公开(公告)号：US08784693B2

公开(公告)日：2014-07-22

申请号：US13711427

申请日：2012-12-11

Applicant: Tsinghua University ,  Hon Hai Precision Industry Co., Ltd.

Inventor： Li Wang ,  Xiang-Ming He ,  Jian-Guo Ren ,  Wei-Hua Pu ,  Jian-Jun Li ,  Jian Gao

IPC: H01M4/38

CPC classification number: H01M4/604 ,  C08F8/40 ,  C08F2810/30 ,  C08K3/04 ,  C08K3/32 ,  H01M4/38 ,  H01M4/60 ,  H01M4/625 ,  H01M10/0525 ,  Y02E60/12 ,  C08F120/44 ,  C08F114/08

Abstract: A method for making a phosphorated composite is provided. First, a mixture is obtained by mixing a source material with red phosphorus. The weight ratio of the source material to the red phosphorus ranges from about 1:10 to about 5:1. Second, the mixture is dried in an inert atmosphere or vacuum. Third, the mixture is heated in a reacting room filled with an inert atmosphere so that the red phosphorus sublimes. Finally, the reacting room is cooled down.

Abstract translation: 提供了一种制备磷化复合材料的方法。 首先，通过将源材料与红磷混合获得混合物。 源材料与红磷的重量比范围为约1:10至约5:1。 第二，将混合物在惰性气氛或真空中干燥。 第三，将混合物在充满惰性气氛的反应室中加热，使红磷升华。 最后，反应室被冷却。

公开(公告)号：US3640974A

公开(公告)日：1972-02-08

申请号：US3640974D

申请日：1969-05-05

Applicant: HERCULES INC

Inventor： BRESLOW DAVID S

IPC: C08F8/30 ,  C08F3/20 ,  C08F27/08

CPC classification number: C08F8/30 ,  C08F2800/20 ,  C08F2810/20 ,  C08F114/06 ,  C08F214/06 ,  C08F114/08 ,  C08F218/08

Abstract: VINYL CHLORIDE AND VINYLIDENE CHLORIDE POLYMERS CAN BE CROSS-LINKED OR OTHERWISE MODIFIED BY REACTION WITH A POLY (DIAZO) COMPOUND SELECTED FROM THE GROUP OF

R-(O-CO-CN2-R'')X AND A-(CN2-R'')X

WHERE X IS AN INTEGER GREATER THAN 1, R IS AN ORGANIC RADICAL INERT TO MODIFICATION REACTIONS, A IS AN AROMATIC RADICAL INERT TO MODIFICATION REACTIONS, AND R'' IS A HYDROGEN, ARYL OR -COOZ RADICAL WHERE Z IS AN ALKYL OR ARYL RADICAL. THE REACTION BETWEEN THE POLY (DIAZO) COMPOUND AND POLYMER CAN BE INITIATED EITHER BY HEATING OR BY EXPOSING TO ULTRAVIOLET RADIATION.

公开(公告)号：US20100239905A1

公开(公告)日：2010-09-23

申请号：US12720600

申请日：2010-03-09

Applicant: Li Wang ,  Xiang-Ming He ,  Jian-Guo Ren ,  Wei-Hua Pu ,  Jian-Jun Li ,  Jian Gao

Inventor： Li Wang ,  Xiang-Ming He ,  Jian-Guo Ren ,  Wei-Hua Pu ,  Jian-Jun Li ,  Jian Gao

IPC: H01M4/60 ,  H01B1/04 ,  H01B1/12 ,  H01M4/583

CPC classification number: H01M4/604 ,  C08F8/40 ,  C08F2810/30 ,  C08K3/04 ,  C08K3/32 ,  H01M4/38 ,  H01M4/60 ,  H01M4/625 ,  H01M10/0525 ,  Y02E60/12 ,  C08F120/44 ,  C08F114/08

Abstract: A phosphorated composite capable of electrochemical reversible lithium storage includes a conductive matrix and a red phosphorus. The conductive matrix includes a material being selected from the group consisting of conductive polymer and conductive carbonaceous material. A weight percentage of the conductive matrix in the phosphorated composite ranges from about 10% to about 85%. A weight percentage of the red phosphorus in the phosphorated composite ranges from about 15% to about 90%. A method for making the phosphorated composite and a lithium-ion battery using the phosphorated composite is also provided.

Abstract translation: 能够进行电化学可逆锂储存的磷酸盐化复合物包括导电基质和红磷。 导电基体包括选自导电聚合物和导电碳质材料的材料。 磷酸化复合物中的导电基质的重量百分数为约10％至约85％。 磷酸盐化合物中红磷的重量百分数为约15％至约90％。 还提供了一种制造磷化复合物的方法和使用该磷化复合材料的锂离子电池。

公开(公告)号：US2915481A

公开(公告)日：1959-12-01

申请号：US25988251

申请日：1951-12-04

Applicant: PURE OIL CO

Inventor： AYERS GEORGE W ,  GEERTS MARCELLUS J ,  KREWER WILLIAM A

IPC: C08F8/00

CPC classification number: C08F8/32 ,  C08F8/48 ,  C08F114/06 ,  C08F114/08 ,  C08F118/04 ,  C08F8/04 ,  C08F8/20 ,  C08F8/00 ,  C08F16/06 ,  C08F8/44 ,  C08F120/14

公开(公告)号：US09850364B2

公开(公告)日：2017-12-26

申请号：US14366986

申请日：2012-12-18

Applicant: SOLVAY SA ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  ECOLE NATIONALE SUPERIEURE DE CHIMIE DE MONTPELLIER ,  UNIVERSITE DE MONTPELLIER 2

Inventor： Jérôme Vinas ,  Pierre-Emmanuel Dufils ,  Jérôme Garnier ,  Patrick Lacroix-Desmazes ,  Alex Van Herk ,  Jérôme Warnant ,  Yves Vanderveken

IPC: C08K3/22 ,  B05D7/00 ,  C08F114/08 ,  C08J5/18

CPC classification number: C08K3/22 ,  B05D7/00 ,  C08F114/08 ,  C08J5/18 ,  C08J2327/08 ,  C08K2003/2213 ,  Y10T428/2998

Abstract: Process for the preparation of a vinylidene chloride polymer composite comprising a solid particulate encapsulated in the vinylidene chloride polymer. The process comprises providing a dispersion of a solid particulate material in a liquid phase, said dispersion comprising a RAFT/MADIX agent; providing vinylidene chloride and optionally one or more ethylenically unsaturated monomer copolymerizable therewith to said dispersion; and polymerizing vinylidene chloride and said optionally present one or more ethylenically unsaturated monomer under the control of said RAFT/MADIX agent to form polymer at the surface of said solid particulate material.

公开(公告)号：US20130099173A1

公开(公告)日：2013-04-25

申请号：US13711427

申请日：2012-12-11

Applicant: Tsinghua University ,  HON HAI PRECISION INDUSTRY CO., LTD.

Inventor： LI WANG ,  XIANG-MING HE ,  JIAN-GUO REN ,  WEI-HUA PU ,  JIAN-JUN LI ,  JIAN GAO

IPC: H01M4/60 ,  H01M4/38

CPC classification number: H01M4/604 ,  C08F8/40 ,  C08F2810/30 ,  C08K3/04 ,  C08K3/32 ,  H01M4/38 ,  H01M4/60 ,  H01M4/625 ,  H01M10/0525 ,  Y02E60/12 ,  C08F120/44 ,  C08F114/08

Abstract: A method for making the phosphorated composite e is provided. First, a mixture is obtained by mixing a source material with red phosphorus. The weight ratio of the source material to the red phosphorus ranges from about 1:10 to about 5:1. Second, the mixture is dried in an inert atmosphere or vacuum. Third, the mixture is heated in a reacting room filled with an inert atmosphere so that the red phosphorus sublimes. Finally, the reacting room is cooled down.

Abstract translation: 提供了制造磷化复合物e的方法。 首先，通过将源材料与红磷混合获得混合物。 源材料与红磷的重量比范围为约1:10至约5:1。 第二，将混合物在惰性气氛或真空中干燥。 第三，将混合物在充满惰性气氛的反应室中加热，使红磷升华。 最后，反应室被冷却。

公开(公告)号：US20140371370A1

公开(公告)日：2014-12-18

申请号：US14366986

申请日：2012-12-18

Applicant: SOLVAY SA ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  ECOLE NATIONAL SUPERIEURE DE CHIMIE DE MONTPELLIER ,  UNIVERSITE DE MONTPELLIER 2

Inventor： Jérome Vinas ,  Pierre-Emmanuel Dufils ,  Jérome Garnier ,  Patrick Lacroix-Desmazes ,  Alex Van Herk ,  Jérome Warnant ,  Yves Vanderveken

IPC: C08K3/22 ,  C08J5/18 ,  B05D7/00

CPC classification number: C08K3/22 ,  B05D7/00 ,  C08F114/08 ,  C08J5/18 ,  C08J2327/08 ,  C08K2003/2213 ,  Y10T428/2998

Abstract: Process for the preparation of a vinylidene chloride polymer composite comprising a solid particulate encapsulated in the vinylidene chloride polymer. The process comprises providing a dispersion of a solid particulate material in a liquid phase, said dispersion comprising a RAFT/MADIX agent; providing vinylidene chloride and optionally one or more ethylenically unsaturated monomer copolymerisable therewith to said dispersion; and polymerising vinylidene chloride and said optionally present one or more ethylenically unsaturated monomer under the control of said RAFT/MADIX agent to form polymer at the surface of said solid particulate material.

Abstract translation: 制备含偏二氯乙烯聚合物的固体颗粒的偏二氯乙烯聚合物复合材料的方法。 该方法包括提供固体颗粒材料在液相中的分散体，所述分散体包含RAFT / MADIX试剂; 提供偏二氯乙烯和任选的一种或多种可与其共聚的烯属不饱和单体与所述分散体; 并在所述RAFT / MADIX试剂的控制下聚合偏二氯乙烯和所述任选存在的一种或多种烯属不饱和单体以在所述固体颗粒材料的表面形成聚合物。

公开(公告)号：US08852800B2

公开(公告)日：2014-10-07

申请号：US13711421

申请日：2012-12-11

Applicant: Tsinghua University ,  Hon Hai Precision Industry Co., Ltd.

Inventor： Li Wang ,  Xiang-Ming He ,  Jian-Guo Ren ,  Wei-Hua Pu ,  Jian-Jun Li ,  Jian Gao

IPC: H01M4/60 ,  H01M4/02 ,  H01M4/13 ,  H01M4/62 ,  C08F8/40 ,  C08K3/04 ,  C08K3/32 ,  H01M4/38 ,  H01M10/0525

CPC classification number: H01M4/604 ,  C08F8/40 ,  C08F2810/30 ,  C08K3/04 ,  C08K3/32 ,  H01M4/38 ,  H01M4/60 ,  H01M4/625 ,  H01M10/0525 ,  Y02E60/12 ,  C08F120/44 ,  C08F114/08

Abstract: A phosphorated composite capable of electrochemical reversible lithium storage includes a conductive matrix and red phosphorus. The conductive matrix includes a material being selected from the group consisting of conductive polymer and conductive carbonaceous material. A weight percentage of the conductive matrix in the phosphorated composite ranges from about 10% to about 85%. A weight percentage of the red phosphorus in the phosphorated composite ranges from about 15% to about 90%. An anode using the phosphorated composite is also provided.

Abstract translation: 能够进行电化学可逆锂储存的磷酸盐化复合物包括导电基质和红磷。 导电基体包括选自导电聚合物和导电碳质材料的材料。 磷酸化复合物中的导电基质的重量百分数为约10％至约85％。 磷酸盐化合物中红磷的重量百分数为约15％至约90％。 还提供了使用磷光复合材料的阳极。

公开(公告)号：US20130099172A1

公开(公告)日：2013-04-25

申请号：US13711421

申请日：2012-12-11

Applicant: Tsinghua University ,  HON HAI PRECISION INDUSTRY CO., LTD.

Inventor： LI WANG ,  XIANG-MING HE ,  JIAN-GUO REN ,  WEI-HUA PU ,  JIAN-JUN LI ,  JIAN GAO

IPC: H01M4/60 ,  H01M4/38

CPC classification number: H01M4/604 ,  C08F8/40 ,  C08F2810/30 ,  C08K3/04 ,  C08K3/32 ,  H01M4/38 ,  H01M4/60 ,  H01M4/625 ,  H01M10/0525 ,  Y02E60/12 ,  C08F120/44 ,  C08F114/08

Abstract: A phosphorated composite capable of electrochemical reversible lithium storage includes a conductive matrix and red phosphorus. The conductive matrix includes a material being selected from the group consisting of conductive polymer and conductive carbonaceous material. A weight percentage of the conductive matrix in the phosphorated composite ranges from about 10% to about 85%. A weight percentage of the red phosphorus in the phosphorated composite ranges from about 15% to about 90%. An anode using the phosphorated composite is also provided.

Abstract translation: 能够进行电化学可逆锂储存的磷酸盐化复合物包括导电基质和红磷。 导电基质包括选自导电聚合物和导电碳质材料的材料。 磷酸化复合物中的导电基质的重量百分数为约10％至约85％。 磷酸化复合物中红磷的重量百分数为约15％至约90％。 还提供了使用磷光复合材料的阳极。

公开(公告)号：US08389158B2

公开(公告)日：2013-03-05

申请号：US12720600

申请日：2010-03-09

Applicant: Li Wang ,  Xiang-Ming He ,  Jian-Guo Ren ,  Wei-Hua Pu ,  Jian-Jun Li ,  Jian Gao

Inventor： Li Wang ,  Xiang-Ming He ,  Jian-Guo Ren ,  Wei-Hua Pu ,  Jian-Jun Li ,  Jian Gao

IPC: H01M4/02 ,  H01M4/13 ,  H01M4/58 ,  H01B1/04 ,  C01B25/00

CPC classification number: H01M4/604 ,  C08F8/40 ,  C08F2810/30 ,  C08K3/04 ,  C08K3/32 ,  H01M4/38 ,  H01M4/60 ,  H01M4/625 ,  H01M10/0525 ,  Y02E60/12 ,  C08F120/44 ,  C08F114/08

Abstract: A lithium-ion battery includes an anode, a cathode, and an electrolyte. The anode includes a phosphorated composite including a conductive matrix and a red phosphorus. The conductive matrix includes a material being selected from the group consisting of conductive polymer and conductive carbonaceous material. A weight percentage of the conductive matrix in the phosphorated composite ranges from about 10% to about 85%. A weight percentage of the red phosphorus in the phosphorated composite ranges from about 15% to about 90%.

Abstract translation: 锂离子电池包括阳极，阴极和电解质。 阳极包括含有导电基体和红磷的磷化复合物。 导电基体包括选自导电聚合物和导电碳质材料的材料。 磷酸化复合物中的导电基质的重量百分数为约10％至约85％。 磷酸盐化合物中红磷的重量百分数为约15％至约90％。