摘要:
Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer represented by Formula 2 below: [M(L1)x(L′2)y(L3)z]a[Ani]b wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic complex; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L′2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different, and wherein m is an integer of 0 to 4; and R7, R′7, R″7, and R″′7 are each independently a polar functional group or a nonpolar functional group. According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.
摘要:
Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L1)x(L′2)y(L3)z]a[Ani]b wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic precatalyst; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.
摘要翻译:本发明提供一种通过下述式1表示的环状烯烃系单体的加成聚合制备环状烯烃系聚合物的金属催化剂配合物:&lt;线内配方说明=“在线式”末端= “铅”?> [M(L 1)(L'2 sub>)(L (L 3) SUB>(L 3 SUB> >)Z是阳离子预催化剂; L 1是含阴离子烃基的配体; L'2是中性配体; L 3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2 <= x + y + z <= 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体,因此具有优异的热稳定性和反应性。
摘要:
A catalyst system capable of producing a cyclic olefin polymer having a polar functional group and a high molecular weight with a high yield in which a catalyst is not deactivated due to polar functional groups of monomers, and a method of producing polymers using the same are provided. The catalyst system for polymerization of olefin according to the present invention has good thermal and chemical stability, and thus, in the method of preparing polyolefin using the catalyst system, the deactivation of a catalyst due to a polar functional group of the monomer can be prevented, and thus a high yield of the cyclic olefin polymer with a high molecular weight can be obtained when a ratio of the catalyst to the monomer is 1:5000, and the removal of a catalyst residue is not required.
摘要:
Provided is a method of preparing a phosphonium compound by reacting a protic phosphonium compound represented by [(R1)—P(R2)a(R2′)b]HX and a salt compound represented by [C][Ani]. Therefore, a phosphonium compound used as a cocatalyst for the preparation of a polar cyclic olefin polymer can be produced at high yield.
摘要:
A method of copolymerizing cyclic olefins and polar vinyl olefins, a copolymer produced by the method, and an optical anisotropic film including the copolymer are provided. According to the copolymerization method, a cyclic olefin and a polar vinyl olefin can be effectively copolymerized using a catalyst system composed of a compound containing a group 13 element and a radical initiator. The resulting copolymer is transparent, and has high adhesion, thermal stability, optical anisotropy and strength, and a low dielectric constant. The optical film including the copolymer can be used as a plastic lens, a polarizer protective film, an adhesive film, and a compensation film, and in a LCD display.
摘要:
A method and apparatus for informing terminals in a UMTS regarding state information of an MBMS in order to prevent terminals from requesting a service that cannot be provided in a cell in which it is newly located. The mobile communication network informs the terminals about its service provision state for a particular MBMS service being provided, and the terminals operate in accordance with this service provision state information to minimize unnecessary operations of the terminal and unnecessary signaling and waste of radio resources.
摘要:
An apparatus and method for transmitting information for a Multimedia Broadcast/Multicast Service (MBMS) is provided that facilitates a mobile communication device receiving a specific MBMS without any difficulty when the device moves from one area to another area. By providing MBMS status information to a controller in the area from which the device moved, the controller in the area from which the device moved can either establish an additional channel to provide the MBMS to the device or initiate a relocation of control of the device to a controller in the area into which the device has moved.
摘要:
The present invention provides a composition for forming a liquid crystal alignment film, which comprises a photoreactive polymer including a multicyclic compound having a photoreactive group on a main chain thereof. The present invention also provides a liquid crystal alignment film produced using the composition, and a liquid crystal display including the liquid crystal alignment film. The photoreactive polymer including the multicyclic compound on the main chain thereof has a high glass transition temperature, thus thermal stability is excellent. Since lattice vacancy is relatively large, the photoreactive group is capable of moving relatively freely in the main chain of the polymer, thus it is possible to improve a slow photoreaction rate, which is considered a disadvantage of a conventional polymer material.
摘要:
The present invention relates to transmitting data units of a radio protocol layer, wherein one logical channel identifier is added to one or more data units belonging to one logical channel. Because only one logical channel identifier is added to the data units belonging to one logical channel in constructing a MAC-e PDU, overheads of the MAC-e PDU are reduced. Such reduction of the PDU overheads increases data throughput, which is advantageous for a high-speed data communication system, such as the HSUPA.
摘要:
The present invention relates to transmitting and receiving a notification of control information for a point-to-multipoint service. Preferably, a mobile terminal receives notification information from a network during a first period. The mobile terminal then determines to receive a control channel during a second period for receiving a control information message according to the notification information. After, the mobile terminal receives the control information message for the point-to-multipoint service during the second period if the mobile terminal determines to receive the control information message during the second period.