公开(公告)号：US5661095A

公开(公告)日：1997-08-26

申请号：US465806

申请日：1995-06-06

申请人： Craig C. Meverden ,  Emory A. Ford

发明人： Craig C. Meverden ,  Emory A. Ford

IPC分类号： B01J31/06 ,  B01J31/12 ,  C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F110/02 ,  B01J31/00 ,  B01J37/00

CPC分类号： C08F10/00 ,  B01J31/123 ,  B01J31/128 ,  C08F110/02

摘要： A catalyst component useful in the polymerization of olefins which includes a support formed of a copolymer of an olefin and a silane monomer having at least one unsaturated hydrocaryl substitutent. A process for making the catalyst component as well as a catalyst composition which includes the catalyst component is also set forth.

摘要翻译： 用于烯烃聚合的催化剂组分，其包括由烯烃和具有至少一个不饱和烃基取代基的硅烷单体的共聚物形成的载体。 还阐述了制备催化剂组分的方法以及包括催化剂组分的催化剂组合物。

公开(公告)号：US5597865A

公开(公告)日：1997-01-28

申请号：US342889

申请日：1994-11-21

申请人： Paul H. Jackson

发明人： Paul H. Jackson

IPC分类号： C09J123/08 ,  C08L31/04 ,  C08L33/06 ,  C08L51/06 ,  C08L53/02

CPC分类号： C09J123/08

摘要： Adhesive blends having special utility in the formation of composite structures with LDPE, EVOH, and impact-modified polystyrene comprise a mixture of an ethylene/ester copolymer such as EVA, polystyrene, such as impact-modified polystyrene, and a functionalized SEBS block copolymer.

摘要翻译： 用于形成具有LDPE，EVOH和冲击改性聚苯乙烯的复合结构的粘合剂共混物包括乙烯/酯共聚物如EVA，聚苯乙烯（例如冲击改性聚苯乙烯）和官能化SEBS嵌段共聚物的混合物。

公开(公告)号：US5587436A

公开(公告)日：1996-12-24

申请号：US302150

申请日：1994-09-08

申请人： Thaddeus W. Klimek ,  Michael B. Edwards

发明人： Thaddeus W. Klimek ,  Michael B. Edwards

IPC分类号： C08F2/34 ,  C08F210/06 ,  C08F210/16 ,  C08F297/08 ,  C08J5/18 ,  C08L23/10 ,  C08L23/14

CPC分类号： C08J5/18 ,  C08F210/06 ,  C08F210/16 ,  C08F297/083 ,  C08L23/10 ,  C08L23/142 ,  C08J2323/10 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2308/00 ,  C08L2314/02

摘要： An improved gas-phase copolymerization process for producing copolymers of propylene and ethylene in multiple reactors using high activity Ti/Al catalysts is provided. The improvement consists of developing a control parameter derived from eight integral regions of the copolymer .sup.13 C NMR spectrum, defining the limits of the control parameter for the process, and operating the process to maintain the parameter within the defined limits. This is accomplished by adjusting the amount of ethylene in the primary and/or secondary reactor and adjusting other process variables as required.

摘要翻译： 提供了一种用于在多个反应器中使用高活性Ti / Al催化剂制备丙烯和乙烯的共聚物的改进的气相共聚方法。 该改进包括开发由共聚物13C NMR谱的八个积分区域导出的控制参数，定义该过程的控制参数的限制，以及操作该过程以将参数保持在限定的限度内。 这是通过调节初级和/或次级反应器中乙烯的量并根据需要调整其它过程变量来实现的。

公开(公告)号：US5466648A

公开(公告)日：1995-11-14

申请号：US268097

申请日：1994-06-28

申请人： Linda N. Winslow

发明人： Linda N. Winslow

IPC分类号： B01J21/08 ,  B01J31/02 ,  B01J31/06 ,  B01J31/14 ,  B01J31/34 ,  C07C2/26 ,  C07C2/30 ,  B01J31/00

CPC分类号： C07C2/30 ,  B01J31/0238 ,  B01J31/0254 ,  B01J31/06 ,  B01J31/143 ,  B01J31/34 ,  C07C2/26 ,  B01J21/08 ,  C07C2521/08 ,  C07C2527/132 ,  C07C2531/02 ,  C07C2531/14 ,  C07C2531/26

摘要： The present invention is directed to a supported tungsten-based catalyst composition useful for the dimerization of alpha-olefins including ethylene. More particularly, the catalyst composition of the instant invention comprises an organic or inorganic support material that is contacted with a tungsten salt and an organic amine compound.

摘要翻译： 本发明涉及用于包括乙烯在内的α-烯烃二聚的负载型钨基催化剂组合物。 更具体地，本发明的催化剂组合物包含与钨盐和有机胺化合物接触的有机或无机载体材料。

公开(公告)号：US5424263A

公开(公告)日：1995-06-13

申请号：US52317

申请日：1993-04-23

申请人： Charles K. Buehler

发明人： Charles K. Buehler

IPC分类号： B01J31/02 ,  B01J31/12 ,  B01J31/14 ,  C08F4/60 ,  C08F10/00 ,  B01J31/00 ,  C08F4/02

CPC分类号： B01J31/0214 ,  B01J31/0212 ,  B01J31/0274 ,  B01J31/128 ,  B01J31/143 ,  C08F10/00

摘要： A catalyst component useful in the polymerization of olefins is disclosed. The catalyst component comprises the product obtained by steps of (a) contacting silica with at least one hydrocarbon soluble magnesium-containing compound; (b) contacting the product of step (a) with component (1), a heterocyclic fused ring compound substituted with at least one oxygen atom, and component (2), a modifying compound selected from the group consisting of silicon halides, boron halides, aluminum halides, alkyl silicon halides and mixtures thereof, with the proviso that components (1) and (2) be present such that the molar ratio of component (2) to component (1) is at least about 4:1; and (c) contacting the product of step (b) with a titanium-containing compound having the structural formula TiX.sub.m (OR).sub.n, where X is halogen; R is hydrocarbyl; m is an integer of 1 to 4; and n is 0 or an integer of 1 to 3 with the proviso that the sum of m and n is 4. A catalyst system, used in the polymerization of alpha-olefins, which comprises the catalyst component of this disclosure, an aluminum-containing compound and a silane compound is also taught. Finally, a process for the polymerization of alpha-olefins, utilizing the catalyst system of the present disclosure, is described.

摘要翻译： 公开了可用于烯烃聚合的催化剂组分。 催化剂组分包括通过以下步骤获得的产物：（a）将二氧化硅与至少一种可溶于烃的含镁化合物接触; （b）使步骤（a）的产物与组分（1）接触，由至少一个氧原子取代的杂环稠环化合物和组分（2），选自卤化硅，卤化硼 ，卤化铝，烷基硅卤化物及其混合物，条件是组分（1）和（2）存在使得组分（2）与组分（1）的摩尔比为至少约4:1; 和（c）使步骤（b）的产物与具有结构式TiXm（OR）n的含钛化合物接触，其中X是卤素; R是烃基; m为1〜4的整数。 并且n为0或1至3的整数，条件是m和n的和为4.在包含本公开内容的催化剂组分的α-烯烃的聚合中使用的催化剂体系，含铝 化合物和硅烷化合物也被教导。 最后，描述了利用本公开的催化剂体系的α-烯烃的聚合方法。

公开(公告)号：US5349847A

公开(公告)日：1994-09-27

申请号：US159082

申请日：1993-11-29

申请人： Chun D. Lee ,  Donald L. Broughton

发明人： Chun D. Lee ,  Donald L. Broughton

IPC分类号： G01N11/14 ,  G01N11/16

CPC分类号： G01N11/142 ,  G01N11/165

摘要： A stationary plate assembly for a rheometer that selectively provides steady state and dynamic testing of melt viscoelastic characteristics of a material sample. The stationary plate assembly has a stationary sample plate magnetically coupled to its supporting member. Therefore, after the steady state testing is complete, the movable plate, material sample and stationary plate may be moved vertically away from the stationary plate supporting member. Therefore, any spurious, erratic rotations of the movable plate when the rheometer is switched form the steady state test mode to the dynamic test mode will not cause a further working of the material sample.

摘要翻译： 用于流变仪的固定板组件，其选择性地提供材料样品的熔体粘弹性特性的稳态和动态测试。 固定板组件具有磁性耦合到其支撑构件的固定样品板。 因此，在稳态测试完成之后，可移动板，材料样品和固定板可以垂直移动离开固定板支撑构件。 因此，当流变仪切换形成稳态测试模式到动态测试模式时，可移动板的任何虚假的，不稳定的旋转将不会导致材料样品的进一步的工作。

公开(公告)号：US5336721A

公开(公告)日：1994-08-09

申请号：US46251

申请日：1993-04-06

申请人： Webster W. Kiang

发明人： Webster W. Kiang

IPC分类号： C09J123/08 ,  C08L33/02

CPC分类号： C09J123/08 ,  Y10T428/3188 ,  Y10T428/31906 ,  Y10T428/3192 ,  Y10T428/31928

摘要： Improved two-component blends which exhibit good adhesion to 4-methylpentene-1 polymers and vinyl alcohol polymers and which may be used as an adhesive interlayer when laminating layers of the polymers are provided. Ethylene-alkyl acrylate copolymers, preferably ethylene n-butyl acrylate copolymers, and modified propylene polymers, preferably maleic anhydride grafted statistical propylene-ethylene copolymers and propylene-ethylene impact copolymers, are combined to obtain the blends of the invention. Useful laminated structures comprised of a layer of poly-4-methylpentene-1 homopolymer or copolymer, a layer of the adhesive blend and a layer of ethylene-vinyl alcohol copolymer with one or more optional layers, such as a paperboard, are also disclosed.

摘要翻译： 提供了对4-甲基戊烯-1聚合物和乙烯醇聚合物具有良好粘附性的改进的双组分共混物，并且可以在层压聚合物层时用作粘合剂中间层。 乙烯 - 丙烯酸烷基酯共聚物，优选乙烯丙烯酸正丁酯共聚物和改性丙烯聚合物，优选马来酸酐接枝的统计丙烯 - 乙烯共聚物和丙烯 - 乙烯抗冲共聚物，以得到本发明的共混物。 还公开了由一层聚-4-甲基戊烯-1均聚物或共聚物，一层粘合剂共混物和一层乙烯 - 乙烯醇共聚物与一种或多种任选层如纸板组成的有用的层压结构。

公开(公告)号：US5270411A

公开(公告)日：1993-12-14

申请号：US865521

申请日：1992-04-09

申请人： Biau-Hung Chang ,  Thomas S. Brima

发明人： Biau-Hung Chang ,  Thomas S. Brima

IPC分类号： C08F2/06 ,  C08F4/04 ,  C08F234/02 ,  C08F ,  C08F212/06

CPC分类号： C08F234/02

摘要： A process for making a biodegradable aliphatic polyester and the polyester so formed is disclosed. The process comprises copolymerizing a cyclic ketene acetal having the structural formula ##STR1## where R is a bivalent moiety, and an olefin. This copolymerization occurs in a solution of a tertiary alcohol and in the presence of a free radical initiating effective amount of a compound having the structural formula ##STR2## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and are C.sub.1 -C.sub.20 hydrocarbyl, C.sub.1 -C.sub.20 hydrocarbyloxy, cyano, halogen, carboxy, carboalkoxy, carbonyl or formyl. The copolymerization occurs at a temperature in the range of between in excess of ambient temperature and less than 100.degree. C. and at a pressure in excess of about 2,000 psi. The aliphatic polyester product of this process contains repeating structural units of the formula ##STR3## where A is a radical of a polymerized olefinic monomer; R is a bivalent moiety; x is a positive integer; and y and z are 0 or a positive integer with the proviso that the sum of y and z is at least 1, ratio of x to y is in the range of between about 3:1 and about 200,000:1, the ratio of z to y is in the range of between 0 and about 0.5:1; and said polyester has a weight average molecular weight of at least about 40,000.

摘要翻译： 公开了一种制造可生物降解的脂族聚酯和如此形成的聚酯的方法。 该方法包括使具有结构式“IMAGE”的环状烯酮缩醛共聚，其中R是二价部分，和烯烃。 这种共聚发生在叔醇的溶液中，并且在存在自由基的情况下，引发有效量的结构式为“IMAGE”的化合物，其中R 1，R 2，R 3，R 4，R 5和R 6相同或不同， C 1 -C 20烃基，C 1 -C 20烃氧基，氰基，卤素，羧基，烷氧羰基，羰基或甲酰基。 共聚发生在超过环境温度和小于100℃之间的温度和超过约2,000psi的压力下进行。 该方法的脂族聚酯产物含有下式的重复结构单元：其中A是聚合烯烃单体的基团; R是二价基团; x是正整数; 并且y和z为0或正整数，条件是y和z之和至少为1，x与y的比值在约3:1至约200,000:1之间，z比 y在0至约0.5：1的范围内; 并且所述聚酯具有至少约40,000的重均分子量。

公开(公告)号：US5246779A

公开(公告)日：1993-09-21

申请号：US927750

申请日：1992-08-10

申请人： Manfred Heimberg ,  Daniel J. Ondrus

发明人： Manfred Heimberg ,  Daniel J. Ondrus

IPC分类号： C08F8/50

CPC分类号： B29C47/92 ,  C08F8/50 ,  B29C2947/92704 ,  B29C47/0004 ,  B29C47/38 ,  B29C47/805 ,  C08F2800/20 ,  C08F2810/10 ,  Y10S525/938 ,  Y10T428/2982

摘要： The present invention is directed to improved microfine propylene polymer powders having reduced fines which are comprised of spherical or substantially spherical particles and have a number average particle size from about 25 to about 60. A process for preparing the improved powders is also provided. The process involves dispersing a molten propylene homopolymer or copolymer which has been visbroken in a liquid medium in the presence of a nonionic surfactant, cooling the dispersion below the melt point of the propylene polymer and recovering the powder.

摘要翻译： 本发明涉及具有减小的细粒的改进的微细丙烯聚合物粉末，其由球形或基本上为球形的颗粒组成，并且具有约25至约60的数均粒径。还提供了制备改进粉末的方法。 该方法包括在非离子表面活性剂的存在下分散已经在液体介质中被分解的熔融丙烯均聚物或共聚物，将分散体冷却到低于丙烯聚合物的熔点并回收粉末。

公开(公告)号：US5221650A

公开(公告)日：1993-06-22

申请号：US854199

申请日：1992-03-20

申请人： Charles K. Buehler

发明人： Charles K. Buehler

IPC分类号： C08F4/654 ,  C08F10/00

CPC分类号： C08F10/00

摘要： A novel catalyst support and a method for preparation thereof, characterized by the presence of selected amounts of a hydrocarbon soluble magnesium-containing compound applied to the support relative to solvent, wherein a surface uniformly and essentially continuously moistened with the solvated magnesium compound is achieved in a condition of incipient precipitation to permit the formation of a regular essentially continuous distribution of the magnesium compound onto and conforming to the support material The drying process under these conditions is effective in maintaining to a high degree the effective surface area and pore volume of the material. The support containing the adsorbed magnesium is then dried in a controlled manner to essential incipient wetness conditions providing a regular spatial distribution of stacked reticular magnesium values at a level of one to five molecular monolayers on the support.A representative process for polymerizing or copolymerizing olefins providing stereospecific polymers such as propylene is disclosed.

摘要翻译： 一种新颖的催化剂载体及其制备方法，其特征在于相对于溶剂存在选择量的可溶于烃的可溶性镁化合物，其中用溶剂化镁化合物均匀且基本上连续润湿的表面在 初始沉淀的条件允许形成镁化合物在支撑材料上并与其一致的规则基本上连续的分布。在这些条件下的干燥过程有效地保持材料的有效表面积和孔体积的高度 。 然后将含有吸附的镁的载体以受控的方式干燥至必需的初始湿度条件，从而提供在载体上1-5个分子单层水平的堆叠网状镁值的规则空间分布。 公开了提供立体特异性聚合物如丙烯的烯烃聚合或共聚的代表性方法。