公开(公告)号：US20240254000A1

公开(公告)日：2024-08-01

申请号：US18634542

申请日：2024-04-12

Applicant: Shin-Etsu Chemical Co., Ltd.

Inventor： Yasushi Takai ,  Noriaki Hamaya

IPC: C01F17/259 ,  C01F17/218 ,  C01F17/265 ,  C23C4/10 ,  C23C4/134

CPC classification number: C01F17/259 ,  C01F17/218 ,  C01F17/265 ,  C23C4/10 ,  C23C4/134 ,  C01P2004/61

Abstract: Provided is a slurry for suspension plasma spraying, which is a spray material used for suspension plasma spraying in an atmosphere including an oxygen-containing gas, contains 5-40 mass % of rare earth fluoride particles having a maximum particle diameter (D100) of 12 μm or less, and contains one or more types of solvent selected from among water and organic solvents. A rare earth acid fluoride-containing sprayed film, in which process shift and particle generation hardly occur, can be stably formed on a base material by carrying out suspension plasma spraying in an atmosphere including an oxygen-containing gas. A spraying member provided with this sprayed film exhibits excellent corrosion resistance to halogen-based gas plasma.

公开(公告)号：US12018385B2

公开(公告)日：2024-06-25

申请号：US18339282

申请日：2023-06-22

Applicant: KoMiCo Ltd.

Inventor： Ki Won Hong ,  Dong Hun Jeong ,  Seong Sik Bang

IPC: C23C4/11 ,  C01F17/218 ,  C01F17/259 ,  C01F17/265 ,  C04B35/505 ,  C04B35/515 ,  C04B35/553 ,  C23C4/134

CPC classification number: C23C4/134 ,  C01F17/218 ,  C01F17/259 ,  C01F17/265 ,  C04B35/505 ,  C04B35/5156 ,  C04B35/553 ,  C23C4/11

Abstract: Disclosed are a material for spray for plasma spray coating having high plasma resistance and a method for producing the same. The material for plasma spray comprises an yttrium compound, and the numbers of moles of Y (yttrium), O (oxygen), and F (fluorine) in the yttrium compound satisfy 1.5

公开(公告)号：US20230100603A1

公开(公告)日：2023-03-30

申请号：US18075586

申请日：2022-12-06

Applicant: Shin-Etsu Chemical Co., Ltd.

Inventor： Yuji Kimura ,  Yasushi Takai ,  Shigeyuki Nakamura

IPC: C23C24/02 ,  C01F17/259

Abstract: A film-forming powder containing a rare earth oxyfluoride has an average particle size D50 of 0.6-15 μm, a total volume of 10 μm pores of 0.51-1.5 cm3/g as measured by mercury porosimetry, and a BET surface area of 3-50 m2/g is suitable for forming a dense film in high yields or deposition rates and high productivity. The film-forming powder having a greater pore volume can be prepared by forming a rare earth ammonium fluoride complex salt on surfaces of rare earth oxide particles to provide precursor particles, and heat treating the precursor particles at a temperature of 350 to 700° C.

公开(公告)号：US11560319B1

公开(公告)日：2023-01-24

申请号：US17849365

申请日：2022-06-24

Applicant: KOMICO LTD.

Inventor： Ki Won Hong ,  Seong Sik Bang ,  Dong Hun Jeong

IPC: C01F17/259 ,  C23C4/134 ,  C23C4/04 ,  H05H1/34

Abstract: Proposed is a method for manufacturing a spherical YOF-based powder. Specifically, proposed is a method for manufacturing a spherical YOF-based powder. The YOF-based powder injected into the plasma jet and melted into the refrigerant in a droplet state is sprayed and quenched, thereby improving density and controlling the component ratio through particle spheroidization.

公开(公告)号：US20210277509A1

公开(公告)日：2021-09-09

申请号：US16316158

申请日：2017-07-10

Applicant: Shin-Etsu Chemical Co., Ltd.

Inventor： Yasushi Takai ,  Noriaki Hamaya

IPC: C23C4/10 ,  C23C4/134 ,  C01F17/265 ,  C01F17/259

Abstract: Provided is a slurry for suspension plasma spraying, which is a spray material used for suspension plasma spraying in an atmosphere including an oxygen-containing gas, contains 5-40 mass % of rare earth fluoride particles having a maximum particle diameter (D100) of 12 μm or less, and contains one or more types of solvent selected from among water and organic solvents. A rare earth acid fluoride-containing sprayed film, in which process shift and particle generation hardly occur, can be stably formed on a base material by carrying out suspension plasma spraying in an atmosphere including an oxygen-containing gas. A spraying member provided with this sprayed film exhibits excellent corrosion resistance to halogen-based gas plasma.

公开(公告)号：US20240051839A1

公开(公告)日：2024-02-15

申请号：US18384076

申请日：2023-10-26

Applicant: Shin-Etsu Chemical Co., Ltd.

Inventor： Yasushi Takai ,  Noriaki Hamaya

IPC: C01F17/259 ,  C01F17/218 ,  C23C4/134 ,  C01F17/265 ,  C23C4/10

CPC classification number: C01F17/259 ,  C01F17/218 ,  C23C4/134 ,  C01F17/265 ,  C23C4/10 ,  C01P2004/61

Abstract: A sprayed article is disclosed including a substrate and a sprayed coating deposited thereon and containing a rare earth oxyfluoride as main phase. Provided is a slurry for suspension plasma spraying, which is a spray material used for suspension plasma spraying in an atmosphere including an oxygen-containing gas, contains 5-40 mass % of rare earth fluoride particles having a maximum particle diameter (D100) of 12 μm or less, and contains one or more types of solvent selected from among water and organic solvents. A rare earth acid fluoride-containing sprayed film, in which process shift and particle generation hardly occur, can be stably formed on a base material by carrying out suspension plasma spraying in an atmosphere including an oxygen-containing gas. A spraying member provided with this sprayed film exhibits excellent corrosion resistance to halogen-based gas plasma.

公开(公告)号：US11827526B2

公开(公告)日：2023-11-28

申请号：US17732782

申请日：2022-04-29

Applicant: Toyota Motor Engineering & Manufacturing North America, Inc.

Inventor： Shingo Ota ,  Ryuta Sugiura ,  Timothy S. Arthur ,  Nikhilendra Singh

IPC: C01G49/10 ,  C01G49/00 ,  H01M10/0562 ,  H01M4/62 ,  C01F7/786 ,  C01F17/259

CPC classification number: C01G49/0018 ,  H01M10/0562 ,  C01F7/786 ,  C01F17/259 ,  C01G49/10 ,  H01M4/62 ,  H01M2300/0008

Abstract: An inorganic compound for a Li-ion conductor includes an oxyhalide compound with a chemical composition of MOX where M is at least one of Al, Sc, La, and Y, and X is at least one of F, Cl, Br, and I. Also, the oxyhalide compound has a thermal decomposition start temperature of the oxyhalide compound is greater than a thermal decomposition start temperature of FeOCl and a conductivity that is general equal to or greater than a conductivity of the FeOCl.

公开(公告)号：US11549185B2

公开(公告)日：2023-01-10

申请号：US16511283

申请日：2019-07-15

Applicant: Shin-Etsu Chemical Co., Ltd.

Inventor： Yuji Kimura ,  Yasushi Takai ,  Shigeyuki Nakamura

IPC: C23C24/02 ,  C01F17/259

Abstract: A film-forming powder containing a rare earth oxyfluoride has an average particle size D50 of 0.6-15 μm, a total volume of ≤10 μm pores of 0.51-1.5 cm3/g as measured by mercury porosimetry, and a BET surface area of 3-50 m2/g is suitable for forming a dense film in high yields or deposition rates and high productivity. The film-forming powder having a greater pore volume can be prepared by forming a rare earth ammonium fluoride complex salt on surfaces of rare earth oxide particles to provide precursor particles, and heat treating the precursor particles at a temperature of 350 to 700° C.

公开(公告)号：US11414325B2

公开(公告)日：2022-08-16

申请号：US16343945

申请日：2017-08-07

Applicant: NIPPON YTTRIUM CO., LTD.

Inventor： Naoki Fukagawa ,  Ryuichi Sato

IPC: C09D1/00 ,  C01B11/24 ,  C09D5/00 ,  C23C14/08 ,  C01F17/259 ,  C23C14/24 ,  C23C14/06 ,  C09D7/61

Abstract: A coating material containing an oxyfluoride of yttrium and having a Fisher diameter of 1.0 to 10 μm and a tap density TD to apparent density AD ratio, TD/AD, of 1.6 to 3.5. The coating material preferably has a pore volume of pores with a diameter of 100 μm or smaller of 1.0 cm3/g or less as measured by mercury intrusion porosimetry. A coating containing an oxyfluoride of yttrium and having a Vickers hardness of 200 HV0.01 or higher. The coating preferably has a fracture toughness of 1.0×102 Pa·m1/2 or higher.

公开(公告)号：US20240102142A1

公开(公告)日：2024-03-28

申请号：US18517251

申请日：2023-11-22

Applicant: Shin-Etsu Chemical Co., Ltd.

Inventor： Noriaki Hamaya ,  Ichiro Uehara

IPC: C23C4/11 ,  B32B9/00 ,  C01F17/259 ,  C01F17/265 ,  C04B35/50 ,  C04B35/515 ,  C09D1/00 ,  C09D5/03 ,  C23C4/134

CPC classification number: C23C4/11 ,  B32B9/005 ,  C01F17/259 ,  C01F17/265 ,  C04B35/50 ,  C04B35/5156 ,  C09D1/00 ,  C09D5/03 ,  C23C4/134 ,  C04B2237/34 ,  C04B2237/36

Abstract: A spray coating containing a rare earth fluoride and/or a rare earth acid fluoride contains carbon at 0.01-2% by mass or titanium or molybdenum at 1-1000 ppm. When an acid fluoride is not contained, the spray coating is gray to black in which, in terms of the L*a*b* chromaticity, L* is 25-64, a* is −3.0 to +5.0, and b* is −4.0 to +8.0. When an acid fluoride is contained, the spray coating is white or gray to black in which, in terms of the L*a*b* chromaticity, L* is equal to or greater than 25 and less than 91, a* is −3.0 to +5.0, and b* is −6.0 to +8.0. By forming this coating on a plasma resistant member, a partial color change is reduced, thus, a member that is capable of reliably realizing the original longevity is obtained.