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1.发明授权N-alkyl-N-[1,3-butadienyl(thio)carbonyl]-(thio) phosphoramidates, compositions, and methods of use as pesticides 失效N-烷基-N- [1,3-丁二烯基（硫代）羰基] - （硫代）氨基磷酸酯，组合物和用作农药的方法
公开(公告)号：US5037813A
公开(公告)日：1991-08-06
申请号：US940561
申请日：1986-12-11
IPC分类号： A01N37/18 , A01N37/28 , A01N37/36 , A01N37/46 , A01N41/12 , A01N47/12 , A01N57/26 , C07C67/00 , C07C233/09 , C07C233/13 , C07C233/20 , C07C233/90 , C07C235/28 , C07C313/00 , C07C325/00 , C07C327/44 , C07D307/38 , C07D307/40 , C07D311/02 , C07D333/04 , C07F9/24 , C07F9/44
CPC分类号： C07F9/2487
摘要： A compound of Formula (I):R.sup.1 (CA.dbd.CA.sup.1).sub.x --C(.dbd.X)NR.sup.2 R.sup.3(I)where R.sup.1 is alkyl optionally substituted by a group selected from alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, aryl, aryloxy, arylalkoxy and cycloalkyl fused to an aryl ring; x=1 or 2; X=O or S; each A and A.sup.1 is independently hydrogen, alkyl or haloalkyl; R.sup.2 is alkyl, alkenyl or cycloalkyl any of which may be substituted by halo, alkenyl, alkyl, cycloalkyl, alkynyl, dioxalanylalkyl or alkoxy; and R.sup.3 is selected from groups (A) to (D):(A) --Y.dbd.X.sup.1 --(R.sup.4).sub.a where X.sup.1 is O or S, Y is phosphorus or carbon, R.sup.4 is hydrogen, alkyl, alkoxy, acyl or CO.sub.2 R.sup.5 is alkyl or aryl, and a is 1 or 2.(B) --S(R.sup.6)(O).sub.bwhere R.sup.6 alkyl, aryl, aryloxy, alkoxy, thioalkoxy, thioaryl, alkythio, alkoxythio or arylthio and b is 0, 1 or 2(C) --S(O).sub.c NR.sup.7 R.sup.8where c is 0, 1 or 2, R.sup.7 is --COR.sup.9 or --CO.sub.2 R.sup.9 where R.sup.9 is hydrogen, alkyl or a fluorine atom, a group (A) or (B) as defined above, or alkyl substituted by acyl, carboalkoxy or cyano, and R.sup.8 is alkyl(D) R.sup.1 --(CA.dbd.CA.sup.1).sub.n --C(.dbd.X)N(R.sup.2)--wherein the substituents are independently selected as in Formula (I) above.
摘要翻译： 式（I）的化合物：R1（CA = CA1）xC（= X）NR2R3（I）其中R1是任选被选自烷氧基，烯基，炔基，烯氧基，炔氧基，芳基，芳氧基，芳基烷氧基和芳基烷氧基的基团取代的烷基 稠合到芳环的环烷基; x = 1或2; X = O或S; 每个A和A1独立地是氢，烷基或卤代烷基; R2是烷基，烯基或环烷基，其中任何一个可以被卤素，烯基，烷基，环烷基，炔基，二氧戊环基烷基或烷氧基取代; （A）-Y = X1-（R4）a其中X1为O或S，Y为磷或碳，R4为氢，烷基，烷氧基，酰基或CO2R5 （B）-S（R 6）（O）b其中R 6烷基，芳基，芳氧基，烷氧基，硫代烷氧基，硫代芳基，烷硫基，烷硫基或芳硫基，b是0,1或 2（C）-S（O）cNR 7 R 8，其中c为0,1或2，R 7为-COR 9或-CO 2 R 9，其中R 9为氢，烷基或氟原子，如上所定义的基团（A）或（B） 或被酰基，烷氧羰基或氰基取代的烷基，R8是烷基（D）R1-（CA = CA1）nC（= X）N（R2） - ，其中取代基如上式（I）所示独立选择。
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公开(公告)号：US5091414A
公开(公告)日：1992-02-25
申请号：US619872
申请日：1990-11-29
IPC分类号： C07F9/24
CPC分类号： C07F9/2487
摘要： A compound of Formula (I):(I) R.sup.1 (CA.dbd.CA.sup.1).sub.x --C(.dbd.X)NR.sup.2 R.sup.3where R.sup.1 is alkyl optionally substituted by a group selected from alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, aryl, aryloxy, arylalkoxy and cycloalkyl fused to an aryl ring; x=1 or 2; X=O or S; each A and A.sup.1 is independently hydrogen, alkyl or haloalkyl; R.sup.2 is alkyl, alkenyl or cycloalkyl any of which may be substituted by halo, alkenyl, alkyl, cycloalkyl, alkynyl, dioxalanylalkyl or alkoxy; and R.sup.3 is selected from groups (A) to (D):(A) --Y=X.sup.1 --(R.sup.4).sub.a where X.sup.1 is O or S, Y is phosphorus or carbon, R.sup.4 is hydrogen, alkyl, alkoxy, acyl or CO.sub.2 R.sup.5 where R.sup.5 is alkyl or aryl, and a is 1 or 2(B) --S(R.sup.6)(O).sub.bwhere R.sup.6 is alkyl, aryl, aryloxy, alkoxy, thioalkoxy, thioaryl, alkythio, alkoxythio or arylthio and b is 0, 1 or 2(C) --S(O).sub.c NR.sup.7 R.sup.8where c is 0, 1 or 2, R.sup.7 is --COR.sup.9 or --CO.sub.2 R.sup.9 where R.sup.9 is hydrogen, alkyl or a fluorine atom, a group (A) or (B) as defined above, or alkyl substituted by acyl, carboalkoxy or cyano, and R.sup.8 is alkyl(D) R.sup.1 --(CA.dbd.CA.sup.1).sub.n --C(.dbd.X)N(R.sup.2)--wherein the subtituents are independently selected as in Formula (I) above.
摘要翻译： 式（I）化合物：（I）R1（CA = CA1）xC（= X）NR2R3其中R1是任选被选自烷氧基，烯基，炔基，烯氧基，炔氧基，芳基，芳氧基，芳基烷氧基和芳氧基的基团取代的烷基， 稠合到芳环的环烷基; x = 1或2; X = O或S; 每个A和A1独立地是氢，烷基或卤代烷基; R2是烷基，烯基或环烷基，其中任何一个可以被卤素，烯基，烷基，环烷基，炔基，二氧戊环基烷基或烷氧基取代; （A）-Y = X1-（R4）a其中X1为O或S，Y为磷或碳，R4为氢，烷基，烷氧基，酰基或CO2R5 其中R 5是烷基或芳基，且a是1或2（B）-S（R 6）（O）b，其中R 6是烷基，芳基，芳氧基，烷氧基，硫代烷氧基，硫代芳基，链炔基，烷硫基或芳硫基，b是0， 1或2（C）-S（O）cNR 7 R 8，其中c是0,1或2，R 7是-COR 9或-CO 2 R 9，其中R 9是氢，烷基或氟原子，定义的基团（A）或（B） 或者被酰基，烷氧羰基或氰基取代的烷基，R8是烷基（D）R1-（CA = CA1）nC（= X）N（R2） - ，其中取代基如上式（I）所示独立选择。
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公开(公告)号：US5124348A
公开(公告)日：1992-06-23
申请号：US701834
申请日：1991-05-17
IPC分类号： A01N37/18 , A01N37/28 , A01N37/36 , A01N37/46 , A01N41/12 , A01N47/12 , A01N57/26 , C07C67/00 , C07C233/09 , C07C233/13 , C07C233/20 , C07C233/90 , C07C235/28 , C07C313/00 , C07C325/00 , C07C327/44 , C07D307/38 , C07D307/40 , C07D311/02 , C07D333/04 , C07F9/24 , C07F9/44
CPC分类号： C07F9/2487
摘要： A compound of Formula (I):R.sup.1 (CA.dbd.CA.sup.1).sub.x --C(.dbd.X)NR.sup.2 R.sup.3 (I)where R.sup.1 is alkyl optionally substituted by a group selected from alkoxy, alkenyl, alkynyl, alkenyloxy, alkynyloxy, aryl, aryloxy, arylalkoxy and cycloalkyl fused to an aryl ring; x=1 or 2; X=O or S; each A and A.sup.1 is independently hydrogen, alkyl or haloalkyl; R.sup.2 is alkyl, alkenyl or cycloalkyl any of which may be substituted by halo, alkenyl, alkyl, cycloalkyl, alkynyl, dioxalanylalkyl or alkoxy; and R.sup.3 is selected from groups (A) to (D):(A) --Y.dbd.X.sup.1 --(R.sup.4).sub.a where X.sup.1 is O or S, Y is phosphorus or carbon, R.sup.4 is hydrogen, alkyl, alkoxy, acyl or CO.sub.2 R.sup.5 where R.sup.5 is alkyl or aryl, and a is 1 or 2(B) --S(R.sup.6)(O).sub.b where R.sup.6 is alkyl, aryl, aryloxy, alkoxy, thioalkoxy, thioaryl, alkythio, alkoxythio or arylthio and b is 0, 1 or 2(C) --S(O).sub.c NR.sup.7 R.sup.8 where c is 0, 1 or 2, R.sup.7 is --COR.sup.9 or --CO.sub.2 R.sup.9 where R.sup.9 is hydrogen, alkyl or a fluorine atom, a group (A) or (B) as defined above, or alkyl substituted by acyl, carboalkoxy or cyano, and R.sup.8 is alkyl(D) R.sup.1 --(CA.dbd.CA.sup.1).sub.n --C(.dbd.X)N(R.sup.2)-- wherein the substituents are independently selected as in Formula (I) above.
摘要翻译： 式（I）的化合物：R1（CA = CA1）xC（= X）NR2R3（I）其中R1是任选被选自烷氧基，烯基，炔基，烯氧基，炔氧基，芳基，芳氧基，芳基烷氧基和芳基烷氧基的基团取代的烷基 稠合到芳环的环烷基; x = 1或2; X = O或S; 每个A和A1独立地是氢，烷基或卤代烷基; R2是烷基，烯基或环烷基，其中任何一个可以被卤素，烯基，烷基，环烷基，炔基，二氧戊环基烷基或烷氧基取代; （A）-Y = X1-（R4）其中X1是O或S，Y是磷或碳，R4是氢，烷基，烷氧基，酰基或CO2R5，其中 R5是烷基或芳基，和a是1或2（B）-S（R6）（O）b，其中R6是烷基，芳基，芳氧基，烷氧基，硫代烷氧基，硫代芳基，链烯基，烷硫基或芳硫基，b是0,1 或2（C）-S（O）cNR 7 R 8，其中c为0,1或2，R 7为-COR 9或-CO 2 R 9，其中R 9为氢，烷基或氟原子，所定义的基团（A）或（B） 或者被酰基，烷氧基或氰基取代的烷基，R8是烷基（D）R1-（CA = CA1）nC（= X）N（R2） - ，其中取代基如上述式（I）中独立地选择。
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公开(公告)号：US4855086A
公开(公告)日：1989-08-08
申请号：US540801
申请日：1983-10-11
申请人： Malcolm H. Black , Robert J. Blade
发明人： Malcolm H. Black , Robert J. Blade
IPC分类号： C07C17/363 , C07C45/30 , C07C45/59 , C07C45/72 , C07C57/42 , C07C57/72 , C07C233/09 , C07D295/185 , C07D307/10 , C07D309/12 , C07D317/20 , C07D317/26 , C07D317/30
CPC分类号： C07D295/185 , C07C17/363 , C07C233/09 , C07C45/305 , C07C45/59 , C07C45/72 , C07C57/42 , C07C57/72 , C07D307/10 , C07D309/12 , C07D317/20 , C07D317/26 , C07D317/30
摘要： The specification describes and claims methods of controlling acarine pests by application of a compound of Formula (I), methods of controlling arthropod pests by application of a compound of Formula (IA), compounds of Formula (IA) per se, pesticidal compositions comprising a compound of Formula (IA), and processes for preparing a compound of Formula (IA).
摘要翻译： 本说明书描述并要求通过应用式（I）化合物控制螨虫害虫的方法，通过施用式（IA）化合物，式（IA）化合物本身来控制节肢动物害虫的方法，农药组合物包含 Formfula（IA）的化合物和制备式（IA）化合物的方法。
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公开(公告)号：US4931469A
公开(公告)日：1990-06-05
申请号：US205572
申请日：1988-06-08
申请人： Malcolm H. Black , Robert J. Blade
发明人： Malcolm H. Black , Robert J. Blade
IPC分类号： C07C17/363 , C07C45/30 , C07C45/59 , C07C45/72 , C07C57/42 , C07C57/72 , C07C233/09 , C07D295/185 , C07D307/10 , C07D309/12 , C07D317/20 , C07D317/26 , C07D317/30 , A01N37/10 , A01N37/12 , A01N37/18
CPC分类号： C07D295/185 , C07C17/363 , C07C233/09 , C07C45/305 , C07C45/59 , C07C45/72 , C07C57/42 , C07C57/72 , C07D307/10 , C07D309/12 , C07D317/20 , C07D317/26 , C07D317/30
摘要： The specification describes and claims methods of controlling acarine pests by application of a compound of Formula (I), methods of controlling arthropod pests by application of a compound of Formula (IA), compounds of Formula (IA) per se, pesticidal compositions comprising a compound of Formula (IA), and processes for preparing a compound of Formula (IA).
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公开(公告)号：US5057504A
公开(公告)日：1991-10-15
申请号：US395287
申请日：1989-08-16
申请人： Malcolm H. Black , John A. Wyatt , John B. Weston , John P. Larkin , Ian H. Smith , David A. Pulman
发明人： Malcolm H. Black , John A. Wyatt , John B. Weston , John P. Larkin , Ian H. Smith , David A. Pulman
IPC分类号： A01N43/90 , A01N47/16 , A01N55/00 , C07D405/12 , C07D491/08
CPC分类号： C07D405/12 , A01N43/90 , A01N47/16 , A01N55/00 , C07D491/08
摘要： Pesticidal bicyclo-octanes are of the formula ##STR1## where R is a substituted or unsubstituted aliphatic or aromatic group, R' and R.sup.3 are H or a substituted or unsubstituted aliphatic or aromatic group, R.sup.2 is a substituted or unsubstituted heterocyclic group containing at least one ring nitrogen and is preferably a 3- or 4- pyridyl group, Z is CH.sub.2 CH.sub.2, CH.sub.2 O--CH.sub.2 S or COCH.sub.2 or CH(OR.sup.5)CH.sub.2 where R.sup.5 is H, alkyl, acyl or carbamoyl at Y and Y' are O or S(O).sub.m where m is 0, 1 or 2.Various methods for their preparation are described.
摘要翻译： 农药双环辛烷具有下式：其中R是取代或未取代的脂族或芳族基团，R'和R 3是H或取代或未取代的脂族或芳族基团，R 2是至少含有取代或未被取代的杂环基 一个环氮，优选为3-或4-吡啶基，Z为CH 2 CH 2，CH 2 O-CH 2 S或COCH 2或CH（OR 5）CH 2，其中R 5为H，Y和Y'为烷基，酰基或氨基甲酰基， O）m，其中m为0,1或2.描述了其制备方法。
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7.发明授权N-[(phenyl(oxy or amino))thioacetyl]-1,2-diamine anthropodicides 失效N - [（苯基（氧基或氨基））硫代乙酰] -1,2-二胺杀虫剂
公开(公告)号：US4320142A
公开(公告)日：1982-03-16
申请号：US150065
申请日：1980-05-15
IPC分类号： A01N39/02 , A01N39/04 , A01N47/12 , A01N47/28 , A01N47/30 , C07C327/40 , C07C157/09 , A01N47/10 , A01N47/22 , A01N47/40 , C07C153/063 , C07C155/02
摘要： Compounds of formula (I) are pesticides active against arthropods. ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 are H, alkyl, alkoxy, halo, CN or CF.sub.3 or two are linked to form a 3 or 4 carbon atom group;X is O or NA where A is H or alkyl;R is H or alkyl;R.sup.4 is H or optionally substituted alkyl, aryl, aralkyl, alkenyl or alkynyl; andR.sup.5 is --CB. R.sup.6 where B is O, S or NR.sup.7 where R.sup.7 is H, alkyl, alkoxy, or optionally substituted aryl or aralkyl;R.sup.6 is H, R.sup.8, OR.sup.8, SR.sup.8 or NR.sup.9 R.sup.10 where R.sup.8 is alkyl, alkenyl or optionally substituted aryl, aralkyl or aryloxyalkyl; and R.sup.9 and R.sup.10 are H, alkyl or optionally substituted aryl or aralkyl;The invention also comprises processes for the preparation of compounds (I), formulations containing them, and their use as pesticides.
摘要翻译： 式（I）化合物是对节肢动物活性的农药。 （I）其中R1，R2和R3是H，烷基，烷氧基，卤素，CN或CF3或两个连接形成3或4个碳原子基团; X是O或NA，其中A是H或烷基; R是H或烷基; R 4是H或任选取代的烷基，芳基，芳烷基，烯基或炔基; R5为-CB。 R6，其中B为O，S或NR7，其中R7为H，烷基，烷氧基或任选取代的芳基或芳烷基; R6是H，R8，OR8，SR8或NR9R10，其中R8是烷基，烯基或任选取代的芳基，芳烷基或芳氧基烷基; 且R 9和R 10为H，烷基或任选取代的芳基或芳烷基; 本发明还包括制备化合物（I），含有它们的制剂及其作为农药的用途的方法。
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公开(公告)号：US4238497A
公开(公告)日：1980-12-09
申请号：US954745
申请日：1978-10-26
IPC分类号： A01N43/50 , A01N47/16 , A01N47/22 , A01N47/38 , A01N47/44 , C07D233/06 , C07D233/20 , C07D233/24 , A61K31/45
CPC分类号： C07C255/00 , A01N43/50 , A01N47/16 , A01N47/22 , A01N47/38 , A01N47/44 , C07D233/06 , C07D233/20 , C07D233/24
摘要： Imidazoline compounds of formula (I): ##STR1## wherein Ar is selected from a phenyl or a mono-, di- or tri-substituted phenyl radical in which the substituents are selected from alkyl, alkoxy, halogen, hydroxy, cyano, amino, trihalomethyl and nitro and in which any two adjacent carbon atoms of the phenyl ring may be joined by a carbon chain containing 3 or 4 carbon atoms;X.sup.1 is S, NR.sup.3 or NZ.sup.1 ;R.sup.1 and R.sup.2 are selected from hydrogen or alkyl;R.sup.3 is alkyl or aryl;m is 0 or 1; andZ.sup.1 and Z.sup.2 are a group SO.sub.n R.sup.9 or a group ##STR2## in which X.sup.2 is O, S or NR.sup.5 ; R.sup.4 is alkyl, aryl, alkoxy, aryloxy, amino or amido;R.sup.5 is alkyl, aryl, alkoxy, aryloxy, alkylthio, arylthio, amino or amido;the alkyl or alkoxy radicals containing from 1 to 4 carbon atoms each; or an acid addition salt of the imidazoline compound.Methods of preparing the compounds are provided, as are pesticidal formulations containing them.The compounds are active against pests, especially arthropods of the Order Acarina.
摘要翻译： 式（I）的咪唑啉化合物：其中Ar选自苯基或单取代，二取代或三取代的苯基，其中取代基选自烷基，烷氧基，卤素，羟基，氰基 ，氨基，三卤甲基和硝基，其中苯环的任何两个相邻碳原子可以通过含有3或4个碳原子的碳链连接; X1为S，NR3或NZ1; R1和R2选自氢或烷基; R3是烷基或芳基; m为0或1; 并且Z 1和Z 2是其中X 2是O，S或NR 5的基团SO n R 9或基团
; R4是烷基，芳基，烷氧基，芳氧基，氨基或酰氨基; R5是烷基，芳基，烷氧基，芳氧基，烷硫基，芳硫基，氨基或酰氨基; 每个含有1至4个碳原子的烷基或烷氧基; 或咪唑啉化合物的酸加成盐。 提供了制备化合物的方法，含有它们的杀虫剂也是如此。 这些化合物对有害生物是有效的，尤其是蜱螨目的节肢动物。 -
公开(公告)号：US4863966A
公开(公告)日：1989-09-05
申请号：US234908
申请日：1981-02-17
IPC分类号： A61K31/165 , A01N37/20 , A01N37/44 , A01N39/02 , A01N39/04 , A61K31/396 , A61K31/40 , A61P17/00 , A61P33/00 , C07C67/00 , C07C325/00 , C07C327/42 , C07D203/12 , C07D295/13
CPC分类号： C07D295/13 , A01N37/44 , A01N39/02 , A01N39/04
摘要： Compounds of formula (I) are pesticides having activity against arthropods: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are H, alkyl, alkoxy, halo, cyano or trifluoromethyl, or two of R.sup.1, R.sup.2 and R.sup.3 are linked to form a 3 or 4 carbon atom group;X is O or NA where A is H or alkyl;R is H or alkyl; andR.sup.4 and R.sup.5 are H, alkenyl or haloalkenyl or optionally substituted alkyl, aryl or aralkyl, or NR.sup.4 R.sup.5 represents a heterocyclic ring; or an acid addition salt thereof.The invention further provides methods for the preparation of the compounds, pesticidal formulations containing them, and their use in controlling arthropod pests.
摘要翻译： 式（I）化合物是具有抗节肢动物活性的农药：其中R 1，R 2和R 3是H，烷基，烷氧基，卤素，氰基或三氟甲基，或者R 1，R 2和R 3中的两个连接形成3或 4个碳原子团; X是O或NA，其中A是H或烷基; R是H或烷基; 和R 4和R 5是H，烯基或卤代烯基或任选取代的烷基，芳基或芳烷基，或NR 4 R 5表示杂环; 或其酸加成盐。 本发明还提供了制备化合物的方法，含有它们的杀虫剂，以及它们在控制节肢动物害虫中的用途。
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