公开(公告)号：US20100004401A1

公开(公告)日：2010-01-07

申请号：US12311034

申请日：2007-09-10

申请人： Yuichi Ito ,  Kazuki Mita ,  Ryoji Mori ,  Masahiko Okamoto ,  Toru Takehara ,  Masakazu Jitsukata ,  Hayato Kurita

发明人： Yuichi Ito ,  Kazuki Mita ,  Ryoji Mori ,  Masahiko Okamoto ,  Toru Takehara ,  Masakazu Jitsukata ,  Hayato Kurita

IPC分类号： C08L23/20

CPC分类号： C08L23/10 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/14 ,  C08L23/16 ,  C08L23/20 ,  C08L2205/03 ,  C08L2207/12 ,  C08L2312/00 ,  C08L2666/02

摘要： [Problem] A polyolefin composition comprising an olefin-based thermoplastic elastomer which is superior to conventional olefin-based thermoplastic elastomers in scratch resistance and abrasion resistance and has excellent heat aging resistance is proposed.[Means for Solving the Problem] A polyolefin composition comprising a syndiotactic α-olefin-based copolymer (A), a polyolefin resin (B) (other than polybutene (C)), polybutene (C), and if necessary, an ethylene-based copolymer rubber (D).

摘要翻译： [问题]提出了包含烯烃类热塑性弹性体的聚烯烃组合物，其耐刮擦性和耐磨性优于常规烯烃类热塑性弹性体，并且具有优异的耐热老化性。 解决问题的方法包含间同立构α-烯烃基共聚物（A），聚烯烃树脂（B）（聚丁烯（C）以外），聚丁烯（C）以及必要时的乙烯 - （D）。

公开(公告)号：US08008401B2

公开(公告)日：2011-08-30

申请号：US12311034

申请日：2007-09-10

申请人： Yuichi Ito ,  Kazuki Mita ,  Ryoji Mori ,  Masahiko Okamoto ,  Toru Takehara ,  Masakazu Jitsukata ,  Hayato Kurita

发明人： Yuichi Ito ,  Kazuki Mita ,  Ryoji Mori ,  Masahiko Okamoto ,  Toru Takehara ,  Masakazu Jitsukata ,  Hayato Kurita

IPC分类号： C08F8/00 ,  C08L9/00 ,  C08L23/04 ,  C08L45/00 ,  C08G18/42 ,  C09B67/00 ,  C08K5/00

CPC分类号： C08L23/10 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/14 ,  C08L23/16 ,  C08L23/20 ,  C08L2205/03 ,  C08L2207/12 ,  C08L2312/00 ,  C08L2666/02

摘要： A polyolefin composition comprising an olefin-based thermoplastic elastomer which is superior to conventional olefin-based thermoplastic elastomers in scratch resistance and abrasion resistance and has excellent heat aging resistance is proposed. [Means for Solving the Problem] A polyolefin composition comprising a syndiotactic α-olefin-based copolymer (A), a polyolefin resin (B) (other than polybutene (C)), polybutene (C), and if necessary, an ethylene-based copolymer rubber (D).

摘要翻译： 提出了一种包含烯烃类热塑性弹性体的聚烯烃组合物，其耐刮擦性和耐磨性优于常规烯烃类热塑性弹性体，并且具有优异的耐热老化性。 （解决问题的手段）包含间同立构α-烯烃类共聚物（A），聚烯烃树脂（B）（聚丁烯（C）以外），聚丁烯（C）以及必要时的乙烯 - （D）。

公开(公告)号：US08329821B2

公开(公告)日：2012-12-11

申请号：US13054736

申请日：2009-07-14

申请人： Hayato Kurita ,  Toru Takehara ,  Masakazu Jitsukata ,  Yuichi Ito

发明人： Hayato Kurita ,  Toru Takehara ,  Masakazu Jitsukata ,  Yuichi Ito

IPC分类号： C08F8/00 ,  C08L9/00 ,  C08L23/04

CPC分类号： B32B5/18 ,  B32B5/20 ,  B32B27/065 ,  B32B27/22 ,  B32B27/32 ,  B32B2262/101 ,  B32B2266/0207 ,  B32B2266/025 ,  B32B2270/00 ,  B32B2274/00 ,  B32B2307/718 ,  B32B2605/003 ,  C08J9/0061 ,  C08J9/06 ,  C08J2323/10 ,  C08J2323/16 ,  C08J2423/00 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08L2205/02 ,  Y10T156/10 ,  Y10T428/249993 ,  C08L2666/02 ,  C08L2666/04

摘要： [Problem] To provide a thermoplastic elastomer composition for foaming, which has sufficient foamability and provides a molded article having good appearance. [Solution to Problem] A thermoplastic elastomer composition for foaming, which comprises 10 to 40% by weight of a partially or completely crosslinked ethylene/α-olefin/non-conjugated polyene copolymer rubber (A) comprising ethylene, an α-olefin of 3 to 20 carbon atoms and a non-conjugated polyene, 3 to 33% by weight of an ethylene/α-olefin copolymer (B) comprising ethylene and an α-olefin of 3 to 20 carbon atoms, 10 to 40% by weight of polypropylene (C) having a melting point, as determined by differential scanning calorimetry (DSC), of 40 to 170° C., 10 to 45% by weight of a softener (D) for rubbers, and at least one substance selected from an isotactic propylene-based polymer (E-a) in an amount of 1 to 30% by weight and a syndiotactic α-olefin-based copolymer (E-b) in an amount of 1 to 20% by weight, with the proviso that the total amount of the components (A), (B), (C), (D), (E-a) and (E-b) is 100% by weight.

摘要翻译： [问题]提供一种发泡性的热塑性弹性体组合物，其具有足够的发泡性并提供具有良好外观的模塑制品。 [问题的解决方案]一种用于发泡的热塑性弹性体组合物，其包含10至40重量％的部分或完全交联的乙烯/α-烯烃/非共轭多烯共聚物橡胶（A），其包含乙烯，3链的α-烯烃 至20个碳原子和非共轭多烯，3-33重量％的乙烯和3-20个碳原子的α-烯烃的乙烯/α-烯烃共聚物（B），10-40重量％的聚丙烯 （C）通过差示扫描量热法（DSC）测定的熔点为40〜170℃，10〜45重量％的用于橡胶的软化剂（D），以及选自全同立构的至少一种物质 量为1〜30重量％的丙烯系聚合物（Ea）和1〜20重量％的间同立构α-烯烃系共聚物（Eb），前提条件是组分 （A），（B），（C），（D），（Ea）和（Eb）为100重量％。

公开(公告)号：US07041718B2

公开(公告)日：2006-05-09

申请号：US10655034

申请日：2003-09-05

申请人： Hatsuhiko Harashina ,  Hayato Kurita ,  Tatsuya Yamada

发明人： Hatsuhiko Harashina ,  Hayato Kurita ,  Tatsuya Yamada

IPC分类号： C08K5/34

CPC分类号： C08K5/3445 ,  C08L59/00

摘要： The polyacetal resin composition contains about 0.01–10 parts by weight of a glyoxyldiureide compound per 100 parts by weight of polyacetal resin. The glyoxyldiureide compound includes glyoxyldiureide and its derivatives (metal salts etc.). Optionally, about 0.01–10 parts by weight of a basic nitrogen-containing compound is further added. The basic nitrogen-containing compound includes melamine, melamine resin, and polyamide resin. Further, an antioxidant may be further added. The above composition contributes to stability, particularly heat stability, of polyacetal resin and suppression of emission of formaldehyde.

公开(公告)号：US07186766B2

公开(公告)日：2007-03-06

申请号：US10609411

申请日：2003-07-01

申请人： Hatsuhiko Harashina ,  Hayato Kurita

发明人： Hatsuhiko Harashina ,  Hayato Kurita

IPC分类号： C08K5/3417 ,  C08K5/04 ,  C08K5/98 ,  C08K5/34

CPC分类号： C08K5/13 ,  C08K5/175 ,  C08L59/00

摘要： About 0.001 to 1 part by weight of a phenol component (B1) and/or about 0.001 to 10 parts by weight of an amino acid (B2) are added relative to 100 parts by weight of a polyacetal resin (A) to prepare a polyacetal resin composition. The phenol component (B1) may be a novolak phenol-series resin, a phenol aralkyl-series resin, a polyvinyl phenol-series resin, a polyhydric phenol, a polyphenol, a catechin compound, or a lignin. The amino acid (B2) may be an α-amino acid, a β-amino acid, a γ-amino acid, a δ-amino acid, or a derivative of an amino acid. The polyacetal resin composition may further contain an antioxidant, a heat stabilizer, a processing stabilizer, a weather (light)-resistant stabilizer, or a coloring agent. The polyacetal resin composition ensures marked inhibition of formaldehyde emission.

摘要翻译： 相对于100重量份聚缩醛树脂（A），添加约0.001〜1重量份的苯酚成分（B1）和/或约0.001〜10重量份的氨基酸（B2），以制备聚缩醛 树脂组合物。 苯酚成分（B1）可以是酚醛清漆酚系树脂，苯酚芳烷基系树脂，聚乙烯基苯酚系树脂，多元酚，多酚，儿茶素化合物或木质素。 氨基酸（B2）可以是α-氨基酸，β-氨基酸，γ-氨基酸，δ-氨基酸或氨基酸的衍生物。 聚缩醛树脂组合物还可以含有抗氧化剂，热稳定剂，加工稳定剂，耐候（耐光性）稳定剂或着色剂。 聚缩醛树脂组合物确保甲醛释放的显着抑制。

公开(公告)号：US07183340B2

公开(公告)日：2007-02-27

申请号：US10538121

申请日：2003-12-24

申请人： Hatsuhiko Harashina ,  Hayato Kurita

发明人： Hatsuhiko Harashina ,  Hayato Kurita

IPC分类号： C08K5/04 ,  C08K5/09 ,  C08K5/3492

CPC分类号： C08L59/00 ,  C08K5/3492

摘要： About 0.001 to 5 parts by weight of an antioxidant and about 0.001 to 10 parts by weight of a guanamine compound having at least one unit represented by the following formula (1) or a salt thereof relative to 100 parts by weight of a polyacetal resin are mixed and constitute a resin composition. The resin composition may further comprise a processing stabilizer, a heat stabilizer, a weather-resistant stabilizer, a coloring agent, a gloss control agent, an impact resistance improver, a slide improver, a filler, and/or the like. Wherein R1 and R2 are the same or different and each represents a hydrogen atom or an alkyl group, and “m” denotes an integer of not less than 2.

摘要翻译： 相对于100重量份的聚缩醛树脂，约0.001〜5重量份的抗氧化剂和约0.001〜10重量份的具有至少一个下式（1）表示的单元的胍胺化合物或其盐， 混合并构成树脂组合物。 树脂组合物还可以包含加工稳定剂，热稳定剂，耐候稳定剂，着色剂，光泽调节剂，耐冲击性改进剂，载片改进剂，填料等。 其中R 1和R 2相同或不同，各自表示氢原子或烷基，“m”表示不小于2的整数。

公开(公告)号：US20090234050A1

公开(公告)日：2009-09-17

申请号：US12063045

申请日：2006-08-09

申请人： Shogo Wada ,  Hayato Kurita

发明人： Shogo Wada ,  Hayato Kurita

IPC分类号： C08K5/3492

CPC分类号： C08K5/25 ,  C08K5/103 ,  C08K5/3492 ,  C08L59/00

摘要： Provided is a polyoxymethylene resin composition which has excellent molding characteristics (releasing property and molding cycle) and suppresses the generation of formaldehyde. Specifically the polyoxymethylene resin composition is prepared by blending (A) 100 parts by weight of a polyacetal copolymer containing 1 mmol/kg or less of hemiformal terminal, mmol/kg or less of formyl terminal, and 0.5% by weight or less of unstable terminal; (B) 0.01 to 20 parts by weight of one or a mixture of two or more of a guanamine compound (b-1) and a hydrazide compound (b-2); and (C) 0.1 to 5 parts by weight of an ester compound having 50% or more of esterification percentage.

摘要翻译： 提供具有优异的成型特性（脱模性和成型周期）并抑制甲醛的产生的聚甲醛树脂组合物。 具体地说，聚甲醛树脂组合物通过将（A）100重量份含有1mmol / kg以下的半缩醛末端，mmol / kg以下的甲酰末端和0.5重量％以下的不稳定末端的聚缩醛共聚物 ; （B）0.01至20重量份的胍胺化合物（b-1​​）和酰肼化合物（b-2）中的一种或两种或更多种的混合物; 和（C）0.1〜5重量份具有50％以上酯化率的酯化合物。

公开(公告)号：US20060052492A1

公开(公告)日：2006-03-09

申请号：US10538121

申请日：2003-12-24

申请人： Hatsuhiko Harashina ,  Hayato Kurita

发明人： Hatsuhiko Harashina ,  Hayato Kurita

IPC分类号： C08K5/34

CPC分类号： C08L59/00 ,  C08K5/3492

摘要： About 0.001 to 5 parts by weight of an antioxidant and about 0.001 to 10 parts by weight of a guanamine compound having at least one unit represented by the following formula (1) or a salt thereof relative to 100 parts by weight of a polyacetal resin are mixed and constitute a resin composition. The resin composition may further comprise a processing stabilizer, a heat stabilizer, a weather-resistant stabilizer, a coloring agent, a gloss control agent, an impact resistance improver, a slide improver, a filler, and/or the like. Wherein R1 and R2 are the same or different and each represents a hydrogen atom or an alkyl group, and “m” denotes an integer of not less than 2.

摘要翻译： 相对于100重量份的聚缩醛树脂，约0.001〜5重量份的抗氧化剂和约0.001〜10重量份的具有至少一个下式（1）表示的单元的胍胺化合物或其盐， 混合并构成树脂组合物。 树脂组合物还可以包含加工稳定剂，热稳定剂，耐候稳定剂，着色剂，光泽调节剂，耐冲击性改进剂，载片改进剂，填料等。

公开(公告)号：US20050075429A1

公开(公告)日：2005-04-07

申请号：US10655034

申请日：2003-09-05

申请人： Hatsuhiko Harashina ,  Hayato Kurita ,  Tatsuya Yamada

发明人： Hatsuhiko Harashina ,  Hayato Kurita ,  Tatsuya Yamada

IPC分类号： C08K5/3445 ,  C08K5/29

CPC分类号： C08K5/3445 ,  C08L59/00

摘要： The polyacetal resin composition contains about 0.01-10 parts by weight of a glyoxyldiureide compound per 100 parts by weight of polyacetal resin. The glyoxyldiureide compound includes glyoxyldiureide and its derivatives (metal salts etc.). Optionally, about 0.01-10 parts by weight of a basic nitrogen-containing compound is further added. The basic nitrogen-containing compound includes melamine, melamine resin, and polyamide resin. Further, an antioxidant may be further added. The above composition contributes to stability, particularly heat stability, of polyacetal resin and suppression of emission of formaldehyde.

摘要翻译： 聚缩醛树脂组合物每100重量份的聚缩醛树脂含有约0.01〜10重量份的乙醛酰二酰脲化合物。 乙醛酰二酰脲化合物包括乙醛酰二酰脲及其衍生物（金属盐等）。 任选地，还加入约0.011-10重量份的含碱性的含氮化合物。 碱性含氮化合物包括三聚氰胺，三聚氰胺树脂和聚酰胺树脂。 此外，可以进一步添加抗氧化剂。 上述组合物有助于聚缩醛树脂的稳定性，特别是热稳定性和抑制甲醛排放。

公开(公告)号：US5679284A

公开(公告)日：1997-10-21

申请号：US661712

申请日：1996-06-11

申请人： Hayato Kurita

发明人： Hayato Kurita

IPC分类号： C08K5/524 ,  C08K5/134 ,  C08K5/527 ,  C08L67/00 ,  C08L67/02 ,  C08L77/12 ,  C09K19/52 ,  C09K19/00

CPC分类号： C08K5/1345 ,  C08K5/527 ,  C08L67/00 ,  Y10T428/105 ,  Y10T428/1077

摘要： An improved synthetic resin composition is provided that consists essentially of 100 parts by weight of a resin component composed of in excess of 50 up to 99 parts by weight of a liquid crystal polyester resin (A) capable of forming an anisotropic melt phase, and 1 up to less than 50 parts by weight of a polyalkylene terephthalate resin (B), to which has been added 0.001 to 5 parts by weight of a phosphorus ester (C) (e.g., a pentaerythritol phosphite). The presence of the phosphorus ester in the specifically defined polymer blend has been found to greatly impede the formation of deleterious mold deposits, and to make possible the formation of quality molded articles on an expeditious basis having good mechanical properties.

摘要翻译： 提供了一种改进的合成树脂组合物，其基本上由100重量份的由超过50至99重量份的能够形成各向异性熔融相的液晶聚酯树脂（A）组成的树脂组分和1 最多少于50重量份的聚对苯二甲酸亚烷基酯树脂（B），向其中加入0.001-5重量份的磷酯（C）（例如季戊四醇亚磷酸酯）。 已经发现特定定义的聚合物共混物中磷酯的存在极大地妨碍了有害的模具沉积物的形成，并且使得有可能在具有良好机械性能的基础上快速形成优质模制品。