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1.发明授权Photographic element having improved ferrotyping resistance and surface appearance 失效具有改善耐铁性和表面外观的照相元件
公开(公告)号：US5770353A
公开(公告)日：1998-06-23
申请号：US673433
申请日：1996-06-28
申请人： Yongcai Wang , Alfred Bruce Fant , Dennis Edward Smith , Kurt Michael Schroeder , Melvin Michael Kestner
发明人： Yongcai Wang , Alfred Bruce Fant , Dennis Edward Smith , Kurt Michael Schroeder , Melvin Michael Kestner
CPC分类号： G03C1/7614 , G03C1/8155 , G03C1/95 , G03C11/02 , G03C3/00 , Y10S430/132 , Y10S430/151 , Y10S430/162
摘要： Silver halide photographic elements are disclosed comprising a support having a front and a back side, at least one light-sensitive silver halide emulsion layer and a light-insensitive protective overcoat on the front side of the support, and a magnetic recording layer on the back side of the support, the light-insensitive protective overcoat comprising an outermost protective layer, wherein the outermost protective layer comprises a hydrophilic binder and dispersed particles having a mean size of less than 0.4 .mu.m of a polymer having a glass transition temperature of at least 70.degree. C. comprising units derived from monomers A and B at a weight ratio of A:B of from 97:3 to 80:20 and less than 3 wt % ionic monomers, where A represents ethylenically unsaturated monomers which form substantially water insoluble homopolymers and B represents ethylenically unsaturated non-ionic monomers capable of forming water soluble homopolymers. In preferred embodiments of the invention, the light-insensitive protective overcoat further comprises an ultraviolet absorbing layer, which is preferably positioned between the light sensitive silver halide emulsion layer and the outermost protective layer, and which preferably comprises an ultraviolet absorbing dye, a high boiling organic solvent, and a hydrophilic binder. The outermost protective layer preferably also comprises photographic process insoluble matte particles having a mean particle size of larger than 0.5 .mu.m.
摘要翻译： 公开了卤化银照相元件，其包括具有前侧和后侧的支撑体，至少一个感光卤化银乳剂层和在支撑体前侧上的不光泽的保护外涂层，以及背面的磁记录层 所述不透光保护外涂层包括最外保护层，其中最外保护层包括亲水性粘合剂，并且平均尺寸小于0.4μm的聚合物的分散颗粒具有玻璃化转变温度至少为 70℃，包含A：B重量比为97:3至80:20和小于3重量％离子单体的单体A和B的单体，其中A表示烯键式不饱和单体，其形成基本上不溶于水的均聚物 而B代表能形成水溶性均聚物的烯属不饱和非离子单体。 在本发明的优选实施方案中，光不敏感保护外涂层还包括紫外线吸收层，其优选位于感光卤化银乳剂层和最外保护层之间，并且其优选包含紫外线吸收染料，高沸点 有机溶剂和亲水性粘合剂。 最外面的保护层优选还包括平均粒度大于0.5μm的照相工艺不溶性锍颗粒。
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2.发明授权
公开(公告)号：US5935742A
公开(公告)日：1999-08-10
申请号：US633384
申请日：1996-04-16
CPC分类号： G03C3/00 , G03C1/95 , G03C1/32 , G03C1/7954 , Y10S430/151 , Y10S430/162
摘要： A photographic material comprising a cassette containing a processed photographic element, the photographic element comprising a support, at least one light sensitive silver halide layer and a protective overcoat layer on the light sensitive layer, the protective overcoat layer comprising a hydrophilic binder and permanent matte particles, the permanent matte particles comprising greater than 80 mole percent methyl methacrylate and having a mean particle size of from 1 to 1.8 .mu.m and a coating weight of from 70 to 250 mg/m.sup.2.
摘要翻译： 一种照相材料，其包含含有经处理的照相材料的盒，所述照相元件包括支持体，至少一个感光卤化银层和在所述光敏层上的保护性外涂层，所述保护性外涂层包含亲水性粘合剂和永久性无光泽颗粒 包含大于80摩尔％甲基丙烯酸甲酯并且平均粒度为1-1.8μm，涂层重量为70-250mg / m 2的永久性无光泽颗粒。
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公开(公告)号：US06303281B1
公开(公告)日：2001-10-16
申请号：US08603560
申请日：1996-02-21
IPC分类号： G03C176
CPC分类号： G03C1/7614 , G03C1/815 , G03C1/95 , G03C2001/7635 , Y10S430/132 , Y10S430/137 , Y10S430/151 , Y10S430/162
摘要： A silver halide photographic element comprises a support having thereon at least one light-sensitive silver halide emulsion layer and a light-insensitive protective layer, the light-insensitive protective layer comprising an ultraviolet absorbing layer closer to the support and an outermost protective layer, the ultraviolet absorbing layer comprising an ultraviolet aborbing dye, a high boiling organic solvent, and a hydrophilic binder, the outermost protective layer comprising insoluble matte particles having a mean particle size of larger than 0.5 &mgr;m, dispersed polymer particles having a mean size of less than 0.2 &mgr;m, and a glass transition temperature of at least 70° C., and a hydrophilic binder.
摘要翻译： 卤化银照相元件包括其上具有至少一个感光卤化银乳剂层和不光敏保护层的载体，所述不透光保护层包含更靠近载体的紫外线吸收层和最外层保护层， 包含紫外线吸收染料，高沸点有机溶剂和亲水性粘合剂的紫外线吸收层，最外层保护层包含平均粒径大于0.5μm的不溶性无光泽颗粒，平均粒径小于0.2μm的分散聚合物颗粒 妈妈，玻璃化转变温度至少为70℃，以及亲水性粘合剂。
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公开(公告)号：US5756273A
公开(公告)日：1998-05-26
申请号：US595891
申请日：1996-02-06
申请人： Yongcai Wang , Gary William Visconte , Alfred Bruce Fant , James Lee Bello , Kurt Michael Schroeder
发明人： Yongcai Wang , Gary William Visconte , Alfred Bruce Fant , James Lee Bello , Kurt Michael Schroeder
IPC分类号： G03C1/76
CPC分类号： G03C1/7614 , Y10S430/162
摘要： A photographic element having a support, a light-sensitive layer and a protective overcoat layer, at least one layer comprising a hydrophilic colloid containing colloidal core-shell latex particles, the core being a hydrophobic polymer and the shell comprising greater than 10 and less than 90 mole percent of an ethylenically unsaturated monomer having a carboxylic acid group.
摘要翻译： 具有支持体，感光层和保护性外涂层的照相元件，至少一层包含含有胶体核 - 壳胶乳颗粒的亲水胶体，所述芯为疏水性聚合物，所述壳包含大于10且小于 90摩尔％的具有羧酸基团的烯属不饱和单体。
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公开(公告)号：US5738983A
公开(公告)日：1998-04-14
申请号：US633281
申请日：1996-04-16
CPC分类号： G03C1/95 , G03C3/00 , Y10S430/151 , Y10S430/162
摘要： A photographic imaging element comprising a support, at least one light-sensitive silver halide layer, and a light-insensitive layer comprising a polymer particle of the formula: (A).sub.x (B).sub.y (C).sub.z (I) where A is a polyfunctional ethylenically unsaturated crosslinking monomer, B is an ethylenically unsaturated monomer containing carboxylic acid groups, C is a monofunctional ethylenically unsaturated monomer other than B, x is about 0.1 to 2 mole percent, y is about 35 to 70 mole percent and z equals 100-(x+y) mole percent.
摘要翻译： 一种摄影成像元件，其包括载体，至少一种感光卤化银层和不透光层，其包含下式的聚合物颗粒：（A）x（B）y（C）z（I）其中A为 多官能烯属不饱和交联单体，B是含有羧酸基团的烯属不饱和单体，C是除B以外的单官能烯属不饱和单体，x为约0.1至2摩尔％，y为约35至70摩尔％，z为100 - （x + y）摩尔％。
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6.发明授权Ultraviolet ray absorbing polymer latex compositions, method of making same, and imaging elements employing such particles 失效紫外线吸收聚合物胶乳组合物，其制备方法和使用这种颗粒的成像元件
公开(公告)号：US5948605A
公开(公告)日：1999-09-07
申请号：US698749
申请日：1996-08-16
CPC分类号： C08F246/00 , G03C1/815 , Y10S430/132 , Y10S977/887
摘要： The present invention provides UV absorbing particles which are a polymerization reaction product of ethylenically unsaturated monomers selected from esters and amides of acrylic on methacrylic acid, vinyl esters, vinyl ethers, and vinyl nitrites; an initiator, a surfactant and an ultraviolet absorber having the general formula: ##STR1## wherein R is each independently a hydrogen, halogen, alkyl, aryl, alkoxy, acyloxy, alkylthio, arylthio, amine, alkylamino, arylamino, hydroxyl, cyano, nitro, acylamino, sulfonyl, sulfamido, acyloxy and oxycarbonyl.
摘要翻译： 本发明提供了紫外线吸收颗粒，其是选自丙烯酸对甲基丙烯酸，乙烯基酯，乙烯基醚和亚乙烯基酯的丙烯酸酯和酰胺的烯属不饱和单体的聚合反应产物; 具有以下通式的引发剂，表面活性剂和紫外线吸收剂：其中R各自独立地为氢，卤素，烷基，芳基，烷氧基，酰氧基，烷硫基，芳硫基，胺，烷基氨基，芳基氨基，羟基，氰基，硝基，酰氨基， 磺酰基，氨磺酰氨基，酰氧基和氧羰基。
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公开(公告)号：US20130162722A1
公开(公告)日：2013-06-27
申请号：US13334130
申请日：2011-12-22
申请人： Thomas B. Brust , Catherine A. Falkner , Kurt Michael Schroeder , Yongcai Wang , Brian J. Antalek , James R. Hauenstein , Thomas Henry Mourey , James M. Hewitt
发明人： Thomas B. Brust , Catherine A. Falkner , Kurt Michael Schroeder , Yongcai Wang , Brian J. Antalek , James R. Hauenstein , Thomas Henry Mourey , James M. Hewitt
IPC分类号： B41J2/04
CPC分类号： C09D11/322 , C09D11/102
摘要： Pigment-based ink composition, and inkjet printing systems and methods employing such ink composition. The ink contains an aqueous polyurethane additive including polyurethane polymer chains including at least first segments having a polysiloxane group of Mw greater than about 10,000 pendant to the polyurethane polymer chain backbone, wherein (i) the polyurethane additive further comprises polyurethane polymer chains including second segments having a polysiloxane group of Mw less than about 6,000 either pendant to the polyurethane polymer backbone or a part of the polyurethane polymer backbone or (ii) the composition further comprises a polysiloxane polymer additive of Mw of less than about 6,000 which is not pendant to a polyurethane polymer backbone or a part of a polyurethane polymer backbone. The polyurethane additive has a Mw of at least 10,000 and a sufficient number of acid groups to provide an acid number greater than 20.
摘要翻译： 基于颜料的油墨组合物，以及使用这种油墨组合物的喷墨印刷系统和方法。 油墨含有水性聚氨酯添加剂，其包括聚氨酯聚合物链，其包含至少具有Mw大于约10,000的聚硅氧烷基团的聚氨酯聚合物链主链的第一链段，其中（i）聚氨酯添加剂还包含聚氨酯聚合物链，其包含第二链段， 聚氨酯聚合物主链或部分聚氨酯聚合物骨架的Mw小于约6,000的聚硅氧烷基团，或（ii）组合物还包含Mw小于约6,000的聚硅氧烷聚合物添加剂，其不垂直于聚氨酯 聚合物主链或聚氨酯聚合物主链的一部分。 聚氨酯添加剂具有至少10,000的Mw和足够数量的酸基以提供大于20的酸值。
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公开(公告)号：US20130237661A1
公开(公告)日：2013-09-12
申请号：US13334125
申请日：2011-12-22
申请人： Thomas B. Brust , Catherine A. Falkner , Kurt Michael Schroeder , Yongcai Wang , Brian J. Antalek , James R. Hauenstien , Thomas Henry Mourey , James M. Hewitt
发明人： Thomas B. Brust , Catherine A. Falkner , Kurt Michael Schroeder , Yongcai Wang , Brian J. Antalek , James R. Hauenstien , Thomas Henry Mourey , James M. Hewitt
IPC分类号： C09D11/10
CPC分类号： C09D11/322 , C08G18/0823 , C08G18/348 , C08G18/4854 , C08G18/5015 , C08G18/61 , C08G18/6692 , C08G18/755 , C09D11/102
摘要： Pigment-based ink composition, and inkjet printing systems and methods employing such ink composition. The ink contains an aqueous polyurethane additive including polyurethane polymer chains including at least first segments having a polysiloxane group of Mw greater than about 10,000 pendant to the polyurethane polymer chain backbone, wherein (i) the polyurethane additive further comprises polyurethane polymer chains including second segments having a polysiloxane group of Mw less than about 6,000 either pendant to the polyurethane polymer backbone or a part of the polyurethane polymer backbone or (ii) the composition further comprises a polysiloxane polymer additive of Mw of less than about 6,000 which is not pendant to a polyurethane polymer backbone or a part of a polyurethane polymer backbone. The polyurethane additive has a Mw of at least 10,000 and a sufficient number of acid groups to provide an acid number greater than 20.
摘要翻译： 基于颜料的油墨组合物，以及使用这种油墨组合物的喷墨印刷系统和方法。 油墨含有水性聚氨酯添加剂，其包括聚氨酯聚合物链，其包含至少具有Mw大于约10,000的聚硅氧烷基团的聚氨酯聚合物链主链的第一链段，其中（i）聚氨酯添加剂还包含聚氨酯聚合物链，其包含第二链段， 聚氨酯聚合物主链或部分聚氨酯聚合物骨架的Mw小于约6,000的聚硅氧烷基团，或（ii）组合物还包含Mw小于约6,000的聚硅氧烷聚合物添加剂，其不垂直于聚氨酯 聚合物主链或聚氨酯聚合物主链的一部分。 聚氨酯添加剂具有至少10,000的Mw和足够数量的酸基以提供大于20的酸值。
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公开(公告)号：US5709986A
公开(公告)日：1998-01-20
申请号：US594102
申请日：1996-01-30
CPC分类号： G03C1/7614 , G03C1/95 , Y10S430/151 , Y10S430/162
摘要： A photographic element having a support, at least one light-sensitive silver halide layer and a layer containing matte bead particles, the matte bead particles being a copolymer of a styrenic monomer or acrylic acid or methacrylic acid or an acrylic acid ester or a methacrylic acid ester or mixture thereof where the ester group contains up to 6 carbon atoms and an acrylic or methacrylic acid ester where the ester group has from 10 to 22 carbon atoms, each matte bead particle being surrounded by colloidal size particles of a suspension stabilizing agent.
摘要翻译： 具有支持体，至少一个感光卤化银层和含有无光泽珠粒子的层的照相元件，无光泽珠粒子是苯乙烯单体或丙烯酸或甲基丙烯酸或丙烯酸酯或甲基丙烯酸的共聚物 酯基或其混合物，其中酯基含有至多6个碳原子，丙烯酸或甲基丙烯酸酯，其中酯基具有10至22个碳原子，每个无光泽珠粒被悬浮稳定剂的胶体粒子包围。
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公开(公告)号：US5834174A
公开(公告)日：1998-11-10
申请号：US893133
申请日：1997-07-15
CPC分类号： G03C1/95 , G03C1/053 , Y10S430/151
摘要： A photographic element comprising a support, at least one hydrophilic light-sensitive layer, and a light-insensitive layer containing a binder and solid, nonporous polymer matte particle having the formula: (A).sub.x (B).sub.y where A is a monofunctional ethylenically unsaturated monomer, B is a polyfunctional ethylenically unsaturated monomer, x is from 0 to 55 mole %, and y is about 45 to 100 mole %.
摘要翻译： 一种照相元件，其包括载体，至少一个亲水感光层和含有粘合剂的光不敏感层和具有下式的固体无孔聚合物哑光颗粒：（A）x（B）y其中A是单官能烯属不饱和的 单体，B是多官能烯属不饱和单体，x为0至55摩尔％，y为约45至100摩尔％。
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