公开(公告)号：US20040249103A1

公开(公告)日：2004-12-09

申请号：US10490163

申请日：2004-04-30

发明人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

IPC分类号： C08G077/04

CPC分类号： C08G77/20 ,  C07F7/21 ,  C08G77/04 ,  C08G77/045 ,  C08G77/14

摘要： The present inventors have obtained a PSQ derivative of a completely condensed type into which a functional group is readily introduced by using a novel PSQ derivative of an incompletely condensed type in which four alkaline metal atoms are bonded to silsesquioxane of a cage type having eight Si's. The above silsesquioxane derivative is represented by Formula (1). A silsesquioxane derivative to which alkaline metal atoms are bonded is represented by Formula (2). In Formula (1) and Formula (2), R is a group selected from alkyl, aryl and arylalkyl; Y is a group represented by Formula (a) or Formula (b); and M is a monovalent alkaline metal atom. X in Formula (a) and Formula (b) is hydrogen, halogen, a hydroxyl group or a monovalent organic group, and Z is nullOnull, nullCH2null or a single bond. The preferred organic group is a functional group or a group having a functional group.

摘要翻译： 本发明人已经获得了一种完全冷凝型的PSQ衍生物，其中通过使用四种碱金属原子与具有八个Si的笼型的倍半硅氧烷结合的不完全冷凝型的新型PSQ衍生物容易地引入官能团。 上述倍半硅氧烷衍生物由式（1）表示。 碱金属原子键合的倍半硅氧烷衍生物由式（2）表示。 在式（1）和式（2）中，R是选自烷基，芳基和芳烷基的基团; Y为式（a）或式（b）所示的基团。 M为单价碱金属原子。 式（a）和式（b）中的X为氢，卤素，羟基或一价有机基团，Z为-O-，-CH 2 - 或单键。 优选的有机基团是官能团或具有官能团的基团。

公开(公告)号：US20040249089A1

公开(公告)日：2004-12-09

申请号：US10482638

申请日：2004-07-15

发明人： Ricky K.C. Yeung

IPC分类号： C08G077/04

CPC分类号： C08L83/04 ,  B29C43/003 ,  B29K2021/00 ,  B29K2105/0097 ,  C08K3/011 ,  C08L83/00

摘要： The present invention relates to a novel silicone rubber material. The feedstocks for preparing the silicone rubber are a crosslinkable siloxane, a methylsiloxane resin and a cross-linking agent This material is in solid state and has a high adhesivity. The present invention further relates to a process for preparing said silicone rubber material and uses in the area of self-adhesives with skid-prevention.

公开(公告)号：US20040220330A1

公开(公告)日：2004-11-04

申请号：US10797418

申请日：2004-03-10

发明人： James Louis DeRudder ,  Niles Richard Rosenquist ,  Gary Charles Davis ,  Matthew Robert Pixton ,  Mark Erik Nelson ,  Zhaohui Su

IPC分类号： C08L083/00 ,  C08G077/04

CPC分类号： C08L83/10 ,  C08G64/186 ,  C08G64/24 ,  C08G77/448 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/18

摘要： A method is provided for making siloxane polycarbonate copolymers and blends of other polycarbonates with such copolymers wherein the copolymers and blends have excellent transparency and physical characteristic.

摘要翻译： 提供了制备硅氧烷聚碳酸酯共聚物和其它聚碳酸酯与这种共聚物的共混物的方法，其中共聚物和共混物具有优异的透明度和物理特性。

公开(公告)号：US20040210021A1

公开(公告)日：2004-10-21

申请号：US10843017

申请日：2004-05-11

发明人： Kevin M. Harris ,  Murali Rajagopalan

IPC分类号： A63B037/12 ,  C08G077/04

CPC分类号： A63B37/12 ,  A63B37/0003 ,  A63B37/0031 ,  A63B37/0033 ,  A63B37/0043 ,  A63B37/0045 ,  A63B37/0062 ,  A63B37/0064 ,  A63B37/0076 ,  A63B37/0087 ,  C08G18/3225 ,  C08G18/44 ,  C08G18/4854 ,  C08G18/61 ,  C08G18/758

摘要： A golf ball comprising a cover and a core, and optionally at least one intermediate layer interposed between the cover and the core, wherein the cover or the intermediate layer or both are formed from a blend comprising a thermoplastic silicone-urethane copolymer. The silicone content of the silicone-urethane copolymer is between 1 and 20 percent by weight.

摘要翻译： 一种包括盖和芯的高尔夫球，以及可选地插入在所述盖和所述芯之间的至少一个中间层，其中所述盖或所述中间层或两者均由包含热塑性硅氧烷 - 氨基甲酸酯共聚物的共混物形成。 硅氧烷 - 氨基甲酸酯共聚物的硅氧烷含量为1至20重量％。

公开(公告)号：US20040186259A1

公开(公告)日：2004-09-23

申请号：US10804511

申请日：2004-03-19

发明人： Isabella Brehm ,  Ingrid Eissmann ,  Heike Luther ,  Philipp Tomuschat

IPC分类号： C08G077/04

CPC分类号： C08G77/46 ,  C08G77/08 ,  C08G77/38

摘要： The present invention provides a process for reacting A) polyorganosiloxanes which contain nullSi(H) units and are of the general formula (I) 1 with B) a mono- or pholyhydric alcohol, which comprises using small amounts of a mixture which consists of at least one acid and at least one salt of an acid as a catalyst.

摘要翻译： 本发明提供一种使A）含有-Si（H）单元并且具有通式（I）的聚有机硅氧烷与B）一元或一元醇反应的方法，该方法包括使用少量由 至少一种酸和至少一种酸作为催化剂的盐。

公开(公告)号：US20040132948A1

公开(公告)日：2004-07-08

申请号：US10737998

申请日：2003-12-18

申请人： Olympus Corporation

发明人： Michio Shirai

IPC分类号： C08G077/04

CPC分类号： C08G59/502 ,  C08K5/5419 ,  G02B1/04 ,  C08L83/10 ,  C08L63/00

摘要： The present invention is directed to provide an organic/inorganic composite optical material and an optical element in which organic component and inorganic component are in good dispersed state and which has excellent optical characteristics. The organic/inorganic composite optical material comprises an organic high-molecular substance and an inorganic polymer which is prepared by the polycondensation of a metal alkoxide compound, and is characterized in that the metal alkoxide compound includes a functional group capable of interacting with the organic high-molecular substance or a monomer/oligomer generating the organic high-molecular substance to form a chemical bond therebetween.

摘要翻译： 本发明旨在提供有机/无机复合光学材料和其中有机组分和无机组分处于良好分散状态并具有优异光学特性的光学元件。 有机/无机复合光学材料包括通过金属醇盐化合物的缩聚制备的有机高分子物质和无机聚合物，其特征在于金属醇盐化合物包括能够与有机高分子相互作用的官能团 分子物质或产生有机高分子物质的单体/低聚物以在它们之间形成化学键。

公开(公告)号：US20040082681A1

公开(公告)日：2004-04-29

申请号：US10685141

申请日：2003-10-14

发明人： Mike Brand ,  Hardi Dohler ,  Winfried Hamann ,  Jurgen Pomorin

IPC分类号： C08G077/04

CPC分类号： C09D183/06 ,  C08K5/07 ,  Y10T428/1457 ,  Y10T428/31663

摘要： The present invention provides for the use of radiation-curable coating compositions comprising at least one radiation-curable organopolysiloxane having (meth)acrylic ester groups and a photoinitiator, wherein said photoinitiator includes at least one compound of the general formula 1 in which R1 is a linear or branched alkyl radical having 3 to 18 carbon atoms, preferably 4 to 12 carbon atoms, R2 is an alkyl radical having 1 to 4 carbon atoms, preferably hydrogen, R3, R4 are alkyl radicals having 1 to 6 carbon atoms, which may also have been linked to form a 5- or 6-membered carbon ring or one of these radicals may also be hydrogen, and R5 is an alkyl or alkanoyl radical, preferably hydrogen; for preparing abhesive coating materials and producing abhesive coatings.

摘要翻译： 本发明提供了使用包含至少一种具有（甲基）丙烯酸酯基和光引发剂的可辐射固化的有机聚硅氧烷的可辐射固化涂料组合物，其中所述光引发剂包括至少一种通式的化合物，其中R 1， 是具有3至18个碳原子，优选4至12个碳原子的直链或支链烷基，R 2是具有1至4个碳原子的烷基，优选氢，R 3，R 4是烷基 也可以连接形成5或6元碳环或这些基团之一的具有1至6个碳原子的基团也可以是氢，R 5是烷基或烷酰基，优选氢; 用于制备粘合剂涂料和生产粘合剂涂料。

公开(公告)号：US20040014924A1

公开(公告)日：2004-01-22

申请号：US10296997

申请日：2003-06-04

发明人： Reinhold Nowak ,  Joachim Zech ,  Peter Bissinger ,  Erich Wanek ,  Gunther Eckhardt ,  Guenther Lechner

IPC分类号： C08G077/04

CPC分类号： A61K6/093 ,  A61K6/0017 ,  A61K6/0023 ,  A61K6/10 ,  C08G77/388 ,  C08L83/08 ,  C08L83/12

摘要： Arizidinosilicones of the general formula (1), wherein R1 represents H, C1-C12 alkyl, C2-C12 alkenyl, C2-C12 alkinyl, C7-C15 alkaryl, C7-C15 aralkyl, C3-C12 cycloalkyl and these groups can be substituted with C1 or F partially, completely or in a mixed manner and/or may contain 0 to 5 heteroatoms selected from O, N, S, R2 represents a group of the selection of R1 and/or R4, and R3 represents SiR13 or SiR12R4, and wherein R4 represents formula (2), and A represents an (nnull1) radical saturated, unsaturated or aromatic, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S and that includes 1 to 18 carbon atoms, B is selected from O, S, NR1, D is selected from C(O)O, C(O)NR1, C(O), C(O)C(O), C(O)(CH2)m(C(O), C(S)NR1, CH2, E represents a diradical saturated or unsaturated, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S and that includes 0 to 18 carbon atoms, a is 0 or 1, f is an integer from 2 to 1000, n, m is an integer from 1 to 10, and x, y, z each represents 0 or an integer, the sum of which should range between 1 and 10000, with the proviso that, if x is larger 0, y or z is smaller or equal x, preferably smaller or equal 0.05 times x, and especially preferred 0.02 times x. The invention also relates to the use of arizidinosilicones.

摘要翻译： 通式（1）的亚氮烷硅氧烷，其中R1表示H，C1-C12烷基，C2-C12烯基，C2-C12炔基，C7-C15烷芳基，C7-C15芳烷基，C3-C12环烷基，这些基团可以被 C1或F部分，完全或以混合方式和/或可以含有0至5个选自O，N，S的杂原子，R 2表示选自R 1和/或R 4的基团，R 3表示SiR 13或SiR 12 R 4， 其中R 4表示式（2），A表示可以含有0至5个选自O，N，S的杂原子的（n + 1）基饱和，不饱和或芳族，直链，支链或环状的烃基，其包括1至 18个碳原子，B选自O，S，NR1，D选自C（O）O，C（O）NR1，C（O），C（O）C（O），C（O） ）m（C（O），C（S）NR1，CH2，E表示可以含有0至5个选自O，N，S的杂原子的二价饱和或不饱和的直链，支链或环状烃基， 18个碳原子，a为0或1，f为整数 从2到1000，n，m是1至10的整数，x，y，z各自表示0或整数，其总和应在1和10000之间，条件是如果x大于0 ，y或z小于或等于x，优选小于或等于0.05倍×，特别优选0.02倍×。 本发明还涉及三氮杂的使用。

公开(公告)号：US20030199661A1

公开(公告)日：2003-10-23

申请号：US10203983

申请日：2002-12-02

发明人： Jean-Marc Frances

IPC分类号： C08G077/04 ,  C08G059/00

CPC分类号： C09D183/06 ,  C08J7/047 ,  C08J2483/06 ,  Y10T428/31511 ,  Y10T428/31663 ,  C08L83/00 ,  C08L2666/28 ,  C08L2666/44 ,  C08L2666/02

摘要： The invention concerns a novel method for treating the surface of plastic material comprising the following steps: (1) applying on at least one of the surfaces of the plastic material a composition with polymerisable and/or crosslinkable reactive functions, by cationic process or by cationic and radical process comprising 1 to 99 wt. % of at least a polymerisable and/or at least partly polymerised organic matrix A having oxetane reactive functions (frA); 99 to 1 wt. % of at least a polymerisable and/or at least partly polymerised organic matrix B, including (co) monomers, (co)oligomers and/or (co)polymers selected among those having epoxy (null1) and/or acrylate (null2) and/or alkenyl-ether (null3) and/or hydroxy (null4) reactive functions (frB); an efficient amount of at least a cationic or cationic and radical initiator system C; optionally at least a sensitizer D and at least a pigment E; (2) polymerising and/or crosslinking the treated surface by exposure under an irradiating source and/or under electron beam(s).

摘要翻译： 本发明涉及一种用于处理塑料材料表面的新方法，包括以下步骤：（1）通过阳离子方法或通过阳离子方法在塑料材料的至少一个表面上施加具有可聚合和/或可交联的反应性官能团的组合物 和自由基方法，其包含1至99wt。 ％的至少可聚合的和/或至少部分聚合的具有氧杂环丁烷反应性官能团（frA）的有机基质A; 99〜1重量％ 至少可聚合的和/或至少部分聚合的有机基质B的％，包括选自具有环氧（α1）和/或丙烯酸酯（α2）的那些的（共）单体，（共）低聚物和/或（共） /或烯基醚（α3）和/或羟基（α4）反应性官能团（frB）; 有效量的至少阳离子或阳离子和自由基引发剂体系C; 任选地至少一种敏化剂D和至少一种颜料E; （2）通过在照射源和/或电子束下曝光来聚合和/或交联处理过的表面。

公开(公告)号：US20030199660A1

公开(公告)日：2003-10-23

申请号：US10296593

申请日：2002-11-26

发明人： Koji Sakuta

IPC分类号： C08G077/04

CPC分类号： C08G77/46 ,  A61K8/89 ,  A61K8/893 ,  A61K8/894 ,  A61Q1/02 ,  A61Q1/10 ,  A61Q5/00 ,  A61Q15/00 ,  A61Q17/04 ,  A61Q19/00 ,  A61Q19/001 ,  A61Q19/002 ,  A61Q19/08

摘要： This invention relates to a silicone polymer which is insoluble in organic solvents because it has a three-dimensional crosslinked structure which swells up relative to fluorosilicone oils, to a paste-like composition formed by making the silicone compounds swell up in silicone oil, and to a cosmetic material. It is therefore an object of this invention to provide a silicone polymer having a fluorine modified oil with excellent water repellence and oil repellence as base oil, and which swells up relative to these oils, to a homogeneous paste-like composition using this silicone polymer, and to a cosmetic material comprising this composition. This invention is a silicone polymer having a three-dimensional crosslinked structure obtained by polymerizing at least one of an organohydrogen polysiloxane (A1) represented by the general formula (A1): R1aR2bHcSiO(4-a-b-c-)/2nullnull(A1) at least one of a polyoxyalkylene (B1) represented by the following general formula (B1): CfH2f-1O(CgH2gO)hCfH2f-1nullnull(B1) and an organopolyoxyalkylene (B4) represented by the following general formula (B4): R1jR5kSiO(4-j-k)/2nullnull(B4) this polymer being insoluble in organic solvents, and which can contain its own weight or more of pentane-3,3,3-trifluoropropyl pentamethylcyclopentasiloxane. This invention is also a paste-like silicone composition, which is represented by the general formula (C): R1mSiO(4-m)/2nullnull(C) and which is obtained by kneading a mixture of 100 weight parts of the above silicone polymer with 10-1000 weight parts of a fluorine-modified silicone oil having a viscosity at 25 degree C. of 200 mm2/s.

摘要翻译： 本发明涉及一种硅氧烷聚合物，因为它具有相对于氟硅油膨胀的三维交联结构，不溶于有机溶剂，而是通过使硅氧烷化合物在硅油中膨胀而形成的糊状组合物，以及 化妆品。 因此，本发明的目的是提供一种具有优异的防水性和拒油性的氟改性油作为基础油并且相对于这些油膨胀的硅氧烷聚合物，使用该硅氧烷聚合物的均匀的糊状组合物， 以及包含该组合物的化妆品。 本发明是通过使通式（A1）表示的有机氢聚硅氧烷（A1）中的至少一种：R a a a b b c c Si（4-abc-））至少一种而获得的三维交联结构的硅氧烷聚合物， / A1（A1）由以下通式（B1）表示的聚氧化烯（B1）中的至少一种：CfH2f-10（CgH2gO）hCfH2f-1（B1）和由以下通式表示的有机聚氧亚烷基（B4） ）：R 1 jR 5 kSiO（4-jk）/ 2（B4）该聚合物不溶于有机溶剂，并且其可以含有其自身重量或更多的戊烷-3,3,3-三氟丙基五甲基环五硅氧烷。 本发明也是由通式（C）表示的糊状硅氧烷组合物：R 1 mSiO（4-m）/ 2（C），其通过将100重量份的 上述具有10-1000重量份在25℃下的粘度为200mm 2 / s的氟改性硅油的硅氧烷聚合物。