公开(公告)号：US20070123666A1

公开(公告)日：2007-05-31

申请号：US11581470

申请日：2006-10-17

申请人： Young Chung ,  Il Jung ,  Sung Chun ,  Young Park ,  Dai Choi ,  Sung Yoon ,  TaeSun Lim ,  Jungmin Lee

发明人： Young Chung ,  Il Jung ,  Sung Chun ,  Young Park ,  Dai Choi ,  Sung Yoon ,  TaeSun Lim ,  Jungmin Lee

IPC分类号： C08F4/80

CPC分类号： C08F4/70 ,  C08F32/08

摘要： Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer represented by Formula 2 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic complex; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L′2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different, and wherein m is an integer of 0 to 4; and R7, R′7, R″7, and R″′7 are each independently a polar functional group or a nonpolar functional group. According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.

公开(公告)号：US20070093624A1

公开(公告)日：2007-04-26

申请号：US11542166

申请日：2006-10-04

申请人： Young Chung ,  Il Jung ,  Sung Chun ,  Young Park ,  Sung Yoon ,  TaeSun Lim ,  Jungmin Lee ,  Dai Choi

发明人： Young Chung ,  Il Jung ,  Sung Chun ,  Young Park ,  Sung Yoon ,  TaeSun Lim ,  Jungmin Lee ,  Dai Choi

IPC分类号： C08F4/80

CPC分类号： C07F15/006 ,  C08F4/7034 ,  C08F4/80

摘要： Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic precatalyst; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.

摘要翻译： 本发明提供一种通过下述式1表示的环状烯烃系单体的加成聚合制备环状烯烃系聚合物的金属催化剂配合物：＆lt;线内配方说明=“在线式”末端= “铅”？> [M（L 1）（L'2 ）（L _{（L 3）（L 3 >）Z是阳离子预催化剂; L 1是含阴离子烃基的配体; L'2是中性配体; L 3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2 <= x + y + z <= 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体，因此具有优异的热稳定性和反应性。}

公开(公告)号：US07868105B2

公开(公告)日：2011-01-11

申请号：US11581470

申请日：2006-10-17

申请人： Young Keun Chung ,  Il Gu Jung ,  Sung Ho Chun ,  Young Whan Park ,  Dai Seung Choi ,  Sung Cheol Yoon ,  TaeSun Lim ,  Jungmin Lee

发明人： Young Keun Chung ,  Il Gu Jung ,  Sung Ho Chun ,  Young Whan Park ,  Dai Seung Choi ,  Sung Cheol Yoon ,  TaeSun Lim ,  Jungmin Lee

IPC分类号： C08F4/06 ,  C08F4/12 ,  C08F4/16

CPC分类号： C08F4/70 ,  C08F32/08

摘要： Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer represented by Formula 2 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic complex; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L′2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different, and wherein m is an integer of 0 to 4; and R7, R′7, R″7, and R″′7 are each independently a polar functional group or a nonpolar functional group.According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.

摘要翻译： 提供一种通过环状烯烃单体的加成聚合制备环状烯烃聚合物的方法，该方法包括使由下述通式1表示的金属催化剂配合物与由下式2表示的环状烯烃单体接触：[M（L1）x（ L'2）y（L3）z] a [Ani] b式1其中M是X族金属; [M（L1）x（L'2）y（L3）z]是阳离子络合物; L1是含阴离子烃基的配体; L'2是中性配体; L3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2＆nlE; x + y + z＆nlE; 6; a和b分别是能够与金属M弱配位的阳离子数和阴离子数，并且各自为1-10，其用于满足金属催化剂络合物的净电荷平衡，并且其中对于每个 的L 1，L 2和L 3，当多个配体存在于金属催化剂配合物的分子中时，配体可以相同或不同，并且其中m为0-4的整数; 并且R 7，R'7，R“7和R”'7各自独立地为极性官能团或非极性官能团。 根据本发明的方法，即使使用含极性官能团的环状烯烃单体，也可以高产率地制造高分子量环状烯烃加成聚合物。 使用该方法制备的聚合物显示出良好的热稳定性。

公开(公告)号：US07863214B2

公开(公告)日：2011-01-04

申请号：US11542166

申请日：2006-10-04

申请人： Young Keun Chung ,  Il Gu Jung ,  Sung Ho Chun ,  Young Whan Park ,  Sung Cheol Yoon ,  TaeSun Lim ,  Jungmin Lee ,  Dai Seung Choi

发明人： Young Keun Chung ,  Il Gu Jung ,  Sung Ho Chun ,  Young Whan Park ,  Sung Cheol Yoon ,  TaeSun Lim ,  Jungmin Lee ,  Dai Seung Choi

IPC分类号： B01J27/24

CPC分类号： C07F15/006 ,  C08F4/7034 ,  C08F4/80

摘要： Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L1)x(L′2)y(L3)z]a[Ani]b   wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic precatalyst; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.

摘要翻译： 本发明提供一种金属催化剂配合物，其通过以下式1表示的环状烯烃系单体的加成聚合制备环状烯烃系聚合物：[M（L1）x（L'2）y（L3）z] a [Ani] b式1其中M是X族金属; [M（L1）x（L'2）y（L3）z]是阳离子预催化剂; L1是含阴离子烃基的配体; L'2是中性配体; L3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2＆nlE; x + y + z＆nlE; 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体，因此具有优异的热稳定性和反应性。