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1.发明授权
公开(公告)号：US5932625A
公开(公告)日：1999-08-03
申请号：US865676
申请日：1997-05-30
IPC分类号： C08F2/44 , C08F2/46 , C08F2/48 , C08F222/10 , C08F226/06 , B27N3/08
CPC分类号： C08F226/06 , C08F2/44 , C08F2/48 , C08F222/1006
摘要： A photo-curable resin composition suitable as a material for photo-fabricating and capable of producing cured products with excellent mechanical strength and high heat resistance. Further disclosed is a process for molding a resin-based mold which provides superior molding dimensional precision and superb repetition durability. The resin composition contains a monomer component containing (A) 30-70 wt % of a polyfunctional unsaturated monomer having a cyclic structure and (B) 70-30 wt % of a monofunctional unsaturated monomer having a cyclic structure of which the homopolymer has a glass transition temperature (Tg) of 70.degree. C. or higher; (C) a photo-initiator; and (D) an inorganic filler having an average particle diameter or an average fiber length of 1-50 .mu.m, wherein the ratio of the inorganic filler to 100 parts by volume of the monomer components and the photo-initiator is 100-160 parts by volume, and the heat distortion temperature of the cured resin produced from the photo-curable resin composition is 100.degree. C. or higher.
摘要翻译： 适合作为光致制造材料的光固化性树脂组合物，能够制造具有优异的机械强度和高耐热性的固化物。 进一步公开了一种树脂基模具的成型方法，其提供优异的成型尺寸精度和极好的重复耐久性。 树脂组合物含有含有（A）30-70重量％的具有环状结构的多官能不饱和单体的单体成分，（B）70-30重量％具有均聚物具有玻璃的环状结构的单官能不饱和单体 转变温度（Tg）为70℃以上; （C）光引发剂; 和（D）平均粒径或平均纤维长度为1-50μm的无机填料，其中无机填料与100体积份单体组分和光引发剂的比例为100-160份 ，由光固化性树脂组合物制造的固化树脂的热变形温度为100℃以上。
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2.发明授权
公开(公告)号：US5874041A
公开(公告)日：1999-02-23
申请号：US865781
申请日：1997-05-30
IPC分类号： G03F7/004 , B29C33/40 , B29K33/04 , C08F2/44 , C08F2/48 , C08F20/34 , C08F20/36 , C08F220/10 , C08F222/10 , C09D4/00 , C09D4/02 , G03F7/027 , B29C35/08 , B29C41/02
CPC分类号： C08F222/1006
摘要： A photo-curable resin composition suitable as a material for optical molding. The composition can produce cured products with excellent mechanical strength and high heat resistance. Further disclosed is a process for molding a resin-based mold which provides superior molding dimensional precision and superb repetition durability. The composition contains a monomer component which contains (A) 20-80 wt % of a urethane-bond polyfunctional (meth)acrylate having a number average molecular weight of 1,000 or less and (B) 80-20 wt % of an ethylenically unsaturated monomer containing a cyclic structure and at least one ethylenically unsaturated bond in the molecule and of which the homopolymer has a glass transition temperature of 50.degree. C. or higher; (C) a photopolymerization initiator; and (D) an inorganic filler having an average particle diameter or an average fiber length of 1-50 .mu.m, wherein the ratio of the inorganic filler for 100 parts by volume of said monomer components and the photopolymerization initiator is 100-160 parts by volume, and the heat distortion temperature of the cured resin produced from the photo-curable resin composition is 80.degree. C. or higher.
摘要翻译： 适合作为光学成型用材料的光固化性树脂组合物。 该组合物可以产生具有优异的机械强度和高耐热性的固化产物。 进一步公开了一种树脂基模具的成型方法，其提供优异的成型尺寸精度和极好的重复耐久性。 该组合物含有（A）20〜80重量％的数均分子量为1000以下的氨基甲酸酯键多官能（甲基）丙烯酸酯，（B）80〜20重量％的烯属不饱和单体 在分子中含有环状结构和至少一个烯属不饱和键，其均聚物的玻璃化转变温度为50℃以上; （C）光聚合引发剂; 和（D）平均粒径或平均纤维长度为1-50μm的无机填料，其中100体积份的所述单体成分和光聚合引发剂的无机填料的比例为100〜160份 由光固化型树脂组合物制造的固化树脂的体积，热变形温度为80℃以上。
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公开(公告)号：US5976448A
公开(公告)日：1999-11-02
申请号：US198397
申请日：1998-11-24
IPC分类号： B29C35/08 , B29C45/02 , B29C67/00 , B29K105/16 , B29K105/24 , B29C41/02
CPC分类号： B29C67/0081
摘要： An optical forming apparatus which can form a homogeneous three-dimensional object exhibiting desired properties over all parts, while effectively suppressing sedimentation of filler even though the filler is easily precipitated in a photo-curable resin composition. The optical forming apparatus can produce a three-dimensional object consisting of laminated layers of cured resin produced by repetition of forming cured resin layers by selectively irradiating a photo-curable liquid resin composition placed in a container (20), wherein the apparatus is characterized by having a means (60) for circulating the photo-curable liquid resin composition.
摘要翻译： 即使填充剂易于在光固化树脂组合物中沉淀，也可以形成均匀的三维物体，从而在有效地抑制填料的沉淀的同时，形成均匀的三维物体。 光学成形装置可以通过选择性地照射放置在容器（20）中的光固化性液体树脂组合物，来制造由重复形成固化树脂层而制成的固化树脂层叠层的三维物体，其特征在于， 具有使可光固化液体树脂组合物循环的装置（60）。
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