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公开(公告)号：US08187435B2
公开(公告)日：2012-05-29
申请号：US12186511
申请日：2008-08-05
申请人： Yi-Chang Du , Bang-Hao Wu , Li Duan Tsai , Hsiung Hsiao
发明人： Yi-Chang Du , Bang-Hao Wu , Li Duan Tsai , Hsiung Hsiao
IPC分类号： G01N27/26
CPC分类号： G01N27/301
摘要： The invention provides a reference electrode including a liquid electrolyte containing water, a water soluble organic compound with molecular size and boiling point are both greater than water, and an ionic salt; a solid crystal of the ionic salt in the liquid electrolyte; a metal/metal salt complex layer in contact with the liquid electrolyte; an leading wire connected to the metal/metal salt complex layer; an insulation case for containing the liquid electrolyte; and a nano-porous junction material embedded in the insulation case for contacting the liquid electrolyte, wherein a pore size of the nano-porous junction material is greater than a cation diameter of the ionic salt but smaller than a molecular length of the water soluble organic compound. The solid crystal of the ionic salt is the sediment of part of the ionic salt because the amount of the ionic salt is more than its solubility in the liquid electrolyte.
摘要翻译： 本发明提供一种参考电极，其包括含有水的液体电解质，分子大小和沸点的水溶性有机化合物均大于水和离子盐; 在液体电解质中的离子盐的固体晶体; 与液体电解质接触的金属/金属盐络合物层; 连接到金属/金属盐复合层的引线; 用于容纳液体电解质的绝缘壳体; 以及嵌入所述绝缘壳体中用于接触所述液体电解质的纳米多孔连接材料，其中所述纳米多孔连接材料的孔径大于所述离子盐的阳离子直径，但小于所述水溶性有机物的分子长度 复合。 离子盐的固体晶体是离子盐的一部分的沉淀物，因为离子盐的量大于其在液体电解质中的溶解度。
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公开(公告)号：US20090166198A1
公开(公告)日：2009-07-02
申请号：US12186511
申请日：2008-08-05
申请人： Yi-Chang Du , Bang-Hao Wu , Li Duan Tsai , Hsiung Hsiao
发明人： Yi-Chang Du , Bang-Hao Wu , Li Duan Tsai , Hsiung Hsiao
IPC分类号： G01N27/26
CPC分类号： G01N27/301
摘要： The invention provides a reference electrode including a liquid electrolyte containing water, a water soluble organic compound with molecular size and boiling point are both greater than water, and an ionic salt; a solid crystal of the ionic salt in the liquid electrolyte; a metal/metal salt complex layer in contact with the liquid electrolyte; an leading wire connected to the metal/metal salt complex layer; an insulation case for containing the liquid electrolyte; and a nano-porous junction material embedded in the insulation case for contacting the liquid electrolyte, wherein a pore size of the nano-porous junction material is greater than a cation diameter of the ionic salt but smaller than a molecular length of the water soluble organic compound. The solid crystal of the ionic salt is the sediment of part of the ionic salt because the amount of the ionic salt is more than its solubility in the liquid electrolyte.
摘要翻译： 本发明提供一种参考电极，其包括含有水的液体电解质，分子大小和沸点的水溶性有机化合物均大于水和离子盐; 在液体电解质中的离子盐的固体晶体; 与液体电解质接触的金属/金属盐络合物层; 连接到金属/金属盐复合层的引线; 用于容纳液体电解质的绝缘壳体; 以及嵌入所述绝缘壳体中用于接触所述液体电解质的纳米多孔连接材料，其中所述纳米多孔连接材料的孔径大于所述离子盐的阳离子直径，但小于所述水溶性有机物的分子长度 复合。 离子盐的固体晶体是离子盐的一部分的沉淀物，因为离子盐的量大于其在液体电解质中的溶解度。
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公开(公告)号：US06862170B2
公开(公告)日：2005-03-01
申请号：US10765941
申请日：2004-01-29
申请人： Li-Duan Tsai , Yi-Chang Du
发明人： Li-Duan Tsai , Yi-Chang Du
摘要： A solid-state electrolytic capacitor and its producing method are disclosed. First, a capacitor element containing conducting polymer as the electrolyte sucks non-conjugate polymer precursors solution and the polymeric precursor polymerizes and crosslinks. Therefore, the conducting polymer combines non-conjugate polymer into a kind of interpenetration or semi-interpenetration network polymer material. Finally complete the manufacture of the capacitor by sealing the capacitor, and conducting the age process.
摘要翻译： 公开了一种固态电解电容器及其制造方法。 首先，含有导电聚合物作为电解质的电容器元件吸收非共轭聚合物前体溶液，并且聚合物前体聚合和交联。 因此，导电聚合物将非共轭聚合物结合成一种互穿或半互穿网状聚合物材料。 最后通过密封电容器完成电容器的制造，并进行老化过程。
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4.发明授权Oxidizing agent useful for oxidative polymerization of high conductive polymers 有权可用于高导电聚合物氧化聚合的氧化剂公开(公告)号：US09156923B2
公开(公告)日：2015-10-13
申请号：US12588323
申请日：2009-10-13
申请人： Li-Duan Tsai , Yi-Chang Du
发明人： Li-Duan Tsai , Yi-Chang Du
摘要： An oxidizing agent useful for oxidative polymerization of high conductive polymers is provided. This oxidizing agent is a kind of organic metal complex formed of metal ion salts having oxidizing capability and nitrogen-containing compound having lone pair electrons with partial π-electron character. This organic metal complex has weak oxidizing strength for monomers at room temperature. As such, a mixture of the organic metal complex and the monomers has long-term stability under room temperature. While, at a high temperature, the organic metal complex provides proper oxidative polymerization capability for the monomers. The conductive polymers synthesized by the organic metal complex have excellent conductivity.
摘要翻译： 提供了可用于高导电聚合物的氧化聚合的氧化剂。 该氧化剂是由具有氧化能力的金属离子盐和具有部分和电子特性的具有孤对电子的含氮化合物形成的一种有机金属络合物。 该有机金属络合物在室温下对单体的氧化强度弱。 因此，有机金属络合物和单体的混合物在室温下具有长期的稳定性。 而在高温下，有机金属络合物为单体提供适当的氧化聚合能力。 由有机金属络合物合成的导电聚合物具有优异的导电性。
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5.发明申请Oxidizing agent useful for oxidative polymerization of high conductive polymers 有权可用于高导电聚合物氧化聚合的氧化剂公开(公告)号：US20100099889A1
公开(公告)日：2010-04-22
申请号：US12588323
申请日：2009-10-13
申请人： Li-Duan Tsai , Yi-Chang Du
发明人： Li-Duan Tsai , Yi-Chang Du
IPC分类号： C07F15/00
摘要： An oxidizing agent useful for oxidative polymerization of high conductive polymers is provided. This oxidizing agent is a kind of organic metal complex formed of metal ion salts having oxidizing capability and nitrogen-containing compound having lone pair electrons with partial π-electron character. This organic metal complex has weak oxidizing strength for monomers at room temperature. As such, a mixture of the organic metal complex and the monomers has long-term stability under room temperature. While, at a high temperature, the organic metal complex provides proper oxidative polymerization capability for the monomers. The conductive polymers synthesized by the organic metal complex have excellent conductivity.
摘要翻译： 提供了可用于高导电聚合物的氧化聚合的氧化剂。 该氧化剂是由具有氧化能力的金属离子盐和具有部分和电子特性的具有孤对电子的含氮化合物形成的一种有机金属络合物。 该有机金属络合物在室温下对单体的氧化强度弱。 因此，有机金属络合物和单体的混合物在室温下具有长期的稳定性。 而在高温下，有机金属络合物为单体提供适当的氧化聚合能力。 由有机金属络合物合成的导电聚合物具有优异的导电性。
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6.发明申请Oxidizing agent useful for oxidative polymerization of high conductive polymers 审中-公开可用于高导电聚合物氧化聚合的氧化剂公开(公告)号：US20070096055A1
公开(公告)日：2007-05-03
申请号：US11384368
申请日：2006-03-21
申请人： Li-Duan Tsai , Yi-Chang Du
发明人： Li-Duan Tsai , Yi-Chang Du
IPC分类号： C11D3/39
摘要： An oxidizing agent useful for oxidative polymerization of high conductive polymers is provided. This oxidizing agent is a kind of organic metal complex formed of metal ion salts having oxidizing capability and nitrogen-containing compound having lone pair electrons with partial π-electron character. This organic metal complex has weak oxidizing strength for monomers at room temperature. As such, a mixture of the organic metal complex and the monomers has long-term stability under room temperature. While, at a high temperature, the organic metal complex provides proper oxidative polymerization capability for the monomers. The conductive polymers synthesized by the organic metal complex have excellent conductivity.
摘要翻译： 提供了可用于高导电聚合物的氧化聚合的氧化剂。 该氧化剂是由具有氧化能力的金属离子盐和具有部分π型电子特性的单对电子的含氮化合物形成的一种有机金属络合物。 该有机金属络合物在室温下对单体的氧化强度弱。 因此，有机金属络合物和单体的混合物在室温下具有长期的稳定性。 而在高温下，有机金属络合物为单体提供适当的氧化聚合能力。 由有机金属络合物合成的导电聚合物具有优异的导电性。
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7.发明授权Mixture solution for preparing a conductive polymer to produce solid electrolytic capacitors and its method 有权用于制备导电聚合物以制备固体电解电容器的混合溶液及其方法公开(公告)号：US07208104B2
公开(公告)日：2007-04-24
申请号：US10712045
申请日：2003-11-14
申请人： Li-Duan Tsai , Yi-Chang Du
发明人： Li-Duan Tsai , Yi-Chang Du
CPC分类号： H01G9/028 , C08F22/105 , C08F283/00 , C08G59/18 , C08G59/24 , C08G61/123 , C08G61/126 , C08L63/00 , G03F7/0045 , G03F7/027 , G03F7/031 , G03F7/038 , G03F7/0388 , H01G9/038 , H01G9/058 , H01G11/48 , H01G11/56 , H01M2300/0085 , Y02E60/13 , Y10T29/417 , Y10T428/31511 , C08F222/1006 , C08L2666/04
摘要： A mixture solution for preparing conducting polymers. The conducting polymer is formed from a mixture of monomer and oxidant solution. The oxidant solution has a high concentration, and also includes a five or six-member ring compound with a functional group which acts as a retardant for the polymerization. Thus, the mixture of a monomer and oxidant solution exhibits excellent stability at room temperature. The conducting polymer accumulating in the space of the capacitor element can be more efficiently formed by using this high concentration oxidant solution. Therefore, the immersion and polymerization processes to form conducting polymer as the electrolyte of a solid electrolytic capacitor can be limited to only a few occurrences.
摘要翻译： 用于制备导电聚合物的混合溶液。 导电聚合物由单体和氧化剂溶液的混合物形成。 氧化剂溶液具有高浓度，并且还包括具有作为聚合阻聚剂的官能团的五元或六元环化合物。 因此，单体和氧化剂溶液的混合物在室温下表现出优异的稳定性。 通过使用该高浓度氧化剂溶液，可以更有效地形成积聚在电容器元件的空间的导电性聚合物。 因此，形成作为固体电解电容器的电解质的导电性聚合物的浸渍和聚合方法仅限于少数情况。
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