摘要:
The present invention provides a method of producing a tetracyanoborate-containing ionic compound in a milder condition more efficiently and less expensively than conventional methods, and a tetracyanoborate-containing ionic compound having a reduced content of impure components. An ionic compound of the present invention is represented by the following general formula (I), has a content of fluorine atom-containing impurities of 3 mol % or less per 100 mol % of the ionic compound, and a method for producing an ionic compound represented by the general formula (I) of the present invention comprises a step of reacting starting materials containing a cyanide and a boron compound. (In the formula, Ktm+ denotes an organic cation [Ktb]m+ or an inorganic cation [Ke]m+; and m denotes an integer of 1 to 3.)
摘要翻译:本发明提供了一种以比常规方法更有效和低成本地更温和的方式制备含四氰基硼酸盐的离子化合物的方法,以及具有降低的不纯成分含量的含四氰基硼酸盐的离子化合物。 本发明的离子性化合物由下述通式(I)表示,相对于每100摩尔%的离子性化合物,含有氟原子的杂质含量为3摩尔%以下,以及离子性化合物的制造方法 由本发明的通式(I)表示的方法包括使含有氰化物和硼化合物的原料反应的步骤。 (式中,Ktm +表示有机阳离子[Ktb] m +或无机阳离子[Ke] m +,m表示1〜3的整数)
摘要:
The present invention provides a method of producing a tetracyanoborate-containing ionic compound in a milder condition more efficiently and less expensively than conventional methods, and a tetracyanoborate-containing ionic compound having a reduced content of impure components. An ionic compound of the present invention is represented by the following general formula (I), has a content of fluorine atom-containing impurities of 3 mol % or less per 100 mol % of the ionic compound, and a method for producing an ionic compound represented by the general formula (I) of the present invention comprises a step of reacting starting materials containing a cyanide and a boron compound. (In the formula, Ktm+ denotes an organic cation [Ktb]m+ or an inorganic cation [Ke]m+; and m denotes an integer of 1 to 3.)
摘要翻译:本发明提供了一种以比常规方法更有效和低成本地更温和的方式制备含四氰基硼酸盐的离子化合物的方法,以及具有降低的不纯成分含量的含四氰基硼酸盐的离子化合物。 本发明的离子性化合物由下述通式(I)表示,相对于每100摩尔%的离子性化合物,含有氟原子的杂质含量为3摩尔%以下,以及离子性化合物的制造方法 由本发明的通式(I)表示的方法包括使含有氰化物和硼化合物的原料反应的步骤。 (式中,Ktm +表示有机阳离子[Ktb] m +或无机阳离子[Ke] m +,m表示1〜3的整数)
摘要:
A lithium-ion capacitor includes a non-aqueous electrolyte solution that includes (A) a compound represented by the following general formula (1), (B) a cyclic carbonate ester that includes at least one carbon-carbon unsaturated bond, and (C) a carboxylic ester, the non-aqueous electrolyte solution having a ratio (MB/MC) of 0.001 to 0.5, the ratio (MB/MC) being the ratio of the content (MB) (mmol/g) of the cyclic carbonate ester (B) to the content (MC) (mmol/g) of the carboxylic ester (C). Z+.[X(CN)m(Y)n]− (1) wherein X is at least one element selected from boron, aluminum, silicon, phosphorus, and arsenic, Y is a halogen, Z is lithium or magnesium, m is an integer from 3 to 6, and n is an integer from 0 to 5, provided that m+n≧3.
摘要:
The present invention provides an ionic compound which: can exert excellent basic performance such as excellent electrochemical stability including an excellent ionic conductivity; is excellent in pH stability; and can suitably find use in a variety of applications, and an electrolyte material, an electrolytic solution, and an electrolytic capacitor each containing the ionic compound. Anionic compound of the present invention has an anion represented by a general formula (1) and a cation represented by a general formula (2): where X represents an element selected from B, C, N, O, Al, Si, P, S, As, and Se, M1 and M2 represent linking groups, Q represents a monovalent element or organic group, a represents an integer of 1 or more, and b, c, d, and e each represent an integer of 0 or more; Rs-LH⊕ (2) where L represents an element selected from C, Si, N, P, S, and O, R represents a monovalent element, functional group, or organic group, and s represents an integer of 2, 3, or 4.
摘要:
An ionic compound is provided that has an anion represented by a: formula (1) and a cation represented by a formula (2): where X is an element selected from the group consisting of B, C, N, O, Al, Si, P, S, As, and Se, M1 and M2 are identical or different, and represent linking groups, and, when multiple M1s or multiple M2s are present, they may be identical or different, Q represents a monovalent element or organic group, a represents an integer of 1 or more, and b, c, d, and a each represent an integer of 0 or more; and RS-LH⊕(2) where L is an element selected from the group consisting of C, Si, N, P, S, and 0, R represents a monovalent element, functional group, or organic group, and s represents an integer of 2 to 4.
摘要:
Provide is an aluminum electrolytic capacitor exhibiting low specific resistance and low impedance property and realizing high reliability. An electrolytic capacitor has a structure in which: a capacitor element which is formed by rolling an anode foil and a cathode foil each connected with an electrode extraction lead through a separator and which is impregnated with a drive electrolytic solution is included in a cylindrical outer case having a closed-end; and an open end of the outer case is sealed with an elastic sealing body, in which: the drive electrolytic solution contains a tricyanomethide salt represented by the below-indicated chemical formula (1); and the drive electrolytic solution has a water content of 3.0 wt % or less: where, R represents a cation pairing with a tricyanomethide ion in formation of a tricyanomethide salt.
摘要:
Provide is an aluminum electrolytic capacitor exhibiting low specific resistance and low impedance property and realizing high reliability. An electrolytic capacitor has a structure in which: a capacitor element which is formed by rolling an anode foil and a cathode foil each connected with an electrode extraction lead through a separator and which is impregnated with a drive electrolytic solution is included in a cylindrical outer case having a closed-end; and an open end of the outer case is sealed with an elastic sealing body, in which: the drive electrolytic solution contains a tricyanomethide salt represented by the below-indicated chemical formula (1); and the drive electrolytic solution has a water content of 3.0 wt % or less: where, R represents a cation pairing with a tricyanomethide ion in formation of a tricyanomethide salt.
摘要:
The present invention provides an ionic compound containing a cyanoborate; a process for production thereof; and an electrolytic solution and a device. The electrolytic solution comprises an ionic compound represented by general formula (1) and a solvent, Mn+([B(CN)4-mYm]−)n (1) wherein Mn+ represents an organic or inorganic cation having a valency of 1 to 3; Y represents a halogen, a hydrocarbon group which has a main chain having 1 to 10 carbon atoms and which may optionally contain a halogen, —C(O)R14, —S(O)lR14, —Z(R14)2, or —XR14; R14 represents H, a halogen, or an organic substituent group which has a main chain having 1 to 10 atoms; Z represents N or P; X represents O or S; R13 represents H, or an hydrocarbon group which has a main chain having 1 to 10 atoms; l represents an integer of 1 to 2; m and n represent an integer of 1 to 3 respectively.
摘要:
The present invention provides an ionic compound containing a cyanoborate; a process for production thereof; and an electrolytic solution and a device, each utilizing the ionic compound. The electrolytic solution of the present invention comprises an ionic compound represented by general formula (1) and a solvent. Further, a production process of the present invention comprises reacting a compound represented by general formula (8) with a substitution reaction reagent to obtain a compound represented by general formula (1). Mn+([B(CN)4-mYm]−)n (1) Mn+([B(CN)4-m(XR13)m]−)n (8) (wherein, Mn+ represents an organic or inorganic cation having a valency of 1 to 3; Y represents a halogen, a hydrocarbon group which has a main chain having 1 to 10 carbon atoms and which may optionally contain a halogen, —C(O)R14, —S(O)lR14, —Z(R14)2, or —XR14; R14 represents H, a halogen, or an organic substituent group which has a main chain having 1 to 10 atoms; Z represents N or P; X represents O or S; R13 represents H, or an hydrocarbon group which has a main chain having 1 to 10 atoms; l represents an integer of 1 to 2; m and n represent an integer of 1 to 3 respectively)
摘要翻译:本发明提供了含有氰基硼酸盐的离子化合物; 其生产方法; 以及各自使用离子化合物的电解液和器件。 本发明的电解液含有通式(1)表示的离子性化合物和溶剂。 此外,本发明的制造方法包括使通式(8)表示的化合物与取代反应试剂反应,得到通式(1)表示的化合物。 Mn +([B(CN)4-mYm] - )n(1)Mn +([B(CN)4-m(XR13)m] - )n(8)(其中,Mn +表示具有 化合价为1至3; Y表示卤素,具有1至10个碳原子的主链且可任选含有卤素,-C(O)R 14,-S(O)1 R 14,-Z( R 14)2或-XR 14; R 14表示H,卤素或具有1〜10个原子的主链的有机取代基; Z表示N或P; X表示O或S; R 13表示H,或烃 基团,其具有1至10个原子的主链; l表示1至2的整数; m和n分别表示1至3的整数)