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    Process for producing acrylic elastomer
    1.
    发明授权
    Process for producing acrylic elastomer 失效
    丙烯酸弹性体的制造方法

    公开(公告)号：US5252678A

    公开(公告)日：1993-10-12

    申请号：US966845

    申请日：1992-10-27

    申请人： Yuichi Yamamoto ,  Kazuma Yokoi ,  Haruyoshi Tatsu

    发明人： Yuichi Yamamoto ,  Kazuma Yokoi ,  Haruyoshi Tatsu

    IPC分类号： C08F2/38 ,  C08F220/12 ,  C08F220/28 ,  C08F8/08 ,  C08F4/34

    CPC分类号： C08F220/12 ,  C08F220/28

    摘要： An acrylic elastomer capable of giving a vulcanization product having a distinguished tensile strength and a good stretching even by cross-linking with an organic peroxide can be obtained by using an organic peroxide having a non-conjugated double bond as a polymerization initiator in polymerization of at least one of (a) alkyl acrylates having an alkyl group of 1 to 8 carbon atoms and (b) alkoxyalkyl acrylates having an alkoxylalkyl group of 2 to 8 carbon atoms.

    摘要翻译： 能够通过使用具有非共轭双键的有机过氧化物作为聚合引发剂在聚合反应中得到具有显着拉伸强度和拉伸强度的硫化产物的丙烯酸类弹性体， （a）具有1至8个碳原子的烷基的丙烯酸烷基酯和（b）具有2至8个碳原子的烷氧基烷基的丙烯酸烷氧基烷基酯的至少一种。

    Process for producing acrylic elastomer
    2.
    发明授权
    Process for producing acrylic elastomer 失效
    丙烯酸弹性体的制造方法

    公开(公告)号：US5194540A

    公开(公告)日：1993-03-16

    申请号：US728892

    申请日：1992-07-11

    申请人： Yuichi Yamamoto ,  Kazuma Yokoi ,  Haruyoshi Tatsu

    发明人： Yuichi Yamamoto ,  Kazuma Yokoi ,  Haruyoshi Tatsu

    IPC分类号： C08F2/38 ,  C08F4/32 ,  C08F4/34 ,  C08F220/12 ,  C08F220/18

    CPC分类号： C08F4/32 ,  C08F220/12 ,  C08F220/18 ,  C08F2220/1808

    摘要： An acrylic elastomer capable of giving a vulcanization product having a distinguished tensile strength and a good stretching even by cross-linking with an organic peroxide can be obtained by using an organic peroxide having a non-conjugated double bond as a polymerization initiator in polymerization of at least one of (a) alkyl acrylates having an alkyl group of 1 to 8 carbon atoms and (b) alkoxyalkyl acrylates having an alkoxyalkyl grouop of 2 to 8 carbon atoms.

    摘要翻译： 能够通过使用具有非共轭双键的有机过氧化物作为聚合引发剂在聚合反应中得到具有显着拉伸强度和拉伸强度的硫化产物的丙烯酸类弹性体， （a）具有1至8个碳原子的烷基的丙烯酸烷基酯和（b）具有2至8个碳原子的烷氧基烷基团团的烷氧基烷基丙烯酸酯的至少一种。

    Vulcanizable, fluorine-containing elastomer composition
    4.
    发明授权
    Vulcanizable, fluorine-containing elastomer composition 失效
    可硫化的含氟弹性体组合物

    公开(公告)号：US5334667A

    公开(公告)日：1994-08-02

    申请号：US172730

    申请日：1993-12-27

    申请人： Yuichi Yamamoto ,  Haruyoshi Tatsu

    发明人： Yuichi Yamamoto ,  Haruyoshi Tatsu

    IPC分类号： C07F1/08 ,  C08F8/42 ,  C08K5/00 ,  C08K5/17 ,  C08K5/29 ,  C08L27/12

    CPC分类号： C08K5/0025 ,  C08F8/42 ,  C08K5/0091

    摘要： By using salicylaldoimino copper complex having the following formula as a cross-linking agent for a fluorine-containing elastomer containing at least one of iodine and bromine in the molecule, a vulcanization product with an improved heat resistance can be obtained and generation of harmful substances such as methyl iodine, methyl bromine, etc. can be made less at the cross-linking: ##STR1##

    摘要翻译： 通过在分子中使用具有下式的水杨醛缩氨基铜络合物作为含有碘和溴中的至少一种的含氟弹性体的交联剂，可以获得具有改善的耐热性的硫化产物，并产生有害物质 作为甲基碘，甲基溴等可以在交联时减少：

    Fluorine-containing elastomer composition
    6.
    发明授权
    Fluorine-containing elastomer composition 失效
    含氟弹性体组合物

    公开(公告)号：US5874506A

    公开(公告)日：1999-02-23

    申请号：US834521

    申请日：1997-04-04

    申请人： Haruyoshi Tatsu ,  Akihiro Naraki ,  Yuichi Yamamoto

    发明人： Haruyoshi Tatsu ,  Akihiro Naraki ,  Yuichi Yamamoto

    IPC分类号： C08F214/22 ,  C08F14/22 ,  C08K5/00 ,  C08K5/13 ,  C08L27/16 ,  C08F8/30

    CPC分类号： C08K5/0025

    摘要： A fluorine-containing elastomer comprising vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene having a high fluorine content (e.g. at least 68% by weight) can be vulcanized with a polyol-based cross-linking agent by further copolymerizing 2H-pentafluoropropylene into the elastomer, whereby the resulting vulcanization products having improved characteristics such as rheological properties, normal state physical properties and compression set can be obtained. Vulcanization products obtained by vulcanization with a polyol-based cross-linking agent and a quaternary onium salt compound have a good permeation resistance to fuel oil as a result of a permeation test with a mixed solvent of gasoline/methanol in a volume ratio of 85/15.

    摘要翻译： 包含氟含量高（例如至少68重量％）的偏二氟乙烯，四氟乙烯和六氟丙烯的含氟弹性体可以通过将二氢五氟丙烯进一步共聚合到弹性体中而用多元醇系交联剂硫化， 可以获得具有改进特性的硫化产品，如流变特性，正常状态物理性能和压缩永久变形。 通过用多元醇系交联剂和季鎓盐化合物硫化获得的硫化产物通过汽油/甲醇的混合溶剂的体积比为85/10的渗透试验，对燃料油具有良好的耐渗透性， 15。

    Process for producing peroxide-vulcanizable, fluorine-containing elastomer
    7.
    发明授权
    Process for producing peroxide-vulcanizable, fluorine-containing elastomer 失效
    生产过氧化物可硫化的含氟弹性体的方法

    公开(公告)号：US5225504A

    公开(公告)日：1993-07-06

    申请号：US986580

    申请日：1992-12-07

    申请人： Haruyoshi Tatsu ,  Masashi Fukazawa ,  Yuichi Yamamoto

    发明人： Haruyoshi Tatsu ,  Masashi Fukazawa ,  Yuichi Yamamoto

    IPC分类号： C08F4/40 ,  C08F2/38 ,  C08F14/16 ,  C08F214/16 ,  C08F214/18

    CPC分类号： C08F214/184

    摘要： A fluorine-containing elastomer capable of giving a primary vulcanization product with a good permanent set through peroxide vulcanization is produced by homopolymerization or copolymerization of a fluorine-containing olefin having 2 to 8 carbon atoms in the presence of an iodine and bromine-containing compound represented by the general formula RBrnIm, wherein R represents a fluorohydrocarbon group, a chlorofluorohydrocarbon group, a chlorohydrocarbon group or a hydrocarbon group, and n and m each are integers of 1 and 2, and a small amount of perfluoro(vinylether) compound having a general formula of CF.sub.2 .dbd.CFO[CF.sub.2 CF(CF.sub.3)O]m(CF.sub.2)nX, wherein X is a bromine atom or an iodine atom and m and n each are 1, 2 or 3.

    摘要翻译： 能够通过过氧化物硫化得到具有良好永久变形性的初级硫化产物的含氟弹性体是通过在含碘和含溴化合物的存在下，通过含2-8个碳原子的含氟烯烃的均聚或共聚来制备的 通式为RBrnIm，其中R表示氟代烃基，氯氟烃基，氯代烃基或烃基，n和m各自为1和2的整数，少量的具有一般的全氟（乙烯基醚）化合物 CF 2 = CFO [CF 2 CF（CF 3）O] m（CF 2）n X的化合物，其中X为溴原子或碘原子，m和n各自为1,2或3。