公开(公告)号：US20150367333A1

公开(公告)日：2015-12-24

申请号：US14764923

申请日：2014-01-29

申请人： SHANGHAI BI KE CLEAN ENERGY TECHNOLOGY CO., LTD

发明人： Yijun WANG ,  Guo RUI ,  Fan ZHANG ,  Yongsheng GAN ,  Xiaomang ZHANG

IPC分类号： B01J29/40 ,  B01J21/12 ,  B01J27/16 ,  C07C1/20 ,  B01J35/02 ,  B01J37/04 ,  B01J37/00 ,  B01J37/08 ,  B01J21/16 ,  B01J35/00

CPC分类号： C07C1/20 ,  B01J21/12 ,  B01J21/16 ,  B01J27/16 ,  B01J29/40 ,  B01J35/0006 ,  B01J35/026 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0072 ,  B01J37/04 ,  B01J37/082 ,  B01J37/28 ,  B01J2229/20 ,  B01J2229/42 ,  C07C2529/40 ,  Y02P20/52 ,  C07C11/16

摘要： A method of preparing a catalyst, comprising: (1) mixing a ZSM-5 molecular sieve, a phosphorus source, a matrix material, a bonding agent and water to formulate an aqueous slurry, wherein the total content of the components except for water is 20-50 wt % based on the total weight of the aqueous slurry; (2) spray drying the slurry obtained in step (1) to obtain a granular intermediate product; and (3) calcining the granular intermediate product obtained in step (2) to obtain the catalyst used for preparing olefin from methanol in a fluid bed. The invention also provides a catalyst prepared according to said method, and a process of preparing olefin from methanol using said catalyst. In the methanol-to-olefin process, the conversion of methanol is >99%; the propylene selectivity is high; and the C4 selectivity is up to 32%.

摘要翻译： 一种制备催化剂的方法，包括：（1）将ZSM-5分子筛，磷源，基质材料，粘合剂和水混合以配制含水浆料，其中除水以外的组分的总含量为 20-50重量％，基于含水浆料的总重量; （2）喷雾干燥步骤（1）中获得的浆料，得到颗粒状中间产物; 和（3）煅烧步骤（2）中得到的颗粒状中间产物，得到在流化床中用于从甲醇制备烯烃的催化剂。 本发明还提供了根据所述方法制备的催化剂，以及使用所述催化剂由甲醇制备烯烃的方法。 在甲醇 - 烯烃方法中，甲醇的转化率> 99％; 丙烯选择性高; C4选择性高达32％。