联剂，约0.1至约10重量份的具有下式的2,3-二巯基吡嗪或喹喔啉化合物其中R 1，R 2，R 3和R 4如 权利要求1和（3）作为酸受体，约0.1至约50重量份的元素周期表中II或IVa族金属的化合物。

公开(公告)号：US4165416A

公开(公告)日：1979-08-21

申请号：US781300

申请日：1977-03-25

申请人： Yasuo Matoba ,  Akira Hashimoto ,  Mikio Sugahara

发明人： Yasuo Matoba ,  Akira Hashimoto ,  Mikio Sugahara

IPC分类号： C08K5/17 ,  C08K5/39 ,  C08K5/37 ,  C08J3/24

CPC分类号： C08K5/17 ,  C08K5/39

摘要： A cured or uncured chlorinated polyethylene composition free from hexamethylphosphoric triamide complex comprising (A) chlorinated polyethylene, (B) a mercaptotriazine as cross-linking agent, (C) a cross-linking accelerator selected from the group consisting of specified dithiocarbamic compounds, secondary and tertiary amines, and the carboxylates, mercaptothiazole salts, dithiocarbamates and dithiophosphates of said secondary and tertiary amines and the benzothiazylsulfenamides of said secondary amines, and (D) an acid acceptor of metal compounds; as well as a process for curing uncured chlorinated polyethylene which comprises heating same in the absence of hexamethylphosphoric triamide complex in the presence of (B), (C) and (D) at a temperature of about 120.degree. to about 200.degree. C.

摘要翻译： 不含六甲基磷酰三胺络合物的固化或未固化的氯化聚乙烯组合物，其包含（A）氯化聚乙烯，（B）巯基三嗪作为交联剂，（C）交联促进剂，选自指定的二硫代氨基甲酸酯化合物，仲和 叔胺和所述仲胺和所述仲胺的苯并噻唑基亚磺酰胺的羧酸盐，巯基噻唑盐，二硫代氨基甲酸盐和二硫代磷酸盐，和（D）金属化合物的酸受体; 以及用于固化未固化的氯化聚乙烯的方法，该方法包括在（B），（C）和（D）的存在下，在约120℃至约200℃的温度下，在不存在六甲基磷酰三胺酰胺配合物的情况下对其进行加热。

公开(公告)号：US20110160342A1

公开(公告)日：2011-06-30

申请号：US13060264

申请日：2009-03-03

申请人： Yasuo Matoba ,  Tadahiro Ono ,  Motoki Kitagawa

发明人： Yasuo Matoba ,  Tadahiro Ono ,  Motoki Kitagawa

IPC分类号： C08L71/03

CPC分类号： C08L71/03 ,  C08G65/14 ,  C08G65/24 ,  C08K5/0016 ,  C08K5/0025 ,  C08L2205/05

摘要： Disclosed is a vulcanizable rubber composition for use in an air spring, which has excellent low-temperature behavior, and a vulcanized rubber formed product for air springs, which is obtained by vulcanization of the rubber composition. Also disclosed is a vulcanizable rubber composition for use in an air spring, comprising: an epihalohydrin-based copolymer comprising 50 to 70 mol % of a constituent unit derived from ethylene oxide and/or propylene oxide, 20 to 50 mol % of a constituent unit derived from epihalohydrin, and 0 to 15 mol % of a constituent unit derived from allyl glycidyl ether; a vulcanizing agent; a plasticizer; and an acid acceptor, and a rubber formed product for air springs, which is obtained by vulcanization of the composition.

摘要翻译： 公开了一种用于空气弹簧的耐硫化橡胶组合物，其具有优异的低温性能，以及通过硫化橡胶组合物获得的用于空气弹簧的硫化橡胶成型产品。 还公开了一种用于空气弹簧的可硫化橡胶组合物，其包含：包含50-70mol％来自环氧乙烷和/或环氧丙烷的构成单元的表卤代醇基共聚物，20-50mol％的构成单元 衍生自表卤代醇，0〜15摩尔％的来自烯丙基缩水甘油醚的构成单元; 硫化剂; 增塑剂; 和酸受体，以及通过硫化组合物而获得的空气弹簧用橡胶成型体。

公开(公告)号：US4174341A

公开(公告)日：1979-11-13

申请号：US683678

申请日：1976-05-05

申请人： Yasuo Matoba ,  Yoshio Kise ,  Nobuo Yamada ,  Akira Hashimoto ,  Tetsuya Nakata

发明人： Yasuo Matoba ,  Yoshio Kise ,  Nobuo Yamada ,  Akira Hashimoto ,  Tetsuya Nakata

IPC分类号： C08L23/00 ,  C08K5/00 ,  C08K5/09 ,  C08K5/36 ,  C08K5/37 ,  C08K5/40 ,  C08K5/50 ,  C08K5/51 ,  C08K5/5399 ,  C08L1/00 ,  C08L27/00 ,  C08L101/00 ,  C08F114/04 ,  C08C19/20 ,  C08C19/22

CPC分类号： C08K5/00 ,  C08K5/5399

摘要： A cured or uncured chlorinated polyethylene composition comprising(A) chlorinated polyethylene,(B) a complex formed between hexamethylphosphoric triamide and a member selected from the group consisting of carboxylic acids, cyanuric acid, substituted or unsubstituted phenols, alcohols and metal salts, and(C) a member selected from the group consisting of (a) a mercaptotriazine, (b) a thiuram disulfide and (c) sulfur. And a process for curing chlorinated polyethylene, which comprises heating it in the presence of (B) and (C) at a temperature of about 100.degree. to about 200.degree. C.

摘要翻译： 固化或未固化的氯化聚乙烯组合物，其包含（A）氯化聚乙烯，（B）在六甲基磷酰三胺和选自羧酸，氰尿酸，取代或未取代的酚，醇和金属盐之间形成的配合物和（B） C）选自（a）巯基三嗪，（b）二硫化秋兰姆和（c）硫的成员。 和氯化聚乙烯的固化方法，其包括在（B）和（C）存在下，在约100℃至约200℃的温度下加热。