公开(公告)号：US20110224107A1

公开(公告)日：2011-09-15

申请号：US13112032

申请日：2011-05-20

Applicant: Olusegun M. Falana ,  Aziz Hikem ,  Sarkis R. Kakadjian ,  Frank Zamora

Inventor： Olusegun M. Falana ,  Aziz Hikem ,  Sarkis R. Kakadjian ,  Frank Zamora

IPC: C09K8/52

CPC classification number: C07C255/05

Abstract: Hydrolyzed nitrilotriacetonitrile compositions are disclosed prepared by a method characterized by a one-shot addition of an amount of nitrilotriacetonitrile to a solution containing an acid catalyst, where the reaction is complete in a time period of less than an hour. The method is also characterized by adjusting the pH of the reaction mixture to a pH of at least 8. The method is also characterized by oxidatively removing free cyanide to a desired low level through the addition of an oxidizing agent the produces environmentally benign by-products to the crude hydrolyzed NTAN to form hydrolyzed NTAN compositions having minimized, negligible, or substantially no free cyanide levels.

Abstract translation: 公开了水解的次氮基三乙腈组合物，其通过以下方法制备，其特征在于将一定量的次氮基三乙腈一次性加入到含有酸催化剂的溶液中，其中反应在少于1小时的时间内完成。 该方法的特征还在于将反应混合物的pH调节至至少8的pH。该方法的特征还在于通过加入产生环境友好的副产物的氧化剂将游离氰化物氧化去除所需的低水平 到粗水解的NTAN以形成具有最小化，可忽略或基本上没有游离氰化物水平的水解的NTAN组合物。

公开(公告)号：US20030114700A1

公开(公告)日：2003-06-19

申请号：US10236904

申请日：2002-09-09

Applicant: BASF Akiengesellschaft

Inventor： Thomas Greindl ,  Gerold Braun ,  Friedrich Wirsing ,  Georg Krug

IPC: C07C253/20

CPC classification number: C07C253/00 ,  Y02P20/582 ,  C07C255/04 ,  C07C255/05

Abstract: The invention relates to a continuous process, carried out in two steps, for the cyanoalkylation of compounds having one or more NH functions by reaction thereof with carbonyl compounds and hydrocyanic acid, in which the first step is carried out without pressure at a temperature which is below the boiling point of the reaction mixture.

公开(公告)号：US20020007081A1

公开(公告)日：2002-01-17

申请号：US09893858

申请日：2001-06-28

Inventor： Michael Schelhaas ,  Manfred Jautelat

IPC: C07C255/02

CPC classification number: C07C253/00 ,  C07C255/05

Abstract: The present invention relates to a process for producing tricarbonitriles corresponding to formula I 1 wherein n is an integer from 2 to 11 by forming an intermediate in the presence of a strong base in a first stage from an aliphatic null-null-dinitrile corresponding to formula II 2 wherein n is an integer from 3 to 12, and reacting the intermediate in a second stage to form a trinitrile corresponding to formula I by the addition of acrylonitrile.

Abstract translation: 本发明涉及一种制备相应于式Ⅰ的三羰基腈的方法，其中n为2至11的整数，通过在第一阶段中在强碱存在下由相应于式II的脂族α-ω-二腈形成中间体 其中n为3-12的整数，并在第二阶段使中间体与丙烯腈相加形成对应于式I的三腈。

公开(公告)号：US08362298B2

公开(公告)日：2013-01-29

申请号：US13112012

申请日：2011-05-20

Applicant: Olusegun M. Falana ,  Aziz Hikem ,  Sarkis R. Kakadjian ,  Frank Zamora

Inventor： Olusegun M. Falana ,  Aziz Hikem ,  Sarkis R. Kakadjian ,  Frank Zamora

IPC: C07C55/22

CPC classification number: C07C255/05

Abstract: Hydrolyzed nitrilotriacetonitrile compositions are disclosed prepared by a method characterized by a one-shot addition of an amount of nitrilotriacetonitrile to a solution containing an acid catalyst, where the reaction is complete in a time period of less than an hour. The method is also characterized by adjusting the pH of the reaction mixture to a pH of at least 8. The method is also characterized by oxidatively removing free cyanide to a desired low level through the addition of an oxidizing agent the produces environmentally benign by-products to the crude hydrolyzed NTAN to form hydrolyzed NTAN compositions having minimized, negligible, or substantially no free cyanide levels.

Abstract translation: 公开了水解的次氮基三乙腈组合物，其通过以下方法制备，其特征在于将一定量的次氮基三乙腈一次性加入到含有酸催化剂的溶液中，其中反应在少于1小时的时间内完成。 该方法的特征还在于将反应混合物的pH调节至至少8的pH。该方法的特征还在于通过加入产生环境友好的副产物的氧化剂将游离氰化物氧化去除所需的低水平 到粗水解的NTAN以形成具有最小化，可忽略或基本上没有游离氰化物水平的水解的NTAN组合物。

公开(公告)号：US08222445B2

公开(公告)日：2012-07-17

申请号：US12529697

申请日：2008-08-15

Applicant: Harald Strittmatter ,  Stefan Koger

Inventor： Harald Strittmatter ,  Stefan Koger

IPC: C07C255/05 ,  C07C255/06 ,  C07C253/04

CPC classification number: C07C253/04 ,  C07C253/34 ,  C07C255/05

Abstract: The present invention relates to an industrially usable process for preparing alkali metal and alkaline earth metal tricyanomethanides in particularly high purity.

Abstract translation: 本发明涉及工业上可用于制备特别高纯度的碱金属和碱土金属三氰基甲烷化物的方法。

公开(公告)号：US08022242B2

公开(公告)日：2011-09-20

申请号：US12310601

申请日：2007-08-16

Applicant: Christoph Täschler ,  Andreas Breuer

Inventor： Christoph Täschler ,  Andreas Breuer

IPC: C07C255/05 ,  C07C255/06

CPC classification number: C07C253/04 ,  C07C253/32 ,  C07C255/05

Abstract: The present invention relates to a process for preparing highly pure alkali metal or alkaline earth metal tricyanomethanides.

Abstract translation: 本发明涉及制备高纯碱金属或碱土金属三氰基甲烷的方法。

公开(公告)号：US11721838B2

公开(公告)日：2023-08-08

申请号：US17217211

申请日：2021-03-30

Applicant: Ningde Amperex Technology Limited

Inventor： Jian Liu ,  Wenqiang Li ,  Jianming Zheng ,  Xiexue Peng

IPC: H01M10/0567 ,  H01M10/0569 ,  H01M10/0568 ,  H01M10/0525 ,  H01M4/525 ,  C07F5/02 ,  C07C261/02 ,  C07C255/04 ,  C07C255/03 ,  C07C255/05 ,  C07C317/28 ,  H01M4/02

CPC classification number: H01M10/0567 ,  C07C255/03 ,  C07C255/04 ,  C07C255/05 ,  C07C261/02 ,  C07C317/28 ,  C07F5/027 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/028 ,  H01M2300/004

Abstract: An electrolyte including an additive of compound of formula I,






wherein n is an integer ranging from 0 to 10;
R1 and R2 are each independently selected from a substituted or unsubstituted C1-C10 alkylidene group, a substituted or unsubstituted C2-C10 alkenylene group, or a substituted or unsubstituted C1-C10 alkyleneoxy group; A1 selected from CH, C, N, S, O, B or Si; A2 is selected from CH—R3, N—R3, S, O, B—R3 or SiH—R3; A3 selected from CH2, CH, C, N, S, O, B or Si; R3 is selected from hydrogen, halogen, a substituted or unsubstituted C1-C10 alkyl group, or a substituted or unsubstituted C3-C10 cycloalkyl group; X1 is selected from a substituted or unsubstituted C1-C10 alkylidene group, a substituted or unsubstituted C2-C10 alkenylene group, ═Rc═, or ═Rc—, wherein Rc is selected from a substituted or unsubstituted C2-C6 alkylidene group.

公开(公告)号：US20110218125A1

公开(公告)日：2011-09-08

申请号：US13112012

申请日：2011-05-20

Applicant: Olusegun M. Falana ,  Aziz Hikem ,  Sarkis R. Kakadjian ,  Frank Zamora

Inventor： Olusegun M. Falana ,  Aziz Hikem ,  Sarkis R. Kakadjian ,  Frank Zamora

IPC: C09K8/52

CPC classification number: C07C255/05

Abstract: Hydrolyzed nitrilotriacetonitrile compositions are disclosed prepared by a method characterized by a one-shot addition of an amount of nitrilotriacetonitrile to a solution containing an acid catalyst, where the reaction is complete in a time period of less than an hour. The method is also characterized by adjusting the pH of the reaction mixture to a pH of at least 8. The method is also characterized by oxidatively removing free cyanide to a desired low level through the addition of an oxidizing agent the produces environmentally benign by-products to the crude hydrolyzed NTAN to form hydrolyzed NTAN compositions having minimized, negligible, or substantially no free cyanide levels.

公开(公告)号：US06861548B2

公开(公告)日：2005-03-01

申请号：US10236904

申请日：2002-09-09

Applicant: Thomas Greindl ,  Gerold Braun ,  Friedrich Wirsing ,  Georg Krug

Inventor： Thomas Greindl ,  Gerold Braun ,  Friedrich Wirsing ,  Georg Krug

IPC: C07C253/00 ,  C07C255/04 ,  C07C255/05 ,  C07C253/22

CPC classification number: C07C253/00 ,  Y02P20/582 ,  C07C255/04 ,  C07C255/05

Abstract: The invention relates to a continuous process, carried out in two steps, for the cyanoalkylation of compounds having one or more NH functions by reaction thereof with carbonyl compounds and hydrocyanic acid, in which the first step is carried out without pressure at a temperature which is below the boiling point of the reaction mixture.

Abstract translation: 本发明涉及通过与羰基化合物和氢氰酸反应使其具有一个或多个NH官能团的化合物的氰基烷基化进行两步的连续方法，其中第一步在没有压力的情况下在温度为 低于反应混合物的沸点。

公开(公告)号：US06790976B2

公开(公告)日：2004-09-14

申请号：US09893858

申请日：2001-06-28

Applicant: Michael Schelhaas ,  Manfred Jautelat

Inventor： Michael Schelhaas ,  Manfred Jautelat

IPC: C07C25300

CPC classification number: C07C253/00 ,  C07C255/05

Abstract: The present invention relates to a process for producing tricarbonitriles corresponding to formula I wherein n is an integer from 2 to 11 by forming an intermediate in the presence of a strong base in a first stage from an aliphatic &agr;-&ohgr;-dinitrile corresponding to formula II wherein n is an integer from 3 to 12, and reacting the intermediate in a second stage to form a trinitrile corresponding to formula I by the addition of acrylonitrile.

Abstract translation: 本发明涉及一种制备相应于式I的方法，其中n为2至11的整数，通过在第一阶段中在强碱存在下，形成对应于式II的脂族α-ω-二腈的中间体，其中n为 3至12的整数，并在第二阶段使中间体反应，通过加入丙烯腈形成对应于式I的三腈。