摘要:
The present invention provides a charge storage device, comprising a pair of electrodes, each electrode being operable to store electric charge and having a respective capacitance CP, CN that is different to the other, with the ratio of the capacitances CP/CN being greater than 1. In exemplary embodiments, the charge storage device may be an asymmetrical supercapacitor, which is operable to provide an enhanced energy capacity by increasing the cell voltage through unequalising the electrode capacitance. Hence, by increasing the CP/CN ratio an improved power capability can be achieved over conventional devices, while offering a simple and low cost manufacturing strategy. The present invention has particular application with cameras, electric vehicles, elevators, renewable energy stores, fuel cells, batteries and many forms of electronic devices.
摘要:
The present invention relates to a power storage device including: a positive electrode having a positive-electrode current collector, a positive-electrode active material with a plurality of first projections on the positive-electrode current collector, and a first insulator on an end of each of the plurality of first projections; a negative electrode having a negative-electrode current collector, a negative-electrode active material with a plurality of second projections on a surface of the negative-electrode current collector, and a second insulator on an end of each of the plurality of second projections; a separator between the positive electrode and the negative electrode; and an electrolyte provided in a space between the positive electrode and the negative electrode and containing carrier ions. In each of the first projections and the second projections, a ratio of the height to the width is 3 or more and 1000 or less to 1, i.e. (3 to 1000):1.
摘要:
Multilayer carbon nanotube capacitors, and methods and printable compositions for manufacturing multilayer carbon nanotubes (CNTs) are disclosed. A first capacitor embodiment comprises: a first conductor; a plurality of fixed CNTs in an ionic liquid, each fixed CNT comprising a magnetic catalyst nanoparticle coupled to a carbon nanotube and further coupled to the first conductor; and a first plurality of free CNTs dispersed and moveable in the ionic liquid. Another capacitor embodiment comprises: a first conductor; a conductive nanomesh coupled to the first conductor; a first plurality of fixed CNTs in an ionic liquid and further coupled to the conductive nanomesh; and a plurality of free CNTs dispersed and moveable in the ionic liquid. Various methods of printing the CNTs and other structures, and methods of aligning and moving the CNTs using applied electric and magnetic fields, are also disclosed.
摘要:
Disclosed is an accumulator device that can prevent aluminum forming an outer container from forming an alloy with lithium even when fine lithium metal powder is isolated from a lithium ion supply source to adhere to the outer container.The accumulator device has an outer container at least a part of which is formed of aluminum or an aluminum alloy, a positive electrode and a negative electrode that are arranged in the outer container, and an electrolytic solution injected into the outer container and containing a lithium salt, wherein the negative electrode and/or the positive electrode is doped with a lithium ion by electrochemical contact of a lithium ion supply source arranged in the outer container with the negative electrode and/or the positive electrode, and the portion formed of aluminum or the aluminum alloy in the outer container is set to a positive potential.
摘要:
A specific embodiment of the present invention is a process for continuously producing a porous solid film of spacer-modified nano graphene platelets for supercapacitor electrode applications. This process comprises: (a) dissolving a precursor material in a solvent to form a precursor solution and dispersing multiple nano graphene platelets into the solution to form a suspension; (b) continuously delivering and forming the suspension into a layer of solid film composed of precursor material-coated graphene platelets overlapping one another, and removing the solvent from the solid film (e.g., analogous to a paper-making, mat-making, or web-making procedure); (c) continuously converting the precursor material into nodules bonded to surfaces of graphene platelets to form a porous solid film composed of spacer-modified graphene platelets; and (d) continuously collecting the porous solid film on a collector (e.g., a winding roller). The roll of porous solid film (mat, paper, or web) can then be cut into pieces for used as supercapacitor electrodes.
摘要:
Capacitors containing novel electrodes and electrolytes are described. One electrode composition comprises an oxide of Mn and Fe in a Mn:Fe molar ratio of 3:1 to 5:1. Another electrode composition comprises an oxide comprising Ni, Co, and Fe; wherein the Ni and Co are present in a Ni/Co molar ratio in the range of 0.5 to 2 and a Fe and Ni are present in a Ni/Fe molar ratio in the range of 1.0 to 10. The resulting capacitors can be characterized by superior properties. Methods of forming the electrodes from gels are also described. An electrolyte comprising a Li salt in a carbonate solution, wherein the carbonate solution comprises 10-30% ethylene carbonate and 70-90% propylene carbonate is also described.
摘要:
The invention relates to a module comprising at least two electrical energy storage assemblies (20), each storage assembly (20) comprising a first face topped by a cover (30) electrically connected to said energy storage assembly (20) and a second face opposite the first face, each cover being in contact with a respective end of a strip (40) in order to electrically connect the two storage assemblies (20), in which the strip (40) and the faces of the covers (30) in contact with the strip (40) are flat, the strip (40) being welded to the faces of the covers (30) along weld leads (50, 50′).
摘要:
The present invention discloses a method of synthesizing transition metal nitride by using supercritical ammonia. Transition metal nitride such as vanadium nitride, molybdenum nitride, titanium nitride, nickel nitride, neodymium nitride, iron nitride, etc. can be synthesized in supercritical ammonia with reducing mineralizers such as potassium, sodium, lithium, magnesium, calcium, and aluminum. Since supercritical ammonia has characteristics of both gas and liquid, it can over complicated fine structure or fine particles. The new method is suitable for forming a protective coating on complicated structure or forming micro- to nano-sized particles.
摘要:
Multilayer carbon nanotube capacitors, and methods and printable compositions for manufacturing multilayer carbon nanotubes (CNTs) are disclosed. A first capacitor embodiment comprises: a first conductor; a plurality of fixed CNTs in an ionic liquid, each fixed CNT comprising a magnetic catalyst nanoparticle coupled to a carbon nanotube and further coupled to the first conductor; and a first plurality of free CNTs dispersed and moveable in the ionic liquid. Another capacitor embodiment comprises: a first conductor; a conductive nanomesh coupled to the first conductor; a first plurality of fixed CNTs in an ionic liquid and further coupled to the conductive nanomesh; and a plurality of free CNTs dispersed and moveable in the ionic liquid. Various methods of printing the CNTs and other structures, and methods of aligning and moving the CNTs using applied electric and magnetic fields, are also disclosed.
摘要:
An electrical double-layer capacitor electrode with excellent capacitance characteristics is obtained together with a manufacturing method therefor. Paper-molded sheet of carbon nanotubes is integrated with etched foil constituting a collector, by means of bumps and indentations formed on the surface of etched foil to prepare an electrical double-layer capacitor electrode. Alternatively, carbon nanotubes grown around core catalyst particles on substrate are integrated with etched foil by means of humps and indentations formed on the surface of etched foil to prepare all electrical double-layer capacitor electrode. To manufacture these electrodes, this carbon nanotube sheet or substrate with carbon nanotubes grown thereon is laid over bumps and indentations on the surface of etched foil, and the sheet or substrate and the foil are pressed under 0.01 to 100 t/cm2 of pressure to integrate the carbon nanotubes with the etched foil.
摘要翻译:获得具有优异的电容特性的电双层电容器电极及其制造方法。 通过形成在蚀刻箔的表面上的凸起和凹陷,将碳纳米管的纸模成型片与构成集电体的蚀刻箔一体化,以制备双电层电容器电极。 或者,通过在蚀刻箔的表面上形成的凸起和凹陷将蚀刻的箔与蚀刻箔结合在基板上的核心催化剂颗粒周围生长的碳纳米管,以制备所有双电层电容器电极。 为了制造这些电极,将碳纳米管片或其上生长有碳纳米管的基板放置在蚀刻箔的表面上的凸起和凹陷上,并将片或基片和箔压制在0.01至100t / cm 2的压力下以整合 具有蚀刻箔的碳纳米管。