公开(公告)号：US20070123666A1

公开(公告)日：2007-05-31

申请号：US11581470

申请日：2006-10-17

Applicant: Young Chung ,  Il Jung ,  Sung Chun ,  Young Park ,  Dai Choi ,  Sung Yoon ,  TaeSun Lim ,  Jungmin Lee

Inventor： Young Chung ,  Il Jung ,  Sung Chun ,  Young Park ,  Dai Choi ,  Sung Yoon ,  TaeSun Lim ,  Jungmin Lee

IPC: C08F4/80

CPC classification number: C08F4/70 ,  C08F32/08

Abstract: Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer represented by Formula 2 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic complex; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L′2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different, and wherein m is an integer of 0 to 4; and R7, R′7, R″7, and R″′7 are each independently a polar functional group or a nonpolar functional group. According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.

公开(公告)号：US07868105B2

公开(公告)日：2011-01-11

申请号：US11581470

申请日：2006-10-17

Applicant: Young Keun Chung ,  Il Gu Jung ,  Sung Ho Chun ,  Young Whan Park ,  Dai Seung Choi ,  Sung Cheol Yoon ,  TaeSun Lim ,  Jungmin Lee

Inventor： Young Keun Chung ,  Il Gu Jung ,  Sung Ho Chun ,  Young Whan Park ,  Dai Seung Choi ,  Sung Cheol Yoon ,  TaeSun Lim ,  Jungmin Lee

IPC: C08F4/06 ,  C08F4/12 ,  C08F4/16

CPC classification number: C08F4/70 ,  C08F32/08

Abstract: Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer represented by Formula 2 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic complex; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L′2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different, and wherein m is an integer of 0 to 4; and R7, R′7, R″7, and R″′7 are each independently a polar functional group or a nonpolar functional group.According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.

Abstract translation: 提供一种通过环状烯烃单体的加成聚合制备环状烯烃聚合物的方法，该方法包括使由下述通式1表示的金属催化剂配合物与由下式2表示的环状烯烃单体接触：[M（L1）x（ L'2）y（L3）z] a [Ani] b式1其中M是X族金属; [M（L1）x（L'2）y（L3）z]是阳离子络合物; L1是含阴离子烃基的配体; L'2是中性配体; L3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2＆nlE; x + y + z＆nlE; 6; a和b分别是能够与金属M弱配位的阳离子数和阴离子数，并且各自为1-10，其用于满足金属催化剂络合物的净电荷平衡，并且其中对于每个 的L 1，L 2和L 3，当多个配体存在于金属催化剂配合物的分子中时，配体可以相同或不同，并且其中m为0-4的整数; 并且R 7，R'7，R“7和R”'7各自独立地为极性官能团或非极性官能团。 根据本发明的方法，即使使用含极性官能团的环状烯烃单体，也可以高产率地制造高分子量环状烯烃加成聚合物。 使用该方法制备的聚合物显示出良好的热稳定性。

公开(公告)号：US07814713B2

公开(公告)日：2010-10-19

申请号：US12654039

申请日：2009-12-08

Applicant: Sung Cheol Yoon ,  Young Chul Won ,  Young Whan Park ,  Sung Ho Chun ,  Dai Seung Choi ,  Won Kook Kim ,  Taesun Lim ,  Heon Kim ,  Jungmin Lee ,  Kyung Lim Paik

Inventor： Sung Cheol Yoon ,  Young Chul Won ,  Young Whan Park ,  Sung Ho Chun ,  Dai Seung Choi ,  Won Kook Kim ,  Taesun Lim ,  Heon Kim ,  Jungmin Lee ,  Kyung Lim Paik

IPC: B01J31/00 ,  C08F4/06

CPC classification number: C08F4/70

Abstract: A catalyst system capable of producing a cyclic olefin polymer having a polar functional group and a high molecular weight with a high yield in which a catalyst is not deactivated due to polar functional groups of monomers, and a method of producing polymers using the same are provided. The catalyst system for polymerization of olefin according to the present invention has good thermal and chemical stability, and thus, in the method of preparing polyolefin using the catalyst system, the deactivation of a catalyst due to a polar functional group of the monomer can be prevented, and thus a high yield of the cyclic olefin polymer with a high molecular weight can be obtained when a ratio of the catalyst to the monomer is 1:5000, and the removal of a catalyst residue is not required.

公开(公告)号：US20070093624A1

公开(公告)日：2007-04-26

申请号：US11542166

申请日：2006-10-04

Applicant: Young Chung ,  Il Jung ,  Sung Chun ,  Young Park ,  Sung Yoon ,  TaeSun Lim ,  Jungmin Lee ,  Dai Choi

Inventor： Young Chung ,  Il Jung ,  Sung Chun ,  Young Park ,  Sung Yoon ,  TaeSun Lim ,  Jungmin Lee ,  Dai Choi

IPC: C08F4/80

CPC classification number: C07F15/006 ,  C08F4/7034 ,  C08F4/80

Abstract: Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L1)x(L′2)y(L3)z]a[Ani]b    wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic precatalyst; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.

Abstract translation: 本发明提供一种通过下述式1表示的环状烯烃系单体的加成聚合制备环状烯烃系聚合物的金属催化剂配合物：＆lt;线内配方说明=“在线式”末端= “铅”？> [M（L 1）（L'2 ）（L _{（L 3）（L 3 >）Z是阳离子预催化剂; L 1是含阴离子烃基的配体; L'2是中性配体; L 3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2 <= x + y + z <= 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体，因此具有优异的热稳定性和反应性。}

公开(公告)号：US20060058477A1

公开(公告)日：2006-03-16

申请号：US11227093

申请日：2005-09-16

Applicant: Sung Yoon ,  Young Won ,  Young Park ,  Sung Chun ,  Dai Choi ,  Won Kim ,  Taesun Lim ,  Heon Kim ,  Jung Lee ,  Kyung Paik

Inventor： Sung Yoon ,  Young Won ,  Young Park ,  Sung Chun ,  Dai Choi ,  Won Kim ,  Taesun Lim ,  Heon Kim ,  Jung Lee ,  Kyung Paik

IPC: C08F4/06 ,  B01J31/00

CPC classification number: C08F4/70

Abstract: A catalyst system capable of producing a cyclic olefin polymer having a polar functional group and a high molecular weight with a high yield in which a catalyst is not deactivated due to polar functional groups of monomers, and a method of producing polymers using the same are provided. The catalyst system for polymerization of olefin according to the present invention has good thermal and chemical stability, and thus, in the method of preparing polyolefin using the catalyst system, the deactivation of a catalyst due to a polar functional group of the monomer can be prevented, and thus a high yield of the cyclic olefin polymer with a high molecular weight can be obtained when a ratio of the catalyst to the monomer is 1:5000, and the removal of a catalyst residue is not required.

Abstract translation: 提供一种催化剂体系，其能够制备具有极性官能团和高分子量的环状烯烃聚合物，其高产率，其中由于单体的极性官能团而不使催化剂失活，以及使用其制备聚合物的方法 。 本发明的烯烃聚合用催化剂体系具有良好的热稳定性和化学稳定性，因此在使用该催化剂体系的聚烯烃的制造方法中，可以防止由于单体的极性官能团引起的催化剂的失活 因此，当催化剂与单体的比例为1:5000时，可以获得高产率的具有高分子量的环状烯烃聚合物，并且不需要除去催化剂残余物。

公开(公告)号：US07863214B2

公开(公告)日：2011-01-04

申请号：US11542166

申请日：2006-10-04

Applicant: Young Keun Chung ,  Il Gu Jung ,  Sung Ho Chun ,  Young Whan Park ,  Sung Cheol Yoon ,  TaeSun Lim ,  Jungmin Lee ,  Dai Seung Choi

Inventor： Young Keun Chung ,  Il Gu Jung ,  Sung Ho Chun ,  Young Whan Park ,  Sung Cheol Yoon ,  TaeSun Lim ,  Jungmin Lee ,  Dai Seung Choi

IPC: B01J27/24

CPC classification number: C07F15/006 ,  C08F4/7034 ,  C08F4/80

Abstract: Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L1)x(L′2)y(L3)z]a[Ani]b   wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic precatalyst; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.

Abstract translation: 本发明提供一种金属催化剂配合物，其通过以下式1表示的环状烯烃系单体的加成聚合制备环状烯烃系聚合物：[M（L1）x（L'2）y（L3）z] a [Ani] b式1其中M是X族金属; [M（L1）x（L'2）y（L3）z]是阳离子预催化剂; L1是含阴离子烃基的配体; L'2是中性配体; L3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2＆nlE; x + y + z＆nlE; 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体，因此具有优异的热稳定性和反应性。

公开(公告)号：US20100174039A1

公开(公告)日：2010-07-08

申请号：US12654039

申请日：2009-12-08

Applicant: Sung Cheol Yoon ,  Young Chul Won ,  Young Whan Park ,  Sung He Chun ,  Dai Seung Choi ,  Won Kook Kim ,  Taesun Lim ,  Heon Kim ,  Jungmin Lee ,  Kyung Lim Paik

Inventor： Sung Cheol Yoon ,  Young Chul Won ,  Young Whan Park ,  Sung He Chun ,  Dai Seung Choi ,  Won Kook Kim ,  Taesun Lim ,  Heon Kim ,  Jungmin Lee ,  Kyung Lim Paik

IPC: C08F4/80

CPC classification number: C08F4/70

Abstract: A catalyst system capable of producing a cyclic olefin polymer having a polar functional group and a high molecular weight with a high yield in which a catalyst is not deactivated due to polar functional groups of monomers, and a method of producing polymers using the same are provided. The catalyst system for polymerization of olefin according to the present invention has good thermal and chemical stability, and thus, in the method of preparing polyolefin using the catalyst system, the deactivation of a catalyst due to a polar functional group of the monomer can be prevented, and thus a high yield of the cyclic olefin polymer with a high molecular weight can be obtained when a ratio of the catalyst to the monomer is 1:5000, and the removal of a catalyst residue is not required.

公开(公告)号：US07648937B2

公开(公告)日：2010-01-19

申请号：US11227093

申请日：2005-09-16

Applicant: Sung Cheol Yoon ,  Young Chul Won ,  Young Whan Park ,  Sung Ho Chun ,  Dai Seung Choi ,  Won Kook Kim ,  Taesun Lim ,  Heon Kim ,  Jungmin Lee ,  Kyung Lim Paik

Inventor： Sung Cheol Yoon ,  Young Chul Won ,  Young Whan Park ,  Sung Ho Chun ,  Dai Seung Choi ,  Won Kook Kim ,  Taesun Lim ,  Heon Kim ,  Jungmin Lee ,  Kyung Lim Paik

IPC: B01J31/00 ,  C08F4/06

CPC classification number: C08F4/70

Abstract: A catalyst system capable of producing a cyclic olefin polymer having a polar functional group and a high molecular weight with a high yield in which a catalyst is not deactivated due to polar functional groups of monomers, and a method of producing polymers using the same are provided. The catalyst system for polymerization of olefin according to the present invention has good thermal and chemical stability, and thus, in the method of preparing polyolefin using the catalyst system, the deactivation of a catalyst due to a polar functional group of the monomer can be prevented, and thus a high yield of the cyclic olefin polymer with a high molecular weight can be obtained when a ratio of the catalyst to the monomer is 1:5000, and the removal of a catalyst residue is not required.

Abstract translation: 提供一种催化剂体系，其能够制备具有极性官能团和高分子量的环状烯烃聚合物，其高产率，其中由于单体的极性官能团而不使催化剂失活，以及使用其制备聚合物的方法 。 本发明的烯烃聚合用催化剂体系具有良好的热稳定性和化学稳定性，因此在使用该催化剂体系的聚烯烃的制造方法中，可以防止由于单体的极性官能团引起的催化剂的失活 因此，当催化剂与单体的比例为1:5000时，可以获得高产率的具有高分子量的环状烯烃聚合物，并且不需要除去催化剂残余物。