公开(公告)号：US20180237704A1

公开(公告)日：2018-08-23

申请号：US15860638

申请日：2018-01-02

申请人： Battelle Memorial Institute

发明人： James J. Strohm ,  Benjamin Q. Roberts ,  Tricia D. Smurthwaite ,  Theresa M. Bergsman ,  Mark D. Bearden

IPC分类号： C10G15/08

CPC分类号： C10G15/08 ,  B01J19/0093 ,  B01J19/088 ,  B01J19/126 ,  B01J2219/00792 ,  B01J2219/00822 ,  B01J2219/00826 ,  B01J2219/00835 ,  B01J2219/0086 ,  B01J2219/00941 ,  B01J2219/0894 ,  B01J2219/1215 ,  B01J2219/1227 ,  B01J2219/1239 ,  B01J2219/1245 ,  B01J2219/1269 ,  B01J2219/1272 ,  C10G1/002 ,  C10G29/205 ,  C10G2300/1033 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  H05H1/46 ,  H05H2001/4622

摘要： Conversion of heavy fossil hydrocarbons (HFH) to a variety of value-added chemicals and/or fuels can be enhanced using microwave (MW) and/or radio-frequency (RE) energy. Variations of reactants, process parameters, and reactor design can significantly influence the relative distribution of chemicals and fuels generated as the product. In one example, a system for flash microwave conversion of HFH includes a source concentrating microwave or RF energy in a reaction zone having a pressure greater than 0.9 atm, a continuous feed having HFH and a process gas passing through the reaction zone, a HFH-to-liquids catalyst contacting the HFH in at least the reaction zone, and dielectric discharges within the reaction zone. The HFH and the catalyst have a residence time in the reaction zone of less than 30 seconds. In some instances, a plasma can form in or near the reaction zone.

公开(公告)号：US09120073B2

公开(公告)日：2015-09-01

申请号：US12479500

申请日：2009-06-05

申请人： Walter Riley Buchanan ,  Christopher Daniel Hruska

发明人： Walter Riley Buchanan ,  Christopher Daniel Hruska

IPC分类号： B01J19/08 ,  B01J12/00 ,  B01J19/00 ,  H05H1/24

CPC分类号： B01J19/0093 ,  B01J19/088 ,  B01J2219/00783 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00828 ,  B01J2219/00831 ,  B01J2219/00853 ,  B01J2219/00869 ,  B01J2219/0809 ,  B01J2219/0815 ,  B01J2219/0835 ,  B01J2219/0843 ,  B01J2219/0847 ,  B01J2219/0892 ,  H05H1/24 ,  H05H1/2406 ,  H05H2001/2418 ,  H05H2001/2437 ,  H05H2245/121

摘要： A plasma reactor consisting of a plurality of elements placed between two or more plasma generating electrodes is presented. Said elements consisting of surfaces, conducting, and/or dielectric which allow for the dielectric isolation of the electrodes from each other and creating a plurality of dielectrically isolated spaces for plasma generation. This plasma reactor achieves a high surface area, with low capacitance allowing simplified construction and is suitable for high frequency operation.

摘要翻译： 提出了由放置在两个或更多个等离子体产生电极之间的多个元件组成的等离子体反应器。 所述元件由表面，导电和/或电介质构成，其允许电极彼此的电介质隔离并且产生用于等离子体产生的多个介电隔离空间。 该等离子体反应器实现了高表面积，具有低容量，允许简化结构，并且适用于高频操作。

公开(公告)号：US20120309957A1

公开(公告)日：2012-12-06

申请号：US13578520

申请日：2011-02-07

申请人： Bruno Frédéric Stengel

发明人： Bruno Frédéric Stengel

IPC分类号： C07H1/00 ,  C07H3/06 ,  B01J23/28 ,  B01J8/02

CPC分类号： C07H3/06 ,  A23K20/163 ,  B01J19/0093 ,  B01J23/28 ,  B01J27/24 ,  B01J2219/00822 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00833 ,  B01J2219/00835 ,  B01J2219/00851 ,  B01J2219/0086 ,  B01J2219/00869 ,  C07H1/00 ,  C07H3/02

摘要： The present invention relates to a process for an epimerization of a saccharide in a microdevice consisting of a network of micron-sized channels in presence of molybdenum containing catalyst. It further relates to the use of a microdevice consisting of a network of micron-sized channels for the epimerization reaction of saccharides and the oligomerisation of the thus obtained epimerized saccharide, preferably into manno-oligosaccharides.

摘要翻译： 本发明涉及一种在含钼催化剂存在下由微米级通道网络组成的微型装置中的糖的差向异构化方法。 它还涉及由微米级通道网络组成的微装置用于糖的差向异构化反应和由此获得的差向异构化糖的低聚，优选用于低聚半乳糖。

公开(公告)号：US08188153B2

公开(公告)日：2012-05-29

申请号：US12718356

申请日：2010-03-05

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C27/00 ,  B01J8/00

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与Fischer接触的微通道反应器 - 催化剂将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US20110097673A1

公开(公告)日：2011-04-28

申请号：US12990395

申请日：2009-04-28

申请人： Ann Forret ,  William Pelletant ,  Ali Hoteit

发明人： Ann Forret ,  William Pelletant ,  Ali Hoteit

IPC分类号： F23L7/00

CPC分类号： F23C10/00 ,  B01J8/22 ,  B01J19/0093 ,  B01J2208/00212 ,  B01J2208/00548 ,  B01J2208/00973 ,  B01J2219/00788 ,  B01J2219/00826 ,  B01J2219/00835 ,  B01J2219/00873 ,  B01J2219/00957 ,  B01J2219/00986 ,  C01B3/344 ,  C01B3/386 ,  C01B3/44 ,  C01B3/48 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/062 ,  C01B2203/065 ,  C01B2203/08 ,  C01B2203/1058 ,  C01B2203/86 ,  F23C2900/99008 ,  Y02E20/346 ,  Y02P30/30

摘要： The invention relates to a method for upgrading heavy liquid fractions resulting from oil refining, by combustion in a fluidized-bed chemical looping process. The method according to the invention allows to produce energy by oxidizing totally the heavy liquid feeds while allowing direct capture of the CO2 emitted in the combustion fumes. The method according to the invention also allows a synthesis gas to be produced.

摘要翻译： 本发明涉及一种通过在流化床化学循环过程中燃烧来提炼由炼油产生的重质液体馏分的方法。 根据本发明的方法允许通过完全氧化重质液体进料同时允许直接捕获在燃烧烟气中排出的CO 2来产生能量。 根据本发明的方法还允许产生合成气。

公开(公告)号：US20110014086A1

公开(公告)日：2011-01-20

申请号：US12677042

申请日：2008-09-10

申请人： Toshinobu Tokita

发明人： Toshinobu Tokita

IPC分类号： G01N33/48 ,  C08F2/48

CPC分类号： B81C1/00071 ,  B01J19/0093 ,  B01J2219/00783 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00833 ,  B01L3/502707 ,  B01L2200/0689 ,  B01L2300/0816 ,  B01L2300/0887 ,  B81B2201/058

摘要： There is provided a method of producing a microfluidic device including a substrate having a depressed portion and a cover member, whereby to reduce the dispersion of a geometric individual difference and the possibility that a non-joint area can occur in a joint portion between the substrate and the cover member. At the time of producing the microfluidic device, the depressed portion serving as a channel, a chamber and a reservoir is formed in advance in the substrate and a liquid-state energy ray curable resin is applied to the surface of the substrate in which the depressed portion is formed. The energy ray curable resin is cured by an energy ray irradiation unit and caused to serve as the cover on the depressed portion of the substrate, thereby to form the channel, chamber and reservoir.

摘要翻译： 提供了一种制造微流体装置的方法，该微流体装置包括具有凹陷部分和覆盖部件的基板，从而减小几何个体差异的分散，以及在基板之间的接合部分中可能发生非接合区域的可能性 和盖构件。 在制造微流体装置时，预先在基板中形成用作通道的凹陷部分，腔室和储存器，并且将液态能量射线固化树脂施加到基板的表面，其中凹陷 形成部分。 能量射线固化树脂通过能量射线照射单元固化，并用作衬底的凹陷部分上的盖，从而形成通道，室和储存器。

公开(公告)号：US20110008215A1

公开(公告)日：2011-01-13

申请号：US12803862

申请日：2010-07-08

申请人： Arkadij M. Elizarov ,  Carroll Edward Ball ,  Jianzhong Zhang ,  Hartmuth C. Kolb ,  Reza Miraghaie ,  Todd Graves ,  Artem Lebedev

发明人： Arkadij M. Elizarov ,  Carroll Edward Ball ,  Jianzhong Zhang ,  Hartmuth C. Kolb ,  Reza Miraghaie ,  Todd Graves ,  Artem Lebedev

IPC分类号： G21C1/00

CPC分类号： B01J19/0093 ,  B01J2219/0081 ,  B01J2219/00826 ,  B01J2219/0086 ,  B01J2219/00871 ,  B01J2219/00936

摘要： Macro- and microfluidic devices and related technologies, and chemical processes using such devices. More specifically, the devices may be used for a fully automated synthesis of radioactive compounds for imaging, such as by positron emission tomography (PET), in an efficient, compact and safe to the operator manner. In particular, embodiments of the present invention relate to an automated, multi-run, microfluidic instrument for the multi-step synthesis of radiopharmaceuticals, such as PET probes, comprising a remote shielded mini-cell containing radiation-handing components.

摘要翻译： 宏观和微流体装置及相关技术以及使用这种装置的化学过程。 更具体地，这些装置可以用于以有效，紧凑和安全的操作者方式全面自动化合成用于成像的放射性化合物，例如通过正电子发射断层摄影（PET）。 特别地，本发明的实施例涉及一种用于多步合成放射性药物的自动化，多运行微流控仪器，例如PET探针，其包括含有辐射递送部件的远程屏蔽微型电池。

公开(公告)号：US07854902B2

公开(公告)日：2010-12-21

申请号：US11843458

申请日：2007-08-22

申请人： Joseph C. Matteo

发明人： Joseph C. Matteo

IPC分类号： B01J10/00

CPC分类号： B01J19/0093 ,  B01J2219/00783 ,  B01J2219/00788 ,  B01J2219/0081 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/0086 ,  B01J2219/00871 ,  B01J2219/00891 ,  B01J2219/00909

摘要： A microfluidic reactor cartridge having glass capillary tubing wound in a coil and surrounded by a ceramic housing capable use in high temperatures and method for using same. In another embodiment, the microfluidic cartridge is a serpentine reactor cartridge with a serpentine microreactor channel formed in a ceramic housing. The serpentine reactor cartridge has an inlet tube attached to its inlet port and an outlet tube attached to its outlet port. The inlet port is a macro/micro interface and the outlet port is a micro/macro interface useful in gas phase reactions where solids must be used to produce a reactant. The method for using a microfluidic reactor cartridge includes two phases, the first phase for producing a radioactive labeled gas such as methyl iodide and the second phase is a methylation reaction.

摘要翻译： 一种微流体反应器筒，其具有缠绕在线圈中的玻璃毛细管并被能够在高温下使用的陶瓷壳体包围，并且使用该陶瓷壳体的方法。 在另一个实施方案中，微流控筒是具有形成在陶瓷壳体中的蛇形微反应器通道的蛇形反应器筒。 蛇形反应器盒具有连接到其入口的入口管和附接到其出口的出口管。 入口是宏/微接口，出口是用于气相反应的微/宏界面，其中固体必须用于产生反应物。 使用微流体反应器筒的方法包括两相，用于产生放射性标记气体如甲基碘的第一相和第二相是甲基化反应。

公开(公告)号：US20100160463A1

公开(公告)日：2010-06-24

申请号：US12718356

申请日：2010-03-05

申请人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

发明人： Yong Wang ,  Anna Lee Tonkovich ,  Terry Mazanec ,  Francis P. Daly ,  Dave VanderWiel ,  Jianli Hu ,  Chunshe Cao ,  Charles Kibby ,  Xiaohong Shari Li ,  Michael D. Briscoe ,  Nathan Gano ,  Ya-Huei Chin

IPC分类号： C07C1/04 ,  B01J8/02

CPC分类号： C10G2/332 ,  B01J19/0093 ,  B01J21/04 ,  B01J23/75 ,  B01J23/8896 ,  B01J23/8913 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J2219/00783 ,  B01J2219/00822 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00835 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  C10G2/341 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2300/70 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P20/582

摘要： The disclosed invention relates to a process for converting a reactant composition comprising H2 and CO to a product comprising at least one aliphatic hydrocarbon having at least about 5 carbon atoms, the process comprising: flowing the reactant composition through a microchannel reactor in contact with a Fischer-Tropsch catalyst to convert the reactant composition to the product, the microchannel reactor comprising a plurality of process microchannels containing the catalyst; transferring heat from the process microchannels to a heat exchanger; and removing the product from the microchannel reactor; the process producing at least about 0.5 gram of aliphatic hydrocarbon having at least about 5 carbon atoms per gram of catalyst per hour; the selectivity to methane in the product being less than about 25%. The disclosed invention also relates to a supported catalyst comprising Co, and a microchannel reactor comprising at least one process microchannel and at least one adjacent heat exchange zone.

摘要翻译： 所公开的发明涉及将包含H 2和CO的反应物组合物转化为包含至少一种具有至少约5个碳原子的脂族烃的产物的方法，该方法包括：使反应物组合物流过与Fischer接触的微通道反应器 - 催化剂将反应物组合物转化成产物，微通道反应器包含多个含有催化剂的工艺微通道; 将热量从工艺微通道传递到热交换器; 并从微通道反应器中除去产物; 该方法每小时产生至少约0.5克具有至少约5个碳原子的每克催化剂的脂族烃; 产品中甲烷的选择性小于约25％。 所公开的发明还涉及包含Co的载体催化剂和包含至少一个工艺微通道和至少一个相邻的热交换区的微通道反应器。

公开(公告)号：US20100158763A1

公开(公告)日：2010-06-24

申请号：US12634833

申请日：2009-12-10

申请人： Thierry Luc Alain Dannoux ,  Pierre Woehl

发明人： Thierry Luc Alain Dannoux ,  Pierre Woehl

IPC分类号： B81B1/00 ,  B01J19/00

CPC分类号： B01J19/0093 ,  B01J2219/00783 ,  B01J2219/00788 ,  B01J2219/00824 ,  B01J2219/00826 ,  B01J2219/00831 ,  B01J2219/00844 ,  B01J2219/0086 ,  B01J2219/00873 ,  B01J2219/00889 ,  B01J2219/00891

摘要： Embodiments of a microchannel reactor comprise a microchannel housing comprising a plurality of channels and an upper microstructure disposed above the microchannel housing. The upper microstructure comprising a gas feed circuit, a liquid feed circuit, and at least one mixing cavity. The mixing cavity is in fluid communication with at least one reactive passage of the microchannel housing. The gas feed circuit comprises at least one gas feed inlet, and the liquid feed circuit comprises at least one liquid feed inlet and at least one liquid reservoir adjacent to the mixing cavity, wherein the liquid reservoir is operable to deliver a liquid feed into the mixing cavity.

摘要翻译： 微通道反应器的实施例包括微通道壳体，其包括多个通道和布置在微通道壳体上方的上部微结构。 上部微结构包括气体供给回路，液体供给回路和至少一个混合腔。 混合腔与微通道壳体的至少一个反应通道流体连通。 所述气体供给回路包括至少一个气体进料入口，并且所述液体进料回路包括至少一个液体进料入口和邻近所述混合腔的至少一个液体储存器，其中所述液体储存器可操作以将液体进料输送到所述混合 腔。