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公开(公告)号:US11691889B2
公开(公告)日:2023-07-04
申请号:US17457695
申请日:2021-12-06
发明人: Naoki Fukagawa , Ryuichi Sato
CPC分类号: C01F17/259 , C01B11/24 , C09D1/00 , C09D5/00 , C09D7/61 , C23C14/06 , C23C14/083 , C23C14/24 , C01P2002/72 , C01P2004/02 , C01P2004/03 , C01P2004/61 , C01P2006/10 , C01P2006/11 , C01P2006/14 , C01P2006/16
摘要: A coating material containing an oxyfluoride of yttrium and having a Fisher diameter of 1.0 to 10 μm and a tap density TD to apparent density AD ratio, TD/AD, of 1.6 to 3.5. The coating material preferably has a pore volume of pores with a diameter of 100 μm or smaller of 1.0 cm3/g or less as measured by mercury intrusion porosimetry. A coating containing an oxyfluoride of yttrium and having a Vickers hardness of 200 HV0.01 or higher. The coating preferably has a fracture toughness of 1.0×102 Pa·m1/2 or higher.
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公开(公告)号:US20150096462A1
公开(公告)日:2015-04-09
申请号:US14117160
申请日:2013-04-12
发明人: Naoki Fukagawa , Yuki Nakashima
IPC分类号: C23C4/10
CPC分类号: C23C4/10 , C04B35/553 , C04B35/62655 , C04B35/62675 , C04B35/62695 , C04B2235/3224 , C04B2235/3225 , C04B2235/3895 , C04B2235/5436 , C04B2235/6583 , C04B2235/96 , C23C4/04 , C23C4/129 , C23C4/134
摘要: A thermal spray material includes granules of an oxyfluoride of yttrium (YOF). The granules may contain a fluoride of yttrium (YF3). The granules preferably have an oxygen content of 0.3 to 13.1 mass %. The granules preferably have a fracture strength of 0.3 MPa or more and less than 10 MPa. Part of yttrium (Y) of the granules may be displaced with at least one rare earth element (Ln) except yttrium, the molar fraction of Ln relative to the sum of Y and Ln being preferably 0.2 or less.
摘要翻译: 热喷涂材料包括钇(YOF)的氟氧化物的颗粒。 颗粒可以含有钇(YF 3)的氟化物。 颗粒的氧含量优选为0.3〜13.1质量%。 该颗粒的断裂强度优选为0.3MPa以上且小于10MPa。 除了钇之外,颗粒的一部分钇(Y)可以用至少一种稀土元素(Ln)置换,Ln相对于Y和Ln之和的摩尔分数优选为0.2以下。
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公开(公告)号:US11773493B2
公开(公告)日:2023-10-03
申请号:US17288302
申请日:2019-10-18
发明人: Ryuichi Sato , Naoki Fukagawa , Kento Matsukura , Shuki Mikoda , Seiji Moriuchi , Yuji Shigeyoshi , Masahiro Fukumoto , Motohiro Yamada
IPC分类号: C23C24/04
CPC分类号: C23C24/04
摘要: A material for cold spraying contains a powder of a compound of a rare earth element with a specific surface area of 30 m2/g or more as determined by a BET single-point method. The powder preferably has a volume of pores with a pore size of 3 to 20 nm of 0.08 cm3/g or more as determined by a gas absorption method. The powder also preferably has a crystallite diameter of 25 nm or less. The powder also preferably has a repose angle of from 10 to 60°. In the L*a*b* color system, the powder also preferably has a value L of 85 or more, a value a of from −0.7 to 0.7, and a value b of from −1 to 2.5.
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公开(公告)号:US09708187B2
公开(公告)日:2017-07-18
申请号:US14390793
申请日:2013-10-24
发明人: Naoki Fukagawa , Satoshi Ariyoshi
CPC分类号: C01B11/24 , C01F17/0012 , C01F17/0062 , C01P2004/54 , C01P2004/61 , C01P2006/10 , C01P2006/11 , C01P2006/20 , C01P2006/21 , C23C4/02 , C23C4/10 , C23C4/134 , Y10T428/2982
摘要: A thermal spray material comprising granules containing a rare earth oxyfluoride has a particle diameter of 1 to 150 μm at a cumulative volume of 50 vol % before ultrasonic dispersion and 10 μm or smaller after ultrasonic dispersion at 300 W for 15 minutes as determined by laser diffraction/scattering particle size distribution analysis. The particle diameter after ultrasonic dispersion is one-third or less of that before ultrasonic dispersion. The thermal spray material has an average aspect ratio of 2.0 or lower and a compressibility of 30% or less. When the granules further contain a rare earth fluoride, upon being analyzed by X-ray diffractometry using Cu-Kα or Cu-Kα1 radiation, S1/S2 is preferably ≧0.10. S1=intensity of the maximum peak assigned to the rare earth oxyfluoride. S2=intensity of the maximum peak assigned to the rare earth fluoride, both observed in a 2θ angle range of 20° to 40°.
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公开(公告)号:US09388485B2
公开(公告)日:2016-07-12
申请号:US14117160
申请日:2013-04-12
发明人: Naoki Fukagawa , Yuki Nakashima
IPC分类号: C04B35/50 , C04B35/505 , C04B35/553 , C23C4/10 , C04B35/626 , C23C4/04
CPC分类号: C23C4/10 , C04B35/553 , C04B35/62655 , C04B35/62675 , C04B35/62695 , C04B2235/3224 , C04B2235/3225 , C04B2235/3895 , C04B2235/5436 , C04B2235/6583 , C04B2235/96 , C23C4/04 , C23C4/129 , C23C4/134
摘要: A thermal spray material includes granules of an oxyfluoride of yttrium (YOF). The granules may contain a fluoride of yttrium (YF3). The granules preferably have an oxygen content of 0.3 to 13.1 mass %. The granules preferably have a fracture strength of 0.3 MPa or more and less than 10 MPa. Part of yttrium (Y) of the granules may be displaced with at least one rare earth element (Ln) except yttrium, the molar fraction of Ln relative to the sum of Y and Ln being preferably 0.2 or less.
摘要翻译: 热喷涂材料包括钇(YOF)的氟氧化物的颗粒。 颗粒可以含有钇(YF 3)的氟化物。 颗粒的氧含量优选为0.3〜13.1质量%。 该颗粒的断裂强度优选为0.3MPa以上且小于10MPa。 除了钇之外,颗粒的一部分钇(Y)可以用至少一种稀土元素(Ln)置换,Ln相对于Y和Ln之和的摩尔分数优选为0.2以下。
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公开(公告)号:US11414325B2
公开(公告)日:2022-08-16
申请号:US16343945
申请日:2017-08-07
发明人: Naoki Fukagawa , Ryuichi Sato
摘要: A coating material containing an oxyfluoride of yttrium and having a Fisher diameter of 1.0 to 10 μm and a tap density TD to apparent density AD ratio, TD/AD, of 1.6 to 3.5. The coating material preferably has a pore volume of pores with a diameter of 100 μm or smaller of 1.0 cm3/g or less as measured by mercury intrusion porosimetry. A coating containing an oxyfluoride of yttrium and having a Vickers hardness of 200 HV0.01 or higher. The coating preferably has a fracture toughness of 1.0×102 Pa·m1/2 or higher.
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公开(公告)号:US11371131B2
公开(公告)日:2022-06-28
申请号:US16882050
申请日:2020-05-22
发明人: Ryuichi Sato , Naoki Fukagawa , Yuji Shigeyoshi , Kento Matsukura
IPC分类号: C23C4/11 , C23C4/10 , C23C4/04 , C23C14/06 , C23C14/34 , C04B35/50 , C04B35/515 , C04B35/553 , C23C14/26 , C23C14/35 , C23C24/08 , C04B111/00
摘要: The present invention relates a coating powder comprising a rare earth oxyfluoride (Ln-O—F) and having: an average particle size (D50) of 0.1 to 10 μm, a pore volume of pores having a diameter of 10 μm or smaller of 0.1 to 0.5 cm3/g as measured by mercury intrusion porosimetry, and a ratio of the maximum peak intensity (S0) assigned to a rare earth oxide (LnxOy) in the 2θ angle range of from 20° to 40° to the maximum peak intensity (S1) assigned to the rare earth oxyfluoride (Ln-O—F) in the same range, S0/S1, of 1.0 or smaller in powder X-ray diffractometry using Cu-Kα rays or Cu-Kα1 rays.
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公开(公告)号:US20150111037A1
公开(公告)日:2015-04-23
申请号:US14390793
申请日:2013-10-24
发明人: Naoki Fukagawa , Satoshi Ariyoshi
IPC分类号: C01B11/24
CPC分类号: C01B11/24 , C01F17/0012 , C01F17/0062 , C01P2004/54 , C01P2004/61 , C01P2006/10 , C01P2006/11 , C01P2006/20 , C01P2006/21 , C23C4/02 , C23C4/10 , C23C4/134 , Y10T428/2982
摘要: A thermal spray material comprising granules containing a rare earth oxyfluoride has a particle diameter of 1 to 150 μm at a cumulative volume of 50 vol % before ultrasonic dispersion and 10 μm or smaller after ultrasonic dispersion at 300 W for 15 minutes as determined by laser diffraction/scattering particle size distribution analysis. The particle diameter after ultrasonic dispersion is one-third or less of that before ultrasonic dispersion. The thermal spray material has an average aspect ratio of 2.0 or lower and a compressibility of 30% or less. When the granules further contain a rare earth fluoride, upon being analyzed by X-ray diffractometry using Cu-Kα or Cu-Kα1 radiation, S1/S2 is preferably ≧0.10. S1=intensity of the maximum peak assigned to the rare earth oxyfluoride. S2=intensity of the maximum peak assigned to the rare earth fluoride, both observed in a 2θ angle range of 20° to 40°.
摘要翻译: 包含稀土氧氟化物的颗粒的热喷涂材料在超声波分散之前的累积体积为50体积%,在300W下超声分散后为10μm以下,通过激光衍射测定,其粒径为1〜150μm /散射粒度分布分析。 超声波分散后的粒径为超声波分散前的粒径的三分之一以下。 热喷涂材料的平均纵横比为2.0以下,压缩率为30%以下。 当颗粒进一步含有稀土氟化物时,通过使用Cu-Kα或Cu-Kα1辐射的X射线衍射分析,S1 / S2优选为≥0.10。 S1 =分配给稀土氟氧化物的最大峰的强度。 S2 =分配给稀土氟化物的最大峰值的强度,均在2℃观察到; 角度范围为20°至40°。
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公开(公告)号:US10934174B2
公开(公告)日:2021-03-02
申请号:US16061242
申请日:2016-12-15
发明人: Ryuichi Sato , Naoki Fukagawa , Yuji Shigeyoshi , Kento Matsukura
IPC分类号: C23C14/06 , C23C4/04 , C04B35/553 , C04B35/50 , C01F17/00 , C23C24/04 , C01F17/265 , C23C14/48 , C23C4/12
摘要: A film-forming material of the present invention contains an oxyfluoride of yttrium represented by YOXFY (X and Y are numbers satisfying 0
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公开(公告)号:US10173929B2
公开(公告)日:2019-01-08
申请号:US15545799
申请日:2016-02-26
发明人: Naoki Fukagawa , Yuji Shigeyoshi
IPC分类号: C04B35/553 , C04B35/505 , C04B35/50 , C04B35/622 , C04B35/626 , C04B35/634 , C04B35/64 , B01J2/00 , C01F17/00
摘要: The present invention is a sintering material including a granule, the sintering material having an apparent tap density of 1.0 to 2.5 g/cm3, a 50% cumulative volume particle diameter (D50N) of 10 to 100 μm as measured before ultrasonication by laser diffraction/scattering particle size distribution analysis, a 50% cumulative volume particle diameter (D50D) of 0.1 to 1.5 μm as measured after ultrasonication at 300 W for 15 minutes by laser diffraction/scattering particle size distribution analysis, and an X-ray diffraction pattern in which the maximum peak observed in the 2θ angle range of from 20° to 40° is assigned to a rare earth oxyfluoride of the form LnOF when analyzed by X-ray diffractometry using Cu—Kα or Cu—Kα1 rays.
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