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    Method for separating carbon dioxide from mixed gas
    2.
    发明授权
    Method for separating carbon dioxide from mixed gas 失效
    从混合气体中分离二氧化碳的方法

    公开(公告)号：US4587114A

    公开(公告)日：1986-05-06

    申请号：US475258

    申请日：1983-03-14

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    IPC分类号： B01J20/20 ,  C01B32/40 ,  B01J21/18

    CPC分类号： C01B31/18 ,  B01J20/20

    摘要： A solid form adsorbent of carbon monoxide, that is obtained by the process including the following steps. First, copper salts or copper oxide is stirred in a solvent. Then, into the solution or suspension thus obtained, active carbon is added. Finally, the solvent is removed by means of pressure reduction, distillation, etc. The carbon monoxide adsorbent produced according to this invention adsorbs carbon monoxide rapidly when it is brought into contact with a mixed gas. The adsorbed carbon monoxide can be readily separated and discharged through either heating the carbon monoxide adsorbent to above 60.degree. C. or reducing the partial pressure of carbon monoxide. The carbon monoxide obtained in accordance with the present invention is stable relative to the water content in the mixed gas, and it is capable of separating carbon monoxide directly from the mixed gas containing the water. Also, the separated carbon monoxide does not contain the vapor of the solvent from the carbon monoxide adsorbent. Therefore, it is not necessary to provide equipment to collect the solvent vapor. Furthermore, this carbon monoxide adsorbent does not produce corrosive gases, etc. The carbon monoxide adsorbent obtained by using copper (II) salts or copper (II) oxide is also stable relative to sulfur content in the mixed gas.

    摘要翻译： 一氧化碳的固体形式吸附剂，其通过包括以下步骤的方法获得。 首先，将铜盐或氧化铜在溶剂中搅拌。 然后，加入如此获得的溶液或悬浮液中，加入活性炭。 最后，通过减压，蒸馏等除去溶剂。根据本发明生产的一氧化碳吸附剂在与混合气体接触时迅速吸附一氧化碳。 吸附的一氧化碳可以通过将一氧化碳吸附剂加热至60℃以上或者降低一氧化碳的分压来容易地分离和排出。 根据本发明获得的一氧化碳相对于混合气体中的含水量是稳定的，并且能够直接从含有水的混合气体中分离一氧化碳。 此外，分离的一氧化碳不含来自一氧化碳吸附剂的溶剂的蒸气。 因此，不需要提供收集溶剂蒸汽的设备。 此外，该一氧化碳吸附剂不产生腐蚀性气体等。使用铜（II）盐或氧化铜（II））得到的一氧化碳吸附剂相对于混合气体中的硫含量也是稳定的。

    Method for preparing a non-aqueous dispersion of particles of a metal and/or a metal compound
    6.
    发明授权
    Method for preparing a non-aqueous dispersion of particles of a metal and/or a metal compound 失效
    制备金属和/或金属化合物颗粒的非水分散体的方法

    公开(公告)号：US6051614A

    公开(公告)日：2000-04-18

    申请号：US997169

    申请日：1992-12-28

    申请人： Hidefumi Hirai ,  Hyoya Shiozaki ,  Hotaka Aizawa

    发明人： Hidefumi Hirai ,  Hyoya Shiozaki ,  Hotaka Aizawa

    IPC分类号： B01J37/03 ,  H01B1/20 ,  H01B1/22 ,  B01D12/00 ,  B01F3/00

    CPC分类号： B01J37/038 ,  H01B1/20 ,  H01B1/22

    摘要： Disclosed is a method for preparing a non-aqueous dispersion of particles of a metal and/or a metal compound, which comprises contacting an aqueous dispersion of particles of a metal and/or a metal compound with a water-immiscible, non-aqueous liquid in the presence of a surfactant and in the presence or absence of a water-soluble inorganic acid salt and/or a water-soluble organic acid salt exhibiting substantially no surface activity, wherein when the contacting of the aqueous dispersion with the non-aqueous liquid is conducted in the absence of the salt, the salt is added after the contacting, thereby causing the particles to be migrated from the aqueous dispersion into the non-aqueous liquid.

    摘要翻译： 公开了一种制备金属和/或金属化合物颗粒的非水分散体的方法，其包括使金属和/或金属化合物的颗粒的水分散体与水不混溶的非水性液体 在表面活性剂的存在下，在存在或不存在表现出基本上没有表面活性的水溶性无机酸盐和/或水溶性有机酸盐的情况下，其中当水分散体与非水性液体接触时 在不存在盐的情况下进行，在接触之后加入盐，从而使颗粒从水性分散体迁移到非水性液体中。

    Solid absorbent for unsaturated hydrocarbon and process for separation of unsaturated hydrocarbon from gas mixture
    7.
    发明授权
    Solid absorbent for unsaturated hydrocarbon and process for separation of unsaturated hydrocarbon from gas mixture 失效
    不饱和烃的固体吸收剂和不饱和烃与气体混合物的分离方法

    公开(公告)号：US4747855A

    公开(公告)日：1988-05-31

    申请号：US6343

    申请日：1987-01-21

    申请人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    发明人： Hidefumi Hirai ,  Makoto Komiyama ,  Keiichiro Wada

    IPC分类号： B01J20/20 ,  C07C7/12 ,  B01D53/04

    CPC分类号： B01J20/20 ,  C07C7/12

    摘要： A solid adsorbent for an unsaturated hydrocarbon including (a) (i) a copper(I) halide or oxide or (ii) a halide, carboxylate, sulfate, basic salt, oxide, or amine complex salt of copper(II) and (b) activated carbon or graphite is described.This solid adsorbent can effectively adsorb an unsaturated hydrocarbon such as ethylene from a gas mixture by being placed in contact with the gas mixture at a temperature of -40.degree. C. to 90.degree. C. under normal pressure.

    摘要翻译： 包括（a）（i）卤化铜（I）或氧化物的铜（I）或（ii）铜（II）和（b）的卤化物，羧酸盐，硫酸盐，碱性盐，氧化物或胺络合物的固体吸附剂 ）活性炭或石墨。 这种固体吸附剂可以在常压下在-40℃至90℃的温度下与气体混合物接触，从气体混合物中有效吸附不饱和烃如乙烯。