Polymerization methods using the catalysts

    公开(公告)号:US20070123666A1

    公开(公告)日:2007-05-31

    申请号:US11581470

    申请日:2006-10-17

    IPC分类号: C08F4/80

    CPC分类号: C08F4/70 C08F32/08

    摘要: Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer represented by Formula 2 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic complex; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L′2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different, and wherein m is an integer of 0 to 4; and R7, R′7, R″7, and R″′7 are each independently a polar functional group or a nonpolar functional group. According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.

    Catalysts for polymerizing cyclic olefin
    2.
    发明申请
    Catalysts for polymerizing cyclic olefin 有权
    用于聚合环烯烃的催化剂

    公开(公告)号:US20070093624A1

    公开(公告)日:2007-04-26

    申请号:US11542166

    申请日:2006-10-04

    IPC分类号: C08F4/80

    摘要: Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic precatalyst; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.

    摘要翻译: 本发明提供一种通过下述式1表示的环状烯烃系单体的加成聚合制备环状烯烃系聚合物的金属催化剂配合物:&lt;线内配方说明=“在线式”末端= “铅”?> [M(L 1)(L'2 )(L (L 3)(L 3 >)Z是阳离子预催化剂; L 1是含阴离子烃基的配体; L'2是中性配体; L 3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2 <= x + y + z <= 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体,因此具有优异的热稳定性和反应性。

    Elastomer spatial light modulators for extreme ultraviolet lithography
    3.
    发明申请
    Elastomer spatial light modulators for extreme ultraviolet lithography 有权
    用于极紫外光刻的弹性体空间光调制器

    公开(公告)号:US20050146768A1

    公开(公告)日:2005-07-07

    申请号:US10962055

    申请日:2004-10-08

    摘要: A new design and fabrication process of an elastomer spatial light modulator (eSLM). The present invention resolves many known challenges and enables the eSLM to operate as programmable masks for the EUV lithography systems. Bottom electrodes are deposited and patterned on an insulation layer. A sacrificial layer is then deposited, patterned and polished on top of the bottom electrodes. A nitride shell forms a protection layer that prevents out-gassing and degradations of elastomer during operations. The sacrificial layer is removed, forming a cavity. An elastomer is injected at one end of the cavity and pulled into it by capillary forces. In an embodiment, the eSLM comprises a 2-D array of elastomer pillars, each containing a capacitive actuator with an elastomer as the supporting and dielectric structure. A stack of Mo/Si multilayer mirror is deposited on the surface to achieve a high reflectivity about 70% or more in EUV.

    摘要翻译: 弹性体空间光调制器(eSLM)的新设计和制造工艺。 本发明解决了许多已知的挑战,使eSLM能够作为EUV光刻系统的可编程掩模来操作。 在绝缘层上沉积和图案化底电极。 然后在底部电极的顶部上沉积,图案化和抛光牺牲层。 氮化物壳形成保护层,其在操作期间防止弹性体的排气和降解。 去除牺牲层,形成空腔。 在空腔的一端注入弹性体,并通过毛细管力将其拉入。 在一个实施例中,eSLM包括弹性体柱的2-D阵列,每个阵列包含具有弹性体作为支撑和电介质结构的电容性致动器。 一层Mo / Si多层反射镜沉积在表面上,以实现在EUV中约70%或更高的高反射率。

    Air conditioner
    4.
    发明申请
    Air conditioner 有权
    冷气机

    公开(公告)号:US20060161305A1

    公开(公告)日:2006-07-20

    申请号:US11314015

    申请日:2005-12-22

    申请人: Il Jung

    发明人: Il Jung

    IPC分类号: G05D23/00

    摘要: Air conditioner including a temperature sensor for sensing a room temperature, a humidity sensor for sensing room humidity, a control unit for controlling to calculate well-being indices according to the room temperature or the room humidity sensed at the temperature sensor and the humidity sensor with reference to well-being index calculating data stored already, and to present the well-being index calculated thus, and well-being index related information corresponding to the well-being index, and output means for presenting the well-being index calculated thus, and the well-being index related information corresponding to the well-being index under the control of the control unit, thereby readily calculating well-being indices and providing information thereof by using an air conditioner provided to houses or offices without exception without requiring any extra equipment.

    摘要翻译: 包括用于感测室温的温度传感器,用于感测室内湿度的湿度传感器的空调器,用于根据在温度传感器和湿度传感器处检测到的室内温度或室内湿度来计算健康指数的控制单元, 提及已经存储的幸福指数计算数据,并呈现由此计算的幸福指数,以及与幸福指数相对应的幸福指数相关信息,以及用于呈现由此计算的健康指数的输出装置, 以及与控制单元控制下的健康指数相对应的幸福指数相关信息,从而容易地计算福利指数并通过使用提供给房屋或办公室的空调器提供信息而无需任何额外的 设备。

    Recombinant escherichia coli and overproduction method of polyhydroxybutyrate using the strain
    5.
    发明申请
    Recombinant escherichia coli and overproduction method of polyhydroxybutyrate using the strain 有权
    重组大肠杆菌和使用该菌株的多羟基丁酸盐的过量产生方法

    公开(公告)号:US20050227340A1

    公开(公告)日:2005-10-13

    申请号:US10998473

    申请日:2004-11-29

    CPC分类号: C12P7/62

    摘要: The present invention relates to a recombinant Escherichia coli having phbCAB originated from Alcaligenes eutrophus and an overproduction method of polyhydroxyalkanoate using the same, more precisely, a recombinant Escherichia coli ‘MG1655/pTZ18U-PHB’ or ‘JIL938/pTZ18U-PHB’ having phbCAB originated from Alcaligenes eutrophus and an overproduction method of polyhydroxyalkanoate comprising the steps of preparing transformed Escherichia coli having phbCAB originated from Alcaligenes eutrophus, inoculating and culturing the cells (growth phase), inducing the production of polyhydroxyalkanoate in the recomibnant Escherichia coli (stationary phase and producing phase), and inducing the extracellular secretion of the polyhydroxyalkanoate from the recombinant Escherichia coli. The method of the present invention facilitates not only overproduction of polyhydroxyalkanoate such as polyhydroxybutyrate by a simple batch culture but also industrial use of biodegradable polyhydroxyalkanoate replacing conventional non-biodegradable plastics by its simple and easy fermentation, separation and purification process.

    摘要翻译: 本发明涉及具有源自嗜碱性杆菌的phbCAB的重组大肠杆菌,以及使用该重组大肠杆菌的具有phbCAB的重组大肠杆菌MG1655 / pTZ18U-PHB'或'JIL938 / pTZ18U-PHB'的多羟基链烷酸酯的过量产生方法 来自产碱杆菌属的富含嗜碱性细菌的产生方法和多羟基链烷酸酯的过量产生方法,包括以下步骤:制备具有源自产碱杆菌属细菌的phbCAB的转化大肠杆菌,接种和培养细胞(生长期),诱导在大肠杆菌(稳定期和生产阶段)中产生聚羟基链烷酸酯 ),并诱导来自重组大肠杆菌的聚羟基链烷酸酯的细胞外分泌。 本发明的方法不仅通过简单的分批培养而不仅过度生产聚羟基链烷酸酯如聚羟基丁酸酯,而且还通过其简单且容易的发酵,分离和纯化方法替代常规的不可生物降解的塑料来生产可降解的聚羟基链烷酸酯的工业应用。