Cyclic compound, its metal complex and modified metal complex
    8.
    发明授权
    Cyclic compound, its metal complex and modified metal complex 有权
    环状化合物,其金属络合物和改性金属络合物

    公开(公告)号:US09236613B2

    公开(公告)日:2016-01-12

    申请号:US13969772

    申请日:2013-08-19

    摘要: A compound represented by formula (1): wherein Y1 to Y4 each independently represent any one of the following groups: in which Rα represents a hydrogen atom or a monovalent hydrocarbon group; P1 to P4 each independently represents a group of atoms necessary for forming a heterocyclic ring together with each Y1 to Y4 and the two carbon atoms adjacent to Y1 to Y4, respectively; P5 and P6 each independently represents a group of atoms necessary for forming a cyclic skeleton together with the carbon atom to which Z1 bonds or Z2 bonds; P1 and P2, P2 and P6, P6 and P4, P4 and P3, P3 and P5, and P5 and P1 may further combine with each other to form a ring; Q1 and Q2 each independently represents a connecting group or a direct binding; and Z1 and Z2 each independently represent any one of the following groups; —NRβ2, —ORβ, —SRβ, —PRβ2 in which Rβ represents a hydrogen atom or a monovalent hydrocarbon group, and when plural Rβs are present, these plural Rβs may be the same or different from each other.

    摘要翻译: 由式(1)表示的化合物:其中Y 1至Y 4各自独立地表示以下基团中的任一个:其中Rα表示氢原子或一价烃基; P1至P4各自独立地表示与Y1至Y4和Y1至Y4相邻的两个碳原子一起形成杂环所需的一组原子团; P5和P6各自独立地表示与Z1键或Z2键的碳原子一起形成环状骨架所需的原子团; P1和P2,P2和P6,P6和P4,P4和P3,P3和P5,P5和P1可以进一步组合形成环; Q1和Q2各自独立地表示连接基团或直接结合; Z1和Z2各自独立地表示以下基团中的任何一个; -NR&bgr; 2,-OR&bgr; -SR&bgr; -PR&bgr; 2其中R&bgr; 表示氢原子或一价烃基,当存在多个R b时,这些多个R a可相同或不同。

    Redox Flow Battery System including an Anode Electrode having a Subsurface Alloy
    9.
    发明申请
    Redox Flow Battery System including an Anode Electrode having a Subsurface Alloy 有权
    氧化还原液流电池系统,包括具有地下合金的阳极电极

    公开(公告)号:US20140234684A1

    公开(公告)日:2014-08-21

    申请号:US14184765

    申请日:2014-02-20

    申请人: Robert Bosch GmbH

    IPC分类号: H01M8/18 H01M4/90

    摘要: A hydrogen/bromine reduction-oxidation flow battery system includes a bromine electrode, a hydrogen electrode, a membrane, a first catalyst, and a second catalyst. The membrane is positioned between the bromine electrode and the hydrogen electrode. The first catalyst is associated with the bromine electrode. The second catalyst is associated with the hydrogen electrode and at least partially formed from a subsurface alloy configured (i) to promote facile dissociation of H2, and (ii) to prevent bromide from adsorbing onto the hydrogen electrode.

    摘要翻译: 氢/溴还原 - 氧化流动电池系统包括溴电极,氢电极,膜,第一催化剂和第二催化剂。 膜位于溴电极和氢电极之间。 第一种催化剂与溴电极相关。 第二催化剂与氢电极相关联并且至少部分地由地下合金形成,其构造为:(i)促进H2的容易解离,和(ii)防止溴吸附在氢电极上。