公开(公告)号：US20050165121A1

公开(公告)日：2005-07-28

申请号：US10766297

申请日：2004-01-28

申请人： Yong Wang ,  Anna Tonkovich ,  Terry Mazanec ,  Francis Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Tonkovich ,  Terry Mazanec ,  Francis Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： B01J19/00 ,  B01J19/24 ,  B01J21/04 ,  B01J23/75 ,  B01J23/889 ,  B01J23/89 ,  B01J35/10 ,  B01J37/02 ,  C10G2/00 ,  C07C27/26

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2 CO和CO的反应物组合物转化成包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物通过 与费 - 托催化剂接触以将反应物组合物转化成产物的微通道反应器，该微通道反应器包含多个含有该催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US20060251552A1

公开(公告)日：2006-11-09

申请号：US11484069

申请日：2006-07-11

申请人： Yong Wang ,  Anna Tonkovich ,  Terry Mazanec ,  Francis Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Tonkovich ,  Terry Mazanec ,  Francis Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： B01J8/04 ,  C07C27/06

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2 CO和CO的反应物组合物转化成包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物通过 与费 - 托催化剂接触以将反应物组合物转化成产物的微通道反应器，该微通道反应器包含多个含有该催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US09023900B2

公开(公告)日：2015-05-05

申请号：US13397942

申请日：2012-02-16

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C10G2/00 ,  C07C1/04 ,  B01J19/00 ,  B01J37/03 ,  B01J38/48 ,  B01J23/94 ,  B01J37/02 ,  B01J23/755 ,  B01J23/83 ,  B01J23/889 ,  B01J23/89 ,  B01J35/00 ,  B01J35/04 ,  B01J35/10 ,  C10G45/58 ,  C10G47/00 ,  B01J23/75 ,  B01J21/04 ,  B01J38/58

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/8896 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/894 ,  B01J23/8986 ,  B01J23/94 ,  B01J35/0066 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/038 ,  B01J38/48 ,  B01J38/58 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00855 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/331 ,  C10G2/334 ,  C10G2/34 ,  C10G2/341 ,  C10G21/00 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2400/04 ,  C10G2400/10 ,  C10L1/08 ,  C10L2200/0492 ,  C10L2270/026 ,  C10L2290/42 ,  C10L2290/544 ,  C10M105/04 ,  Y02P20/582

摘要： Disclosed is a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. Also disclosed is a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 公开了一种将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与费 - 托催化剂接触的微通道反应器 将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 还公开了包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US20130217793A1

公开(公告)日：2013-08-22

申请号：US13397942

申请日：2012-02-16

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C1/04 ,  B01J23/75 ,  B01J21/04

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/8896 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/894 ,  B01J23/8986 ,  B01J23/94 ,  B01J35/0066 ,  B01J35/04 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/038 ,  B01J38/48 ,  B01J38/58 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00855 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/331 ,  C10G2/334 ,  C10G2/34 ,  C10G2/341 ,  C10G21/00 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1022 ,  C10G2400/04 ,  C10G2400/10 ,  C10L1/08 ,  C10L2200/0492 ,  C10L2270/026 ,  C10L2290/42 ,  C10L2290/544 ,  C10M105/04 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

公开(公告)号：US07722833B2

公开(公告)日：2010-05-25

申请号：US11484069

申请日：2006-07-11

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： B01J19/00

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： A microchannel reactor is described which has at least one process microchannel and at least one heat exchange zone. The microchannel reactor may be used for conducting a Fischer-Tropsch synthesis reaction.

摘要翻译： 描述了具有至少一个工艺微通道和至少一个热交换区的微通道反应器。 微通道反应器可用于进行费 - 托合成反应。

公开(公告)号：US07084180B2

公开(公告)日：2006-08-01

申请号：US10766297

申请日：2004-01-28

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C27/00

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2 CO和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物通过 与费 - 托催化剂接触以将反应物组合物转化成产物的微通道反应器，该微通道反应器包含多个含有该催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US08188153B2

公开(公告)日：2012-05-29

申请号：US12718356

申请日：2010-03-05

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C27/00 ,  B01J8/00

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与Fischer接触的微通道反应器 - 催化剂将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US20100160463A1

公开(公告)日：2010-06-24

申请号：US12718356

申请日：2010-03-05

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C1/04 ,  B01J8/02

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与Fischer接触的微通道反应器 - 催化剂将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US20060063845A1

公开(公告)日：2006-03-23

申请号：US11261633

申请日：2005-10-31

申请人： Dennis O'Rear ,  Charles Kibby

发明人： Dennis O'Rear ,  Charles Kibby

IPC分类号： C07C27/06

CPC分类号： C10G2/32 ,  C10G2/50 ,  Y02P20/132 ,  Y02P20/582

摘要： CO2 emissions from syngas conversion processes are reduced by use of a multi-stage Fischer-Tropsch reaction system. A process for the conversion of syngas using a Fischer-Tropsch reactor comprises forming a first syngas and reacting at least a portion of the first syngas in a Fischer-Tropsch reactor to form a first hydrocarbonaceous product and a second syngas. The second syngas is mixed with a hydrogen-containing stream to provide an adjusted syngas, at least a portion of which is reacted in a dual functional syngas conversion reactor to form a second hydrocarbonaceous product and a third syngas comprising a reduced amount of CO2 than was present in the adjusted syngas.

摘要翻译： 通过使用多级费 - 托反应系统来减少来自合成气转化过程的CO 2 CO 2排放。 使用费 - 托反应器转化合成气的方法包括形成第一合成气并在费 - 托反应器中使至少一部分第一合成气反应以形成第一烃类产物和第二合成气。 将第二合成气与含氢物流混合以提供调节的合成气，其中至少一部分在双官能合成气转化反应器中反应以形成第二烃产物和包含减少量的CO 2 比在调节合成气中存在。

公开(公告)号：US08425854B1

公开(公告)日：2013-04-23

申请号：US13224600

申请日：2011-10-07

申请人： Shabbir Husain ,  Charles Kibby ,  Lixin You ,  Babak Fayyaz-Najafi

发明人： Shabbir Husain ,  Charles Kibby ,  Lixin You ,  Babak Fayyaz-Najafi

IPC分类号： B01J7/00 ,  B01J8/00

CPC分类号： C07C1/041 ,  B01J8/009 ,  B01J8/0214 ,  B01J8/0257 ,  B01J8/067 ,  B01J19/249 ,  B01J2208/00212 ,  B01J2219/2453 ,  B01J2219/2459 ,  B01J2219/2462 ,  B01J2219/2475 ,  B01J2219/2481 ,  C07C7/144 ,  C07C9/04

摘要： A synthesis gas conversion process for carrying out the process is disclosed. A hydrogen-containing sweep gas is caused to flow across a water permselective membrane adjacent a synthesis gas conversion reaction zone in which synthesis gas is contacted with a catalyst and converted to effluent including water. Water is removed from the reaction zone through the membrane. The sweep gas has sufficient hydrogen partial pressure to cause hydrogen to pass through the membrane into the reaction zone.

摘要翻译： 公开了一种用于实施该方法的合成气转化方法。 使含氢吹扫气体流过邻近合成气转化反应区的水选择性膜，其中合成气与催化剂接触并转化为包含水的流出物。 水通过膜从反应区域中除去。 吹扫气体具有足够的氢分压，使氢气通过膜进入反应区。