公开(公告)号：US4900588A

公开(公告)日：1990-02-13

申请号：US119115

申请日：1987-11-10

申请人： Yoshimitsu Tajima ,  Motoo Mohri ,  Hideaki Tanaka

发明人： Yoshimitsu Tajima ,  Motoo Mohri ,  Hideaki Tanaka

IPC分类号： C23C16/26 ,  C23C16/56 ,  H01M4/1393 ,  H01M4/96

CPC分类号： H01M4/583 ,  C23C16/26 ,  C23C16/56 ,  H01M4/96 ,  H01M4/587 ,  Y02P70/54

摘要： A method for the production of a carbon electrode comprising disposing an electroconductive and flexible electrode substrate within a reaction tube to which a gaseous material gas of hydrocarbons is supplied, directly depositing a carbon material on said electrode substrate by chemical vapor deposition at 1500.degree. C. or less so as to coat said electrode substrate with a carbon material, and rolling said electrode substrate coated with the carbon material, resulting in a thin-plate shaped carbon electrode having a high density.

公开(公告)号：US4863818A

公开(公告)日：1989-09-05

申请号：US65508

申请日：1987-06-23

申请人： Yoshikazu Yoshimoto ,  Tomonari Suzuki ,  Hiroshi Wada ,  Masaru Yoshida ,  Shigeo Nakajima ,  Yoshimitsu Tajima ,  Nobuhiro Yanagisawa ,  Motoo Mohri ,  Michiyo Kasahara ,  Hideaki Tanaka

发明人： Yoshikazu Yoshimoto ,  Tomonari Suzuki ,  Hiroshi Wada ,  Masaru Yoshida ,  Shigeo Nakajima ,  Yoshimitsu Tajima ,  Nobuhiro Yanagisawa ,  Motoo Mohri ,  Michiyo Kasahara ,  Hideaki Tanaka

IPC分类号： C01B31/04 ,  C23C16/26 ,  D01F9/127 ,  D01F9/133 ,  H01M4/00 ,  H01M4/133 ,  H01M4/58 ,  H01M4/583 ,  H01M4/587 ,  H01M4/96 ,  H01M10/0525 ,  H01M10/36

CPC分类号： H01M4/133 ,  B82Y30/00 ,  C01B31/04 ,  C01B31/0415 ,  C23C16/26 ,  D01F9/1272 ,  D01F9/1275 ,  D01F9/1276 ,  D01F9/133 ,  H01M10/0525 ,  H01M4/583 ,  H01M4/96 ,  C01P2002/78 ,  H01M4/587 ,  Y02P70/54

摘要： A method for the manufacture of a pyrolytic graphite with high crystallinity comprising the deposition of graphite directly onto a catalytic substrate by thermal decomposition of a carbon-containing material at low temperatures. An electrode with graphite as an active material and an electrode substrate as a current collector unified, said graphite being pyrolytic graphite that is deposited on a metal electrode substrate with catalytic properties so as to cover said metal electrode substrate by the method. A battery has a pair of positive and negative electrodes, at least one of which is made of graphite as its electrode active material.

摘要翻译： 一种用于制造具有高结晶度的热解石墨的方法，包括通过在低温下热分解含碳材料将石墨直接沉积到催化底物上。 具有石墨作为活性物质的电极和作为集电体的电极基板一体化，所述石墨为热电石墨，其通过该方法沉积在具有催化性质的金属电极基板上以覆盖所述金属电极基板。 电池具有一对正极和负极，其中至少一个由石墨制成作为其电极活性材料。

公开(公告)号：US4863814A

公开(公告)日：1989-09-05

申请号：US30886

申请日：1987-03-26

申请人： Motoo Mohri ,  Hideaki Tanaka ,  Tomonari Suzuki ,  Yoshimitsu Tajima ,  Yoshikazu Yoshimoto ,  Shigeo Nakajima ,  Michiyo Kasahara

发明人： Motoo Mohri ,  Hideaki Tanaka ,  Tomonari Suzuki ,  Yoshimitsu Tajima ,  Yoshikazu Yoshimoto ,  Shigeo Nakajima ,  Michiyo Kasahara

IPC分类号： C01B31/02 ,  C23C16/26 ,  H01M4/133 ,  H01M4/1393 ,  H01M4/58 ,  H01M4/583 ,  H01M4/587 ,  H01M4/96 ,  H01M10/0525 ,  H01M10/36

CPC分类号： H01M10/0525 ,  C01B31/02 ,  C23C16/26 ,  H01M4/133 ,  H01M4/587 ,  H01M4/96 ,  H01M4/1393 ,  H01M4/583

摘要： An electrode comprising as the main component carbon materials that have a layer structure more disordered than graphite and have hexagonal net faces with a selective orientation. Using said electrode, a secondary battery with a nonaqueous electrolytic solution is manufactured, which comprises a positive electrode, a nonaqueous electrolytic solution, and a negative electrode that has carbon materials as the active substances that can form an electrochemically reversible compound with a light-weight metal element, wherein said positive electrode is made such that its capacity for being charged or discharged is greater than that of said negative electrode.

摘要翻译： 包含作为主要组分的碳材料的电极，其具有比石墨更无序的层结构并且具有选择性取向的六边形网面。 使用所述电极，制造具有非水电解液的二次电池，其包括正极，非水电解液和负极，其具有作为活性物质的碳材料，所述活性物质可形成轻质的电化学可逆化合物 金属元素，其中所述正电极被制成使得其充电或放电的容量大于所述负电极的容量。

公开(公告)号：US4931240A

公开(公告)日：1990-06-05

申请号：US245772

申请日：1988-09-19

申请人： Yoshimitsu Tajima ,  Motoo Mohri

发明人： Yoshimitsu Tajima ,  Motoo Mohri

IPC分类号： C23C16/26 ,  H01M4/1393 ,  H01M4/62 ,  H01M4/96

CPC分类号： H01M4/583 ,  C23C16/26 ,  H01M4/0428 ,  H01M4/1393 ,  H01M4/587 ,  H01M4/96

摘要： A method for the production of a carbon electrode includes directly depositing a carbon material on an electroconductive and flexible electrode substrate by chemical vapor deposition using gaseous hydrocarbons as a starting material, filling the carbon material directly deposited on the electrode substrate with a charge carrier material capable of being reversibly intercalcated therein and deintercalated therefrom, and compressing the electrode substrate filled with the charge carrier material, resulting in a thin plate-shaped carbon electrode.

公开(公告)号：US4835075A

公开(公告)日：1989-05-30

申请号：US119134

申请日：1987-11-10

申请人： Yoshimitsu Tajima ,  Motoo Mohri ,  Hideaki Tanaka

发明人： Yoshimitsu Tajima ,  Motoo Mohri ,  Hideaki Tanaka

IPC分类号： C01B31/02 ,  H01M4/587 ,  H01M4/96 ,  H01M10/05 ,  H01M10/052 ,  H01M10/054

CPC分类号： H01M10/05 ,  H01M4/587 ,  H01M4/96

摘要： A secondary battery using nonaqueous electrolytes that contain a light metal as an active material, and comprising an anode, a cathode and a separator that electrically separates the anode from the cathode, wherein said anode comprises a heat-resistant porous support and a carbon material deposited on said porous support, said carbon material having the following physico-chemical properties: The mean interlayer separation of said carbon active material is in the range of 0.337 to 0.355 nm; the ratio of the Raman intensity of 1360 cm.sup.-1 to that of 1580 cm.sup.-1 with regard to the argon laser Raman spectra of said carbon material is in the range of 0.4 to 1.0; and said carbon material is mainly composed of a carbon having a six-membered ring structure with flat networks and having a selective orientation.

摘要翻译： 一种二次电池，其使用含有轻金属作为活性材料的非水电解质，并且包括将阳极与阴极电分离的阳极，阴极和隔板，其中所述阳极包括耐热多孔载体和沉积的碳材料 在所述多孔载体上，所述碳材料具有以下物理化学性质：所述碳活性材料的平均层间分离在0.337至0.355nm的范围内; 相对于所述碳材料的氩激光拉曼光谱，1360cm -1的拉曼强度与1580cm -1的拉曼强度的比在0.4〜1.0的范围内; 并且所述碳材料主要由具有平坦网络并具有选择性取向的六元环结构的碳组成。

公开(公告)号：US4968527A

公开(公告)日：1990-11-06

申请号：US264598

申请日：1988-10-31

申请人： Yoshikazu Yoshimoto ,  Tomonari Suzuki ,  Hiroshi Wada ,  Masaru Yoshida ,  Shigeo Nakajima ,  Yoshimitsu Tajima ,  Nobuhiro Yanagisawa ,  Motoo Mohri ,  Michiyo Kasahara ,  Hideaki Tanaka

发明人： Yoshikazu Yoshimoto ,  Tomonari Suzuki ,  Hiroshi Wada ,  Masaru Yoshida ,  Shigeo Nakajima ,  Yoshimitsu Tajima ,  Nobuhiro Yanagisawa ,  Motoo Mohri ,  Michiyo Kasahara ,  Hideaki Tanaka

IPC分类号： C01B31/04 ,  C23C16/26 ,  D01F9/127 ,  D01F9/133 ,  H01M4/00 ,  H01M4/133 ,  H01M4/58 ,  H01M4/583 ,  H01M4/587 ,  H01M4/96 ,  H01M10/0525 ,  H01M10/36

CPC分类号： H01M4/133 ,  B82Y30/00 ,  C01B31/04 ,  C01B31/0415 ,  C23C16/26 ,  D01F9/1272 ,  D01F9/1275 ,  D01F9/1276 ,  D01F9/133 ,  H01M10/0525 ,  H01M4/583 ,  H01M4/96 ,  C01P2002/78 ,  H01M4/587 ,  Y02P70/54

摘要： A method for the manufacture of a pyrolytic graphite with high crystallinity comprising the deposition of graphite directly onto a crystalline catalytic substrate by thermal decomposition of a carbon-containing material at a temperature of 1000.degree. C. or less, the pyrolytic graphite having interlayer spacing in a limited range and a c-axis orientation of carbon layers perpendicular to the surface of the substrate. An electrode with graphite as an active material and a crystalline metal electrode substrate as a current collector unified, the graphite being pyrolytic graphite that is deposited on the crystalline metal electrode substrate with catalytic properties so as to cover the crystalline metal electrode substrate by the above-mentioned method.

摘要翻译： 用于制造具有高结晶度的热解石墨的方法包括通过在低温下热分解含碳材料将石墨直接沉积到催化底物上。 还公开了包含石墨作为活性材料的电极和作为集电体的电极基板，所述石墨是热电石墨，其通过所述方法沉积在具有催化性能的金属电极基板上以覆盖所述金属电极基板。 还公开了一种电池，其包括一对正极和负极，至少一个正极和负极由石墨作为其电极活性材料制成。

公开(公告)号：US4621417A

公开(公告)日：1986-11-11

申请号：US702608

申请日：1985-02-19

申请人： Motoo Mohri ,  Yoshimitsu Tajima

发明人： Motoo Mohri ,  Yoshimitsu Tajima

IPC分类号： H01M4/26 ,  B01J20/02 ,  H01M4/24 ,  H01M4/04 ,  C01B6/24 ,  H01M4/88

CPC分类号： H01M4/242 ,  Y10T29/49108

摘要： The preferred embodiment provides such a hydrogen-stored electrode extremely useful for application to the cathode of alkaline battery. It makes it possible to manufacture such a useful hydrogen-stored electrode molded into electrode form after activation of hydrogen-stored alloy by means of hydrogen generated by immersion of blends into solution, in which the blends is composed of hydrogen-stored alloy and additives that generate hydrogen through their reaction with the above solution.

摘要翻译： 优选的实施方案提供了这样一种非常适用于碱性电池阴极的氢储存电极。 通过将共混物浸入溶液中产生的氢活化氢储存合金后，可以制造这样一种有用的储氢电极成型为电极形式，其中共混物由储氢合金和添加剂组成， 通过与上述溶液的反应产生氢气。

公开(公告)号：US4977045A

公开(公告)日：1990-12-11

申请号：US467998

申请日：1990-01-22

申请人： Motoo Mohri

发明人： Motoo Mohri

IPC分类号： H01M4/38 ,  H01M6/18 ,  H01M10/05 ,  H01M10/0562 ,  H01M10/34

CPC分类号： H01M4/383 ,  H01M10/347 ,  H01M6/18

摘要： The preferred embodiment provides a unique solid-state electrolytic battery featuring high reliability and an extremely durably service life. The battery is capable of generating a large amount of dischargeble current and can be satisfactorily charged and discharged using the activated hydrogen-stored alloy/materials. This unique solid-state electrolytic battery incorporates a cathode comprised of activated hydrogen-stored alloy storing metallic-hydrogenated hydrogen; a solid-state electrolyte comprised of hydrogen-ion conductive elements; and an anode containing an activated guest material, primarily hydrogen-ions.

摘要翻译： 该优选实施例提供了一种独特的固态电解电池，具有高可靠性和极其耐用的使用寿命。 电池能够产生大量的放电电流，并且可以使用活化的储氢合金/材料令人满意地充电和放电。 这种独特的固态电解质电池结合了由存储金属氢化氢的活化储氢合金构成的阴极; 由氢离子导电元件构成的固体电解质; 和含有活化的客体材料的阳极，主要是氢离子。

公开(公告)号：US4782584A

公开(公告)日：1988-11-08

申请号：US33687

申请日：1987-04-03

申请人： Motoo Mohri ,  Tetsuya Yoneda

发明人： Motoo Mohri ,  Tetsuya Yoneda

IPC分类号： H01M2/16 ,  H01M6/12 ,  H01M10/28 ,  H01M10/34 ,  H01M6/00

CPC分类号： H01M10/283 ,  H01M10/345 ,  H01M6/12 ,  Y02P70/54 ,  Y10T29/49108 ,  Y10T29/4911

摘要： A powdered positive mixture, a powdered separator mixture, and a powdered negative mixture are filled sequentially into a mold in layers, then the layers of the positive mixture, the separator mixture and the negative mixture are compacted in the mold to form a laminated tablet. The laminated tablet is placed in a container, and is impregnated with an alkaline electrolyte queous solution. Then the container is sealed to produce an alkaline cell.

摘要翻译： 将粉末状的正极混合物（4），粉末状分离剂混合物（5）和粉末状负极混合物（6）依次填充到模具（1）中，然后将正极混合物（4），隔板混合物 （5）和负极混合物（6）在模具（1）中压实以形成层压片剂，然后将层压片剂放入容器（7）中，然后用碱性电解质浆液（ 10），然后将容器（7）密封以完成碱性电池。