Polymerization methods using the catalysts

    公开(公告)号:US20070123666A1

    公开(公告)日:2007-05-31

    申请号:US11581470

    申请日:2006-10-17

    IPC分类号: C08F4/80

    CPC分类号: C08F4/70 C08F32/08

    摘要: Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer represented by Formula 2 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic complex; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L′2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different, and wherein m is an integer of 0 to 4; and R7, R′7, R″7, and R″′7 are each independently a polar functional group or a nonpolar functional group. According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.

    Catalysts for polymerizing cyclic olefin
    2.
    发明申请
    Catalysts for polymerizing cyclic olefin 有权
    用于聚合环烯烃的催化剂

    公开(公告)号:US20070093624A1

    公开(公告)日:2007-04-26

    申请号:US11542166

    申请日:2006-10-04

    IPC分类号: C08F4/80

    摘要: Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic precatalyst; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.

    摘要翻译: 本发明提供一种通过下述式1表示的环状烯烃系单体的加成聚合制备环状烯烃系聚合物的金属催化剂配合物:&lt;线内配方说明=“在线式”末端= “铅”?> [M(L 1)(L'2 )(L (L 3)(L 3 >)Z是阳离子预催化剂; L 1是含阴离子烃基的配体; L'2是中性配体; L 3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2 <= x + y + z <= 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体,因此具有优异的热稳定性和反应性。

    Catalyst system for polymerizing cyclic olefin having polar functional group, polymerizing method using the catalyst system, olefin polymer produced by the method and optical anisotropic film comprising the olefin polymer
    3.
    发明申请
    Catalyst system for polymerizing cyclic olefin having polar functional group, polymerizing method using the catalyst system, olefin polymer produced by the method and optical anisotropic film comprising the olefin polymer 有权
    用于聚合具有极性官能团的环烯烃的催化剂体系,使用催化剂体系的聚合方法,通过该方法制备的烯烃聚合物和包含烯烃聚合物的光学各向异性膜

    公开(公告)号:US20060058477A1

    公开(公告)日:2006-03-16

    申请号:US11227093

    申请日:2005-09-16

    IPC分类号: C08F4/06 B01J31/00

    CPC分类号: C08F4/70

    摘要: A catalyst system capable of producing a cyclic olefin polymer having a polar functional group and a high molecular weight with a high yield in which a catalyst is not deactivated due to polar functional groups of monomers, and a method of producing polymers using the same are provided. The catalyst system for polymerization of olefin according to the present invention has good thermal and chemical stability, and thus, in the method of preparing polyolefin using the catalyst system, the deactivation of a catalyst due to a polar functional group of the monomer can be prevented, and thus a high yield of the cyclic olefin polymer with a high molecular weight can be obtained when a ratio of the catalyst to the monomer is 1:5000, and the removal of a catalyst residue is not required.

    摘要翻译: 提供一种催化剂体系,其能够制备具有极性官能团和高分子量的环状烯烃聚合物,其高产率,其中由于单体的极性官能团而不使催化剂失活,以及使用其制备聚合物的方法 。 本发明的烯烃聚合用催化剂体系具有良好的热稳定性和化学稳定性,因此在使用该催化剂体系的聚烯烃的制造方法中,可以防止由于单体的极性官能团引起的催化剂的失活 因此,当催化剂与单体的比例为1:5000时,可以获得高产率的具有高分子量的环状烯烃聚合物,并且不需要除去催化剂残余物。

    APPARATUS AND METHOD FOR SUPPORTING MOBILITY OF WIRELESS TERMINAL IN WIRELESS COMMUNICATION NETWORK
    6.
    发明申请
    APPARATUS AND METHOD FOR SUPPORTING MOBILITY OF WIRELESS TERMINAL IN WIRELESS COMMUNICATION NETWORK 有权
    在无线通信网络中支持无线终端移动的装置和方法

    公开(公告)号:US20080108368A1

    公开(公告)日:2008-05-08

    申请号:US12013359

    申请日:2008-01-11

    IPC分类号: H04Q7/22

    CPC分类号: H04W4/06 H04L12/189 H04W76/40

    摘要: A method and apparatus for informing terminals in a UMTS regarding state information of an MBMS in order to prevent terminals from requesting a service that cannot be provided in a cell in which it is newly located. The mobile communication network informs the terminals about its service provision state for a particular MBMS service being provided, and the terminals operate in accordance with this service provision state information to minimize unnecessary operations of the terminal and unnecessary signaling and waste of radio resources.

    摘要翻译: 一种用于通知UMTS中的终端关于MBMS的状态信息的方法和装置,以便防止终端请求在其新位于的小区中不能提供的业务。 移动通信网络向终端通知所提供的特定MBMS服务的服务提供状态,并且终端根据该服务提供状态信息进行操作,以最小化终端的不必要操作以及不必要的信令和浪费无线电资源。

    Apparatus and method for transmitting information for MBMS
    7.
    发明申请
    Apparatus and method for transmitting information for MBMS 有权
    用于发送MBMS信息的装置和方法

    公开(公告)号:US20060183498A1

    公开(公告)日:2006-08-17

    申请号:US11333900

    申请日:2006-01-17

    IPC分类号: H04M1/00

    摘要: An apparatus and method for transmitting information for a Multimedia Broadcast/Multicast Service (MBMS) is provided that facilitates a mobile communication device receiving a specific MBMS without any difficulty when the device moves from one area to another area. By providing MBMS status information to a controller in the area from which the device moved, the controller in the area from which the device moved can either establish an additional channel to provide the MBMS to the device or initiate a relocation of control of the device to a controller in the area into which the device has moved.

    摘要翻译: 提供一种用于发送多媒体广播/组播服务(MBMS)的信息的装置和方法,其在设备从一个区域移动到另一个区域时便于移动通信设备接收特定的MBMS,而没有任何困难。 通过向设备移动的区域中的控制器提供MBMS状态信息,设备移动的区域中的控制器可以建立附加信道以向设备提供MBMS,或者启动设备的控制重定位 设备移动到的区域中的控制器。

    Transmitting and receiving notification of control information for point to multipoint service in wireless communication system
    10.
    发明申请
    Transmitting and receiving notification of control information for point to multipoint service in wireless communication system 有权
    发送和接收无线通信系统中点对多点业务的控制信息通知

    公开(公告)号:US20050255836A1

    公开(公告)日:2005-11-17

    申请号:US11121860

    申请日:2005-05-04

    摘要: The present invention relates to transmitting and receiving a notification of control information for a point-to-multipoint service. Preferably, a mobile terminal receives notification information from a network during a first period. The mobile terminal then determines to receive a control channel during a second period for receiving a control information message according to the notification information. After, the mobile terminal receives the control information message for the point-to-multipoint service during the second period if the mobile terminal determines to receive the control information message during the second period.

    摘要翻译: 本发明涉及发送和接收点对多点业务的控制信息的通知。 优选地,移动终端在第一时段期间从网络接收通知信息。 然后,移动终端确定在用于根据通知信息接收控制信息消息的第二时段期间接收控制信道。 之后,如果移动终端在第二时段期间确定接收到控制信息消息,则移动终端在第二周期期间接收点对多点业务的控制信息消息。