公开(公告)号：US5333234A

公开(公告)日：1994-07-26

申请号：US931365

申请日：1992-08-18

申请人： Yutaka Hashimoto ,  Jun Shirakami ,  Masayuki Kamei ,  Shoshiro Taneichi ,  Makoto Ichinose

发明人： Yutaka Hashimoto ,  Jun Shirakami ,  Masayuki Kamei ,  Shoshiro Taneichi ,  Makoto Ichinose

IPC分类号： C03C25/10 ,  C08F2/50 ,  G02B1/04 ,  C08F220/24

CPC分类号： C03C25/105 ,  G02B1/048

摘要： The present invention provides a curable composition for use in optical fiber cladding comprising 48.8.about.92.9 wt % of 2-(perfluorooctyl) ethyl acrylate (I), 1.3.about.23.8 wt % of 2,2,3,3-tetrafluoroproprylacrylate (II), 5.0.about.30.0 wt % of trimethylolpropane triacrylate (III), and 0.1.about.5.0 wt % of photopolymerization initiator (IV), wherein the weight ratio [(I)/(II)] of monomer (I) and monomer (II) is within a range of from 75/25 to 98/2, and an optical fiber having cladding formed by the hardening of this curable composition and a core comprising quartz.

摘要翻译： 本发明提供一种用于光纤包覆的可固化组合物，其包含48.8％的92.9％（重量）的2-（全氟辛基）丙烯酸乙酯（I），1.3％（重量）的2,2,3,3-四氟丙烯酸丙酯（II），23.8％ 5.0差异30.0重量％的三羟甲基丙烷三丙烯酸酯（III）和0.1分子5.0重量％的光聚合引发剂（IV），其中单体（I）和单体（II）的重量比[（I）/（II）]在 75/25至98/2的范围，以及通过该可固化组合物的硬化形成的包层的光纤和包含石英的芯。

公开(公告)号：US5302316A

公开(公告)日：1994-04-12

申请号：US827212

申请日：1992-01-30

申请人： Yutaka Hashimoto ,  Jun Shirakami ,  Masayuki Kamei

发明人： Yutaka Hashimoto ,  Jun Shirakami ,  Masayuki Kamei

IPC分类号： C03C25/24 ,  C03C25/10 ,  C08F20/10 ,  C08F20/22 ,  C08F220/20 ,  C08F220/22 ,  C08F220/24 ,  C09D4/00 ,  G02B1/04 ,  G02B6/44 ,  C09K3/00

CPC分类号： G02B1/048 ,  C03C25/105 ,  C09D4/00

摘要： A curing composition comprising (1) a fluorine-containing curing monomer containing a fluorinated alkyl group having not less than 6 carbon atoms, (2) a fluorine-containing curing monomer containing a fluorinated alkyl group having not more than 5 carbon atoms, and (3) a polyfunctional curing monomer, the weight ratio of said fluorine-containing curing monomer (1) to said fluorine-containing curing monomer (2) ranging from 75/25 to 99/1. The composition is coated on an optical fiber base and cured by active energy rays to provide a core/clad optical fiber excellent in transparency, mechanical strength, environmental resistance, and optical characteristics.

摘要翻译： 一种固化组合物，其包含（1）含有不少于6个碳原子的氟化烷基的含氟固化单体，（2）含有不多于5个碳原子的氟化烷基的含氟固化单体和（ 3）多官能固化单体，所述含氟固化单体（1）与所述含氟固化单体（2）的重量比为75/25至99/1。 将该组合物涂布在光纤基材上并通过活性能量线固化，得到透明性，机械强度，耐环境性和光学特性优异的芯/包层光纤。

公开(公告)号：USRE39423E1

公开(公告)日：2006-12-12

申请号：US08624354

申请日：1996-04-11

申请人： Yutaki Hashimoto ,  Jun Shirakami ,  Masayuki Kamei

发明人： Yutaki Hashimoto ,  Jun Shirakami ,  Masayuki Kamei

IPC分类号： C09K3/00

CPC分类号： G02B1/048 ,  C03C25/105 ,  C09D4/00 ,  C08L33/16 ,  C08F220/22

摘要： A curing composition comprising (1) a fluorine-containing curing monomer containing a fluorinated alkyl group having not less than 6 carbon atoms, (2) a fluorine-containing curing monomer containing a fluorinated alkyl group having not more than 5 carbon atoms, and (3) a polyfunctional curing monomer, the weight ratio of said fluorine-containing curing monomer (1) to said fluorine-containing curing monomer (2) ranging from 75/25 to 99/1. The composition is coated on an optical fiber base and cured by active energy rays to provide a core/clad optical fiber excellent in transparency, mechanical strength, environmental resistance, and optical characteristics.

摘要翻译： 一种固化组合物，其包含（1）含有不少于6个碳原子的氟化烷基的含氟固化单体，（2）含有不多于5个碳原子的氟化烷基的含氟固化单体和（ 3）多官能固化单体，所述含氟固化单体（1）与所述含氟固化单体（2）的重量比为75/25至99/1。 将该组合物涂布在光纤基材上并通过活性能量线固化，得到透明性，机械强度，耐环境性和光学特性优异的芯/包层光纤。

公开(公告)号：US4431595A

公开(公告)日：1984-02-14

申请号：US301413

申请日：1981-09-11

申请人： Yutaka Hashimoto ,  Masayuki Kamei ,  Toshihiko Umaba ,  Tadashi Ito

发明人： Yutaka Hashimoto ,  Masayuki Kamei ,  Toshihiko Umaba ,  Tadashi Ito

IPC分类号： C11D1/92 ,  B01F17/00 ,  B01F17/24 ,  B01F17/26 ,  B01F17/38 ,  B01F17/42 ,  C07C67/00 ,  C07C301/00 ,  C07C309/14 ,  C07C309/45 ,  C07C143/02

CPC分类号： B01F17/0057 ,  Y10S516/05 ,  Y10S516/91

摘要： A fluorine-containing aminosulfonate of the general formulaR.sub.f -Q.sub.l -N(R.sub.1)-Q.sub.2 -N(R.sub.2)-Q.sub.3 -SO.sub.3 Mwherein R.sub.f represents a perfluorinated aliphatic group having 3 to 16 carbon atoms; Q.sub.1 represents --CH.sub.2 --.sub.h in which h represents an integer of 1 to 6, --CH.sub.2 CH.sub.2 Z--.sub.i in which Z represents --O-- or --S--, and i represents an integer of 1 to 4, ##STR1## or a combination of these; Q.sub.2 and Q.sub.3 are identical or different and each represents --CH.sub.2 --.sub.j in which j represents an integer of 1 to 6, ##STR2## in which R.sub.3 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, or ##STR3## M represents a hydrogen atom, an alkali metal atom, an alkaline earth methal atom, or --N(H).sub.m (R.sub.4).sub.n in which R.sub.4 represents an alkyl group having 1 to 3 carbon atoms, and m and n represent 0 or an integer of 1 to 4 provided that m+n=4; R.sub.1 represents a hydrogen atom or an alkyl group having 1 to 12 carbon atoms; and R.sub.2 represents a hydrogen atom, an alkyl or hydroxyalkyl group having 1 to 4 carbon atoms, --Q.sub.3 SO.sub.3 M in which Q.sub.3 and M are as defined, or --CH.sub.2 --.sub.k COOM in which M is as defined and k represents an integer of 1 to 4.

摘要翻译： 通式为Rf-Q1-N（R1）-Q2-N（R2）-Q3-SO3M的含氟氨基磺酸盐，其中Rf表示具有3至16个碳原子的全氟化脂族基团; Q1表示-CH2-h，其中h表示1〜6的整数，Z表示-O-或-S-的-CH 2 CH 2 Z-i，i表示1〜4的整数，或者 这些; Q2和Q3相同或不同，各自表示-CH2-j，其中j表示1至6的整数，其中R 3表示氢原子或具有1至4个碳原子的烷基，或 M表示氢原子，碱金属原子，碱土金属原子或其中R 4表示具有1至3个碳原子的烷基的-N（H）m（R 4）n，m和n表示0或 1〜4的整数，只要m + n = 4; R1表示氢原子或碳原子数1〜12的烷基。 R2表示氢原子，碳原子数1〜4的烷基或羟烷基，其中Q3和M如上所定义的-Q3SO3M或其中M定义为-CH2-kCOOM，k表示1〜4的整数 。

公开(公告)号：US4786658A

公开(公告)日：1988-11-22

申请号：US18398

申请日：1987-02-25

申请人： Yutaka Hashimoto ,  Masayuki Kamei ,  Toshihiko Umaba

发明人： Yutaka Hashimoto ,  Masayuki Kamei ,  Toshihiko Umaba

IPC分类号： C03C25/10 ,  C08F2/46 ,  C08F2/50 ,  C08F265/04 ,  C08F265/06 ,  C08F259/08

CPC分类号： C08F265/06 ,  C03C25/105 ,  C08F265/04

摘要： An active energy ray-curable resin composition which gives a cured product having a refractive index of not more than 1.44 comprises (I) a fluorine-containing polymer composed of (A) and at least one of (B) and (C): (A) a fluorine-containing (meth)acrylate, (B) an alpha,beta-ethylenically unsaturated dicarboxylic acid ester and (C) a mono(meth)acrylate and having a fluorine atom content of at least 30% by weight, (II) a fluorine-containing (meth)acrylate, (III) a mono(meth)acrylate and (IV) a polyfunctional monomer containing at least two (meth)acryloyl groups in the molecule. Optical fibers are produced by coating the above composition on a core material and irradiating active energy rays onto the coating to form a cured cladding of the composition.

摘要翻译： 给出折射率不大于1.44的固化产物的活性能量射线固化树脂组合物包含（I）由（A）和（B）和（C）中的至少一种组成的含氟聚合物：（I） A）含氟（甲基）丙烯酸酯，（B）α，β-烯属不饱和二羧酸酯和（C）单（甲基）丙烯酸酯，其氟原子含量为至少30重量％ ）含氟（甲基）丙烯酸酯，（III）单（甲基）丙烯酸酯和（Ⅳ）分子中含有至少两个（甲基）丙烯酰基的多官能单体。 通过将上述组合物涂覆在芯材上并将活性能量射线照射到涂层上以形成组合物的固化包层来生产光纤。

公开(公告)号：US4536298A

公开(公告)日：1985-08-20

申请号：US480213

申请日：1983-03-30

申请人： Masayuki Kamei ,  Tomio Endo ,  Yutaka Hashimoto

发明人： Masayuki Kamei ,  Tomio Endo ,  Yutaka Hashimoto

IPC分类号： A62D1/02 ,  A62D1/04 ,  A62C1/12

CPC分类号： A62D1/0071 ,  A62D1/0085

摘要： An aqueous foam fire extinguisher comprising (A) a surface-active agent having an anionic hydrophilic group, (B) a cationic water-soluble polymeric substance, and, optionally, (C) a polybasic acid compound.

摘要翻译： 一种水性泡沫灭火器，其包含（A）具有阴离子亲水基团的表面活性剂，（B）阳离子水溶性聚合物质，和任选地（C）多元酸化合物。

公开(公告)号：US5684079A

公开(公告)日：1997-11-04

申请号：US795162

申请日：1991-11-19

申请人： Masanobu Yumoto ,  Tsutomu Imai ,  Hiromu Chano ,  Torao Higuchi ,  Yutaka Hashimoto ,  Masayuki Kamei

发明人： Masanobu Yumoto ,  Tsutomu Imai ,  Hiromu Chano ,  Torao Higuchi ,  Yutaka Hashimoto ,  Masayuki Kamei

IPC分类号： C04B41/48 ,  C09D4/00 ,  C08K3/20

CPC分类号： C04B41/483 ,  C04B41/48 ,  C09D4/00

摘要： A curing composition for reinforcing an inorganic oxide material or a flawable base is disclosed. The composition comprises a curing compound emulsified and dispersed in water with or without the aid of an emulsifier or a water-soluble high polymer. The composition has excellent preservation stability and is free from the risk of fire or environmental pollution. The process for reinforcing an inorganic oxide material or a flawable base using the composition is also disclosed.

摘要翻译： 公开了一种用于增强无机氧化物材料或可挠性基材的固化组合物。 组合物包含在乳化剂或水溶性高聚物的帮助下乳化并分散在水中的固化化合物。 该组合物具有优异的保存稳定性，无火灾或环境污染的风险。 还公开了使用该组合物增强无机氧化物材料或可裂化碱的方法。

公开(公告)号：US4884866A

公开(公告)日：1989-12-05

申请号：US236736

申请日：1988-08-26

申请人： Yutaka Hashimoto ,  Masayuki Kamei ,  Toshihiko Umaba

发明人： Yutaka Hashimoto ,  Masayuki Kamei ,  Toshihiko Umaba

IPC分类号： C03C25/10 ,  C08F2/46 ,  C08F2/50 ,  C08F265/04 ,  C08F265/06

CPC分类号： C08F265/06 ,  C03C25/105 ,  C08F265/04

摘要： An active energy ray-curable resin composition which gives a cured product having a refractive index of not more than 1.44 comprises (I) a fluorine-containing polymer composed of (A) and at least one of (B) and (C): (A) a fluorine-containing (meth)acrylate, (B) an alpha,beta-ethylenically unsaturated dicarboxylic acid ester and (C) a mono(meth)acrylate and having a fluorine atom content of at least 30% by weight, (II) a fluorine-containing (meth)acrylate, (III) a mono(meth)acrylate and (IV) a polyfunctional monomer containing at least two (meth)acryloyl groups in the molecule. Optical fibers are produced by coating the above composition on a core material and irradiating active energy rays onto the coating to form a cured cladding of the composition.

公开(公告)号：US20060209478A1

公开(公告)日：2006-09-21

申请号：US11358045

申请日：2006-02-22

申请人： Katsuya Arai ,  Toshihiro Kougami ,  Masayuki Kamei

发明人： Katsuya Arai ,  Toshihiro Kougami ,  Masayuki Kamei

IPC分类号： H02H9/00

CPC分类号： H01L27/0262

摘要： A semiconductor integrated circuit device includes: a protected circuit protected against electro-static discharge applied from outside the device; an SCR protection circuit having an anode terminal connected to a power line, a cathode terminal connected to a ground line and a trigger terminal; and a trigger circuit connected to the trigger terminal and including an RC circuit connected between the power line and the ground line.

摘要翻译： 一种半导体集成电路器件，包括：保护电路，用于防止从器件外部施加的静电放电; SCR保护电路，其具有连接到电力线的阳极端子，连接到接地线的阴极端子和触发端子; 以及连接到触发端子并且包括连接在电力线和接地线之间的RC电路的触发电路。

公开(公告)号：US07440248B2

公开(公告)日：2008-10-21

申请号：US11358045

申请日：2006-02-22

申请人： Katsuya Arai ,  Toshihiro Kougami ,  Masayuki Kamei

发明人： Katsuya Arai ,  Toshihiro Kougami ,  Masayuki Kamei

IPC分类号： H02H3/20 ,  H02H3/22 ,  H02H9/04

CPC分类号： H01L27/0262

摘要： A semiconductor integrated circuit device includes: a protected circuit protected against electro-static discharge applied from outside the device; an SCR protection circuit having an anode terminal connected to a power line, a cathode terminal connected to a ground line and a trigger terminal; and a trigger circuit connected to the trigger terminal and including an RC circuit connected between the power line and the ground line.

摘要翻译： 一种半导体集成电路器件，包括：保护电路，用于防止从器件外部施加的静电放电; SCR保护电路，其具有连接到电力线的阳极端子，连接到接地线的阴极端子和触发端子; 以及连接到触发端子并且包括连接在电力线和接地线之间的RC电路的触发电路。