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公开(公告)号:US20220259345A1
公开(公告)日:2022-08-18
申请号:US17626067
申请日:2020-07-17
Applicant: ZEON CORPORATION
Inventor: Hirofumi MASUDA , Takafumi KAWANAKA
IPC: C08F220/10 , C08K3/02 , C08K3/04
Abstract: Acrylic rubber bale excellent in storage stability and processability, a method for producing the same, a rubber mixture obtained by mixing the acrylic rubber bale, and a cross-linked product of the rubber mixture are provided. The acrylic rubber bale includes an acrylic rubber having a reactive group and a weight average molecular weight (Mw) of 100,000 to 5,000,000, wherein an amount of gel insoluble in methyl ethyl ketone is 60% by weight or less, and a specific gravity is 0.8 or more.
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公开(公告)号:US20220259347A1
公开(公告)日:2022-08-18
申请号:US17625803
申请日:2020-06-05
Applicant: ZEON CORPORATION
Inventor: Hirofumi MASUDA , Takafumi KAWANAKA
IPC: C08F220/18 , C08K3/04
Abstract: An acrylic rubber excellent in water resistance and a method for producing the same are provided. An acrylic rubber composed of: 70 to 99.9 wt % of a bonding unit derived from (meth) acrylic acid ester; 0.1 to 10 wt % of a bonding unit derived from a cross-linkable monomer; and if necessary, 0 to 20 wt % of a bonding unit derived from another monomer, wherein the ash content is 0.5 wt % or less, the total amount of magnesium and phosphorus in the ash is 30 wt % or more, a ratio of the magnesium to the phosphorus ([Mg]/[P]) by weight is 0.4 to 2.5, and Mooney viscosity (ML1+4, 100° C.) of the rubber is 10 to 150 is particularly excellent in water resistance, and a rubber cross-linked product using the same is also excellent in physical properties.
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公开(公告)号:US20220235190A1
公开(公告)日:2022-07-28
申请号:US17626439
申请日:2020-06-05
Applicant: ZEON CORPORATION
Inventor: Hirofumi MASUDA , Takafumi KAWANAKA
Abstract: An acrylic rubber sheet excellent in storage stability and processability, a method for producing the same, an acrylic rubber bale obtained by laminating the sheets, a mixture obtained by mixing the acrylic rubber sheet and the acrylic rubber bale, a method for producing the mixture and a rubber cross-linking product obtained by cross-linking the mixture. The acrylic rubber sheet comprises, an acrylic rubber mainly composed of a (meth) acrylic acid ester and having a weight average molecular weight (Mw) of 100,000 to 5,000,000 and a ratio (Mz/Mw) of a Z-average molecular weight (Mz) and a weight average molecular weight (Mw) is 1.3 or more, and the acrylic rubber sheet contains a phenolic anti-aging agent, and a gel amount is 50 wt % or less. The acrylic rubber sheet is extremely excellent in storage stability and processability and the sheet can be easily produced by the claimed method.
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公开(公告)号:US20220315683A1
公开(公告)日:2022-10-06
申请号:US17626633
申请日:2020-06-05
Applicant: ZEON CORPORATION
Inventor: Hirofumi MASUDA , Takafumi KAWANAKA
IPC: C08F220/18 , C08F220/28 , C08F220/44 , C08F216/14 , C08F2/26 , C08F6/22 , B29C48/00 , C08K3/04 , C08K5/18
Abstract: Acrylic rubber bale excellent in storage stability and processability, a method for producing the same, a rubber mixture obtained by mixing the acrylic rubber bale, and a cross-linked product of the rubber mixture are provided. The acrylic rubber bale includes an acrylic rubber having a reactive group and a weight average molecular weight (Mw) of 100,000 to 5,000,000, wherein an amount of gel insoluble in methyl ethyl ketone is 50% by weight or less, and a specific gravity is 0.8 or more.
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公开(公告)号:US20220259348A1
公开(公告)日:2022-08-18
申请号:US17626780
申请日:2020-06-05
Applicant: ZEON CORPORATION
Inventor: Hirofumi MASUDA , Takafumi KAWANAKA
IPC: C08F220/18 , C08F6/00 , C08F6/22 , C08L13/00 , C08L33/08 , B29B11/12 , B29C43/36 , B29C48/00 , B29C48/07 , B29C48/505 , B29C48/88 , B29C48/92
Abstract: An acrylic rubber bale excellent in strength properties and processability, a method for producing the same, a rubber mixture containing the acrylic rubber bale, a method for producing the same, and a rubber cross-linked product of the same. The acrylic rubber bale includes an acrylic rubber mainly containing a (meth) acrylic acid ester having a weight average molecular weight (Mw) of 1,000,000 to 5,000,000, and a ratio (Mz/Mw) of a Z-average molecular weight (Mz) and a weight average molecular weight (Mw) is 1.3 or more, wherein an amount of gel insoluble in methyl ethyl ketone is 50% by weight or less.
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公开(公告)号:US20230159682A1
公开(公告)日:2023-05-25
申请号:US17626020
申请日:2020-06-05
Applicant: ZEON CORPORATION
Inventor: Hirofumi MASUDA , Takafumi KAWANAKA
IPC: C08F220/18 , C08F220/28 , C08F222/16 , C08F2/26 , C08F6/00 , C08F6/22 , C08F6/16 , C08K5/134 , B29C48/00
CPC classification number: C08F220/1802 , C08F220/1804 , C08F220/281 , C08F222/16 , C08F2/26 , C08F6/008 , C08F6/22 , C08F6/16 , C08K5/134 , B29C48/022 , B29K2033/08
Abstract: An acrylic rubber, including: 50 to 99.9% by weight of a bond unit derived from at least one (meth) acrylic acid ester selected from the group consisting of (meth) acrylic acid alkyl ester and (meth) acrylic acid alkoxyalkyl ester; 0.1 to 20% by weight of a bond unit derived from a monomer containing a reactive group; and 0 to 30% by weight of a bond unit derived from other monomer, wherein the acrylic rubber contains a phenolic anti-aging agent represented by a general formula (1),
(R1 represents an isopropyl group or a t-butyl group, and R2 represents an alkyl group having 1 to 12 carbon atoms), and the weight average molecular weight (Mw) of the acrylic rubber is in the range of 100,000 to 5,000,000.-
公开(公告)号:US20220267491A1
公开(公告)日:2022-08-25
申请号:US17626383
申请日:2020-06-05
Applicant: ZEON CORPORATION
Inventor: Hirofumi MASUDA , Takafumi KAWANAKA
IPC: C08F220/18 , C08F6/00 , C08F6/22 , C08L13/00 , C08L33/08 , B29B11/12 , B29C43/36 , B29C48/00 , B29C48/07 , B29C48/505 , B29C48/88 , B29C48/92
Abstract: An acrylic rubber bale excellent in storage stability and processability, a method for producing the same, a rubber mixture obtained by mixing the acrylic rubber bale, and a rubber cross-linked product of the rubber mixture are provided. The acrylic rubber bale according to the present invention includes an acrylic rubber having a reactive group and a weight average molecular weight (Mw) of 100,000 to 5,000,000, wherein an amount of gel insoluble in methyl ethyl ketone is 50% by weight or less, and pH is 6 or less.
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公开(公告)号:US20220251265A1
公开(公告)日:2022-08-11
申请号:US17626402
申请日:2020-06-05
Applicant: ZEON CORPORATION
Inventor: Hirofumi MASUDA , Takafumi KAWANAKA
IPC: C08F220/12 , C08K11/00
Abstract: Acrylic rubber bale having remarkably improved storage stability and water resistance without deteriorating cross-linking properties, a method of production, a rubber mixture obtained by mixing the acrylic rubber bale, a method of production, and a rubber cross-linked product obtained by cross-linking the same is provided. The acrylic rubber bale includes an acrylic rubber, and the acrylic rubber is mainly composed of (meth) acrylic acid ester, and has a weight average molecular weight of 100,000 to 5,000,000, and has a ratio of a Z-average molecular weight and a weight average molecular weight of 1.3 or more, where an ash content is 0.6% by weight or less, and the ash contains a periodic table group 2 metal and phosphorus, and a phosphorus content is 10% by weight or more, and the ratio of the periodic table group 2 metal to phosphorus is in the range of 0.6 to 2 molar ratio.
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