LOW TEMPERATURE PROCESSES FOR RECYCLING POLY(ETHYLENE TEREPHTHALATE)

    公开(公告)号:US20250002440A1

    公开(公告)日:2025-01-02

    申请号:US18703806

    申请日:2022-10-25

    Abstract: Processes are provided for the conversion of diglycol terephthalates to a dialkyl terephthalate, specifically bis(hydroxyalkyl) terephthalate to dimethyl terephthalate at low temperatures. The process involves initial catalyzed transesterification of bis(hydroxyalkyl) terephthalate with methanol at a first temperature of between 0° C. and 70° C. for an initial time followed by a second stage of the reaction at or below 30° C. In particular, the process is tolerant of significant amounts of glycol and water, so the precursor bis(hydroxyalkyl) terephthalate does not necessarily need to be highly pure or dry. Filtration of the reaction mixture allows recovery of high yields of dimethyl terephthalate of sufficiently high purity such that further purification is often not required in order to be repurposed for the manufacture of polyesters.

    Processes for producing carboxylic acids

    公开(公告)号:US12152005B2

    公开(公告)日:2024-11-26

    申请号:US17441726

    申请日:2020-03-25

    Abstract: Processes are disclosed for preparing carboxylic acids from organic esters, the processes comprising contacting an ester with water in the presence of an acid catalyst and a homogenizing solvent at conditions effective to form a carboxylic acid. The homogenizing solvent is present in an amount sufficient to form a single-phase reaction mixture comprising the ester, water, and homogenizing solvent. The homogenizing solvent may be selected from acetonitrile, dimethyl sulfoxide, and 1,4-dioxane.

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