公开(公告)号：US20060145123A1

公开(公告)日：2006-07-06

申请号：US11269953

申请日：2005-11-08

申请人： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

发明人： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

IPC分类号： H01L33/00 ,  C09K11/08

CPC分类号： C09K11/7734 ,  C09K11/7737 ,  H01L33/502

摘要： Novel green phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A1)x(Si,A2)(O,A3)2+x:Eu2+, where A1 is at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+ cations; A2 is a 3+, 4+, or 5+ cation, including at least one of B, Al, Ga, C, Ge, N, and P; A3 is a 1−, 2−, or 3− anion, including F, Cl, Br, and S; and x is any value between 1.5 and 2.5, both inclusive. The formula is written to indicate that the A1 cation replaces Sr; the A2 cation replaces Si, and the A3 anion replaces O. These green phosphors are configured to emit visible light having a peak emission wavelength greater than about 480 nm. They have applications in green illumination systems, red-green-blue backlighting systems, white LEDs, and plasma display panels (PDPs).

摘要翻译： 公开了新的绿色荧光体，其具有包含具有式（Sr，A 1 H 2）x Si（Si，Al 2）的硅酸盐基化合物 O，A 3 + 2 + x 2：Eu 2+，其中A 1至少是一个二价阳离子 （2+离子），包括Mg，Ca，Ba或Zn，或1+和3+阳离子的组合; A 2是3+，4+或5+阳离子，包括B，Al，Ga，C，Ge，N和P中的至少一种; A 3是1-，2-或3-阴离子，包括F，Cl，Br和S; x是1.5到2.5之间的任何值，包括两者之间的值。 该公式被写为表示A 1阳离子取代Sr; A 2阳离子取代Si，并且A 3 N阴离子取代O.这些绿色磷光体被配置为发射具有大于约480nm的峰值发射波长的可见光。 它们在绿色照明系统，红绿蓝色背光系统，白色LED和等离子显示面板（PDP）中都有应用。

公开(公告)号：US07922937B2

公开(公告)日：2011-04-12

申请号：US12574544

申请日：2009-10-06

申请人： Yi-Qun Li ,  Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Ning Wang

发明人： Yi-Qun Li ,  Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Ning Wang

IPC分类号： C09K11/59 ,  C09K11/55

CPC分类号： C09K11/7734 ,  H01J61/35 ,  H01L33/502 ,  H01L2924/0002 ,  H01L2924/00

摘要： Novel two-phase yellow phosphors are disclosed having a peak emission intensity at wavelengths ranging from about 555 nm to about 580 nm when excited by a radiation source having a wavelength ranging from 220 nm to 530 nm. The present phosphors may be represented by the formula a[Srx(M1)1-x]zSiO4.(1-a)[Sry(M2)1-y]uSiO5:Eu2+D, wherein M1 and M2 are at least one of a divalent metal such as Ba, Mg, Ca, and Zn, the values of a, x, y, z and u follow the following relationships: 0.6≦a≦0.85; 0.3≦x≦0.6; 0.85≦y≦1; 1.5≦z≦2.5; 2.6≦u≦3.3; and Eu and D each range from 0.001 to about 0.5. D is an anion selected from the group consisting of F, Cl, Br, S, and N, and at least some of the D anion replaces oxygen in the host silicate lattice of the phosphor. The present yellow phosphors have applications in high brightness white LED illumination systems, LCD display panels, plasma display panels, and yellow LEDs and illumination systems.

摘要翻译： 公开了当波长范围为220nm至530nm的辐射源激发时，波长范围为约555nm至约580nm的峰值发射强度的新型二相黄色荧光体。 本发明的荧光体可以由式a [Srx（M1）1-x] zSiO4（1-a）[Sry（M2）1-y] uSiO5：Eu2 + D表示，其中M1和M2是 a，x，y，z和u的二价金属如Ba，Mg，Ca和Zn的关系如下：0.6＆nlE; a＆nlE; 0.85; 0.3＆nlE; x＆nlE; 0.6; 0.85＆nlE; y＆nlE; 1; 1.5＆nlE; z＆nlE; 2.5; 2.6＆nlE; u＆nlE; 3.3; 并且Eu和D各自为0.001至约0.5。 D是选自F，Cl，Br，S和N的阴离子，并且D阴离子中的至少一些取代荧光体的主体硅酸盐晶格中的氧。 目前的黄色荧光粉可用于高亮度白光LED照明系统，液晶显示面板，等离子显示面板以及黄色LED和照明系统。

公开(公告)号：US20100019202A1

公开(公告)日：2010-01-28

申请号：US12574544

申请日：2009-10-06

申请人： Yi-Qun Li ,  Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Ning Wang

发明人： Yi-Qun Li ,  Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Ning Wang

IPC分类号： C09K11/59

CPC分类号： C09K11/7734 ,  H01J61/35 ,  H01L33/502 ,  H01L2924/0002 ,  H01L2924/00

摘要： Novel two-phase yellow phosphors are disclosed having a peak emission intensity at wavelengths ranging from about 555 nm to about 580 nm when excited by a radiation source having a wavelength ranging from 220 nm to 530 nm. The present phosphors may be represented by the formula a[Srx(M1)1-x]zSiO4.(1-a)[Sry(M2)1-y]uSiO5:Eu2+D, wherein M1 and M2 are at least one of a divalent metal such as Ba, Mg, Ca, and Zn, the values of a, x, y, z and u follow the following relationships: 0.6≦a≦0.85; 0.3≦x≦0.6; 0.85≦y≦1; 1.5≦z≦2.5; 2.6≦u≦3.3; and Eu and D each range from 0.001 to about 0.5. D is an anion selected from the group consisting of F, Cl, Br, S, and N, and at least some of the D anion replaces oxygen in the host silicate lattice of the phosphor. The present yellow phosphors have applications in high brightness white LED illumination systems, LCD display panels, plasma display panels, and yellow LEDs and illumination systems.

摘要翻译： 公开了当波长范围为220nm至530nm的辐射源激发时，波长范围为约555nm至约580nm的峰值发射强度的新型二相黄色荧光体。 本发明的荧光体可以由式a [Srx（M1）1-x] zSiO4（1-a）[Sry（M2）1-y] uSiO5：Eu2 + D表示，其中M1和M2是 二价金属如Ba，Mg，Ca和Zn，a，x，y，z和u的值遵循以下关系：0.6 <= a <= 0.85; 0.3 <= x <= 0.6; 0.85 <= y <= 1; 1.5 <= z <= 2.5; 2.6 <= u <= 3.3; 并且Eu和D各自为0.001至约0.5。 D是选自F，Cl，Br，S和N的阴离子，并且D阴离子中的至少一些取代荧光体的主体硅酸盐晶格中的氧。 目前的黄色荧光粉可用于高亮度白光LED照明系统，液晶显示面板，等离子显示面板以及黄色LED和照明系统。

公开(公告)号：US07601276B2

公开(公告)日：2009-10-13

申请号：US11417690

申请日：2006-05-03

申请人： Yi-Qun Li ,  Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Ning Wang

发明人： Yi-Qun Li ,  Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Ning Wang

IPC分类号： C09K11/55 ,  C09K11/59

CPC分类号： C09K11/7734 ,  H01J61/35 ,  H01L33/502 ,  H01L2924/0002 ,  H01L2924/00

摘要： Novel two-phase yellow phosphors are disclosed having a peak emission intensity at wavelengths ranging from about 555 nm to about 580 nm when excited by a radiation source having a wavelength ranging from 220 nm to 530 nm. The present phosphors may be represented by the formula a[Srx(M1)1−x]zSiO4.(1-a)[Sry(M2)1−y]uSiO5:Eu2+D, wherein M1 and M2 are at least one of a divalent metal such as Ba, Mg, Ca, and Zn, the values of a, x, y, z and u follow the following relationships: 0.6≦a≦0.85; 0.3≦x≦0.6; 0.85≦y≦1; 1.5≦z≦2.5; 2.6≦u≦3.3; and Eu and D each range from 0.001 to about 0.5. D is an anion selected from the group consisting of F, Cl, Br, S, and N, and at least some of the D anion replaces oxygen in the host silicate lattice of the phosphor. The present yellow phosphors have applications in high brightness white LED illumination systems, LCD display panels, plasma display panels, and yellow LEDs and illumination systems.

摘要翻译： 公开了当波长范围为220nm至530nm的辐射源激发时，波长范围为约555nm至约580nm的峰值发射强度的新型二相黄色荧光体。 本发明的荧光体可以由式a [Srx（M1）1-x] zSiO4（1-a）[Sry（M2）1-y] uSiO5：Eu2 + D表示，其中M1和M2是 二价金属如Ba，Mg，Ca和Zn，a，x，y，z和u的值遵循以下关系：0.6 <= a <= 0.85; 0.3 <= x <= 0.6; 0.85 <= y <= 1; 1.5 <= z <= 2.5; 2.6 <= u <= 3.3; 并且Eu和D各自为0.001至约0.5。 D是选自F，Cl，Br，S和N的阴离子，并且D阴离子中的至少一些取代荧光体的主体硅酸盐晶格中的氧。 目前的黄色荧光粉可应用于高亮度白光LED照明系统，液晶显示面板，等离子显示面板以及黄色LED和照明系统。

公开(公告)号：US20060261309A1

公开(公告)日：2006-11-23

申请号：US11417690

申请日：2006-05-03

申请人： Yi-Qun Li ,  Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Ning Wang

发明人： Yi-Qun Li ,  Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Ning Wang

IPC分类号： H01L33/00 ,  C09K11/54 ,  H01K11/00

CPC分类号： C09K11/7734 ,  H01J61/35 ,  H01L33/502 ,  H01L2924/0002 ,  H01L2924/00

摘要： Novel two-phase yellow phosphors are disclosed having a peak emission intensity at wavelengths ranging from about 555 nm to about 580 nm when excited by a radiation source having a wavelength ranging from 220 nm to 530 nm. The present phosphors may be represented by the formula a[Srx(M1)1-x]zSiO4●(1-a)[Sry(M2)1-y]uSiO5:Eu2+D, wherein M1 and M2 are at least one of a divalent metal such as Ba, Mg, Ca, and Zn, the values of a, x, y, z and u follow the following relationships: 0.6≦a≦0.85; 0.3≦x≦0.6; 0.85≦y≦1; 1.5≦z≦2.5; 2.6≦u≦3.3; and Eu and D each range from 0.001 to about 0.5. D is an anion selected from the group consisting of F, Cl, Br, S, and N, and at least some of the D anion replaces oxygen in the host silicate lattice of the phosphor. The present yellow phosphors have applications in high brightness white LED illumination systems, LCD display panels, plasma display panels, and yellow LEDs and illumination systems.

摘要翻译： 公开了当波长范围为220nm至530nm的辐射源激发时，波长范围为约555nm至约580nm的峰值发射强度的新型二相黄色荧光体。 本发明的荧光体可以由式a [Sr x 1（M 1）1-x N z SiO 2 S / >（1-a）[Sr y y（（（u u Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu Eu 2 + D，其中M1和M2是二价金属如Ba，Mg，Ca和Zn中的至少一种，a，x，y，z和u的值遵循以下关系 ：0.6 <= a <= 0.85; 0.3 <= x <= 0.6; 0.85 <= y <= 1; 1.5 <= z <= 2.5; 2.6 <= u <= 3.3; 并且Eu和D各自为0.001至约0.5。 D是选自F，Cl，Br，S和N的阴离子，并且D阴离子中的至少一些取代荧光体的主体硅酸盐晶格中的氧。 目前的黄色荧光粉可用于高亮度白光LED照明系统，液晶显示面板，等离子显示面板以及黄色LED和照明系统。

公开(公告)号：US07906041B2

公开(公告)日：2011-03-15

申请号：US12542164

申请日：2009-08-17

申请人： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

发明人： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

IPC分类号： H01L33/00

CPC分类号： C09K11/7734 ,  C09K11/7737 ,  H01L33/502

摘要： Novel green phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A1)x(Si,A2)(O,A3)2+x:Eu2+, where A1 is at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+ cations; A2 is a 3+, 4+, or 5+ cation, including at least one of B, Al, Ga, C, Ge, N, and P; A3 is a 1−, 2−, or 3− anion, including F, Cl, Br, and S; and x is any value between 1.5 and 2.5, both inclusive. The formula is written to indicate that the A1 cation replaces Sr; the A2 cation replaces Si, and the A3 anion replaces O. These green phosphors are configured to emit visible light having a peak emission wavelength greater than about 480 nm. They have applications in green illumination systems, red-green-blue backlighting systems, white LEDs, and plasma display panels (PDPs).

摘要翻译： 公开了新的绿色荧光体，其包含具有式（Sr，Al）x（Si，A2）（O，A3）2 + x：Eu 2+）的硅酸盐基化合物，其中A1是至少一个二价阳离子 ），包括Mg，Ca，Ba或Zn，或1+和3+阳离子的组合; A2是3+，4+或5+阳离子，包括B，Al，Ga，C，Ge，N和P中的至少一种; A3是1-，2-或3-阴离子，包括F，Cl，Br和S; x是1.5到2.5之间的任何值，包括两者之间的值。 公式写成表明A1阳离子取代Sr; A2阳离子取代Si，并且A3阴离子取代O.这些绿色磷光体被配置为发射具有大于约480nm的峰值发射波长的可见光。 它们在绿色照明系统，红绿蓝色背光系统，白色LED和等离子显示面板（PDP）中都有应用。

公开(公告)号：US20090294731A1

公开(公告)日：2009-12-03

申请号：US12542164

申请日：2009-08-17

申请人： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

发明人： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

IPC分类号： C09K11/08

CPC分类号： C09K11/7734 ,  C09K11/7737 ,  H01L33/502

摘要： Novel green phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A1)x(Si,A2)(O,A3)2+x:Eu2+, where A1 is at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+cations; A2 is a 3+, 4+, or 5+cation, including at least one of B, Al, Ga, C, Ge, N, and P; A3 is a 1-, 2-, or 3-anion, including F, Cl, Br, and S; and x is any value between 1.5 and 2.5, both inclusive. The formula is written to indicate that the A1 cation replaces Sr; the A2 cation replaces Si, and the A3 anion replaces O. These green phosphors are configured to emit visible light having a peak emission wavelength greater than about 480 nm. They have applications in green illumination systems, red-green-blue backlighting systems, white LEDs, and plasma display panels (PDPs).

摘要翻译： 公开了新的绿色荧光体，其包含具有式（Sr，Al）x（Si，A2）（O，A3）2 + x：Eu 2+）的硅酸盐基化合物，其中A1是至少一个二价阳离子 ），包括Mg，Ca，Ba或Zn，或1+ + 3 +阳离子的组合; A2是3+，4+或5 +阳离子，包括B，Al，Ga，C，Ge，N和P中的至少一种; A3是1-，2-或3-阴离子，包括F，Cl，Br和S; x是1.5到2.5之间的任何值，包括两者之间的值。 公式写成表明A1阳离子取代Sr; A2阳离子取代Si，并且A3阴离子取代O.这些绿色磷光体被配置为发射具有大于约480nm的峰值发射波长的可见光。 它们在绿色照明系统，红绿蓝色背光系统，白色LED和等离子显示面板（PDP）中都有应用。

公开(公告)号：US07575697B2

公开(公告)日：2009-08-18

申请号：US11269953

申请日：2005-11-08

申请人： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

发明人： Yi-Qun Li ,  Yi Dong ,  Dejie Tao ,  Shifan Cheng ,  Ning Wang

IPC分类号： C09K11/59 ,  C09K11/55 ,  H01L51/54 ,  H01J17/49

CPC分类号： C09K11/7734 ,  C09K11/7737 ,  H01L33/502

摘要： Novel green phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A1)x(Si,A2)(O,A3)2+x:Eu2+, where A1 is at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+ cations; A2 is a 3+, 4+, or 5+ cation, including at least one of B, Al, Ga, C, Ge, N, and P; A3 is a 1−, 2−, or 3− anion, including F, Cl, Br, and S; and x is any value between 1.5 and 2.5, both inclusive. The formula is written to indicate that the A1 cation replaces Sr; the A2 cation replaces Si, and the A3 anion replaces O. These green phosphors are configured to emit visible light having a peak emission wavelength greater than about 480 nm. They have applications in green illumination systems, red-green-blue backlighting systems, white LEDs, and plasma display panels (PDPs).

摘要翻译： 公开了新的绿色荧光体，其包含具有式（Sr，Al）x（Si，A2）（O，A3）2 + x：Eu 2+）的硅酸盐基化合物，其中A1是至少一个二价阳离子 ），包括Mg，Ca，Ba或Zn，或1+和3+阳离子的组合; A2是3+，4+或5+阳离子，包括B，Al，Ga，C，Ge，N和P中的至少一种; A3是1-，2-或3-阴离子，包括F，Cl，Br和S; x是1.5到2.5之间的任何值，包括两者之间的值。 公式写成表明A1阳离子取代Sr; A2阳离子取代Si，并且A3阴离子取代O.这些绿色磷光体被配置为发射具有大于约480nm的峰值发射波长的可见光。 它们在绿色照明系统，红绿蓝色背光系统，白色LED和等离子显示面板（PDP）中都有应用。

公开(公告)号：US09550162B2

公开(公告)日：2017-01-24

申请号：US11231309

申请日：2005-09-19

申请人： Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Yi-Qun Li

发明人： Yi Dong ,  Shifan Cheng ,  Dejie Tao ,  Yi-Qun Li

IPC分类号： B01J19/00

CPC分类号： B01J19/0046 ,  B01J2219/00315 ,  B01J2219/00364 ,  B01J2219/00369 ,  B01J2219/00387 ,  B01J2219/00477 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/005 ,  B01J2219/00527 ,  B01J2219/00572 ,  B01J2219/00585 ,  B01J2219/00596 ,  B01J2219/00605 ,  B01J2219/0061 ,  B01J2219/00612 ,  B01J2219/00619 ,  B01J2219/00621 ,  B01J2219/00628 ,  B01J2219/00659 ,  B01J2219/00704 ,  B01J2219/00736 ,  B01J2219/0075 ,  B01J2219/00754

摘要： This invention provides methods and systems to prepare replicate arrays from master arrays of liquid solutions. Replicate arrays of liquid solutions can be reacted to form product solid inorganic material arrays for analysis and selection of optimum processes and products with desirable properties.

摘要翻译： 本发明提供从液体溶液的主阵列制备复制阵列的方法和系统。 液体溶液的复制阵列可以反应形成产品固体无机材料阵列，用于分析和选择具有所需性能的最佳工艺和产品。

公开(公告)号：US07655156B2

公开(公告)日：2010-02-02

申请号：US11258679

申请日：2005-10-25

申请人： Shifan Cheng ,  Dejie Tao ,  Yi Dong ,  Yi-Qun Li

发明人： Shifan Cheng ,  Dejie Tao ,  Yi Dong ,  Yi-Qun Li

IPC分类号： C09K11/59 ,  C09K11/55 ,  C09K11/61 ,  H01L33/00

CPC分类号： C09K11/7734 ,  H01L33/502

摘要： Novel orange phosphors are disclosed having the comprise silicate-based compounds having the formula (Sr,A1)x,(Si,A2)(O,A3)2+x:Eu2+, where A1 is at least one divalent cation (a 2+ ion) including Mg, Ca, Ba, or Zn, or a combination of 1+ and 3+ cations; A2 is a 3+, 4+, or 5+ cation, including at least one of B, Al, Ga, C, Ge, P; A3 is a 1−, 2−, or 3− anion, including F, Cl, and Br; and x is any value between 2.5 and 3.5, inclusive. The formula is written to indicate that the A1 cation replaces Sr; the A2 cation replaces Si, and the A3 anion replaces O. These orange phosphors are configured to emit visible light having a peak emission wavelength greater than about 565 nm. They have applications in white LED illumination systems, plasma display panels, and in orange and other colored LED systems.

摘要翻译： 公开了具有式（Sr，Al）x，（Si，A2）（O，A3）2 + x：Eu2 +的硅酸盐基化合物的新型橙色荧光体，其中A1是至少一种二价阳离子 离子），包括Mg，Ca，Ba或Zn，或1+和3+阳离子的组合; A2是3+，4+或5+阳离子，包括B，Al，Ga，C，Ge，P中的至少一种; A3是1-，2-或3-阴离子，包括F，Cl和Br; x是2.5到3.5之间的任何值。 公式写成表明A1阳离子取代Sr; A2阳离子取代Si，并且A3阴离子取代O.这些橙色荧光体被配置为发射具有大于约565nm的峰值发射波长的可见光。 它们在白光LED照明系统，等离子显示面板以及橙色和其他彩色LED系统中都有应用。