公开(公告)号：US06320014B1

公开(公告)日：2001-11-20

申请号：US09256088

申请日：1999-02-24

申请人： Koji Takahashi ,  Koji Nakamachi ,  Hiroji Niimi ,  Shoji Hiraoka ,  Masayuki Sakai ,  Hitoshi Tsuboi

发明人： Koji Takahashi ,  Koji Nakamachi ,  Hiroji Niimi ,  Shoji Hiraoka ,  Masayuki Sakai ,  Hitoshi Tsuboi

IPC分类号： C08G6318

CPC分类号： C08G63/80 ,  C08G63/672

摘要： Disclosed are polyester pellets made of a polyester which comprises dicarboxylic acid constituent units derived from dicarboxylic acids containing terephthalic acid and isophthalic acid and diol constituent units derived from diols containing ethylene glycol and 1,3-bis(2-hydroxyethoxy)benzene, and which has the properties: constituent units derived from terephthalic acid are 15 to 99.5% by mol and constituent units derived from isophthalic acid are 0.5 to 85% by mol, both based on the total amount of dicarboxylic acid isophthalic acid constituent units (i); constituent units derived from ethylene glycol are 25 to 99.5% by mol and constituent units derived from 1,3-bis(2-hydroxyethoxy)benzene are 0.5 to 75% by mol, both based on the total amount of the diol constituent units (ii); the intrinsic viscosity is in the range of 0.5 to 1.5 dl/g; and the melting point (Tm (°C.)), as measured by a differential scanning calorimeter, satisfies the formula [1/527−0.0017·ln(1−(mI+mB)/200)]−1−273

摘要翻译： 公开了由聚酯制成的聚酯粒料，其包含衍生自含有对苯二甲酸和间苯二甲酸的二羧酸的二羧酸结构单元和源自含有乙二醇和1,3-双（2-羟基乙氧基）苯的二醇的二醇结构单元， 性质：由对苯二甲酸衍生的结构单元为15〜99.5摩尔％，来自间苯二甲酸的构成单元为二烷基间苯二甲酸成分单元（i）的总量为0.5〜85摩尔％。 衍生自乙二醇的构成单元为25〜99.5摩尔％，来自1,3-双（2-羟基乙氧基）苯的构成单元为0.5〜75摩尔％，均基于二醇构成单元（ii ）; 特性粘度在0.5〜1.5dl / g的范围内; 通过差示扫描量热计测定的熔点（Tm（℃））满足公式[1 / 527-0.0017.ln（1-（mI + mB）/ 200）]〜1-273

公开(公告)号：US06344534B2

公开(公告)日：2002-02-05

申请号：US09794341

申请日：2001-02-28

申请人： Shougang He ,  Tadashi Teranishi

发明人： Shougang He ,  Tadashi Teranishi

IPC分类号： C08G6318

CPC分类号： C08G63/199

摘要： A polyester polymer is a condensation product of a diol component and a dicarboxylic acid component, and the diol component (i) includes at least one tricyclo[5.2.1.02,6]decanedimethanol represented by the following formula (1): wherein two hydroxymethyl groups are bound to carbon atoms constituting tricyclo[5.2.1.02,6]decane ring and wherein each of carbon atoms constituting the ring may have at least one additional substituent; or (ii) the dicarboxylic acid component includes at least one tricyclo[5.2.1.02,6]decanedicarboxylic acid represented by the following formula (2): wherein two carboxyl groups are bound to carbon atoms constituting tricyclo[5.2.1.02,6]decane ring and wherein each of carbon atoms constituting the ring may have at least one additional substituent. The polyester polymer has an excellent formability in addition to a high heat resistance, low water absorption property, and satisfactory optical characteristics.

摘要翻译： 聚酯聚合物是二醇组分和二羧酸组分的缩合产物，二醇组分（i）包括至少一种由下式（1）表示的三环[5.2.1.0 2,6]癸烷二甲醇：其中两个羟甲基 与构成三环[5.2.1.02,6]癸烷环的碳原子结合，并且其中构成环的每个碳原子可以具有至少一个另外的取代基; 或（ii）二羧酸成分包括由下式（2）表示的至少一种三环[5.2.1.0 2,6]癸烷二羧酸：其中两个羧基与构成三环[5.2.1.02,6]癸烷的碳原子结合 并且其中构成环的每个碳原子可以具有至少一个另外的取代基。 除了高耐热性，低吸水性和令人满意的光学特性之外，聚酯聚合物具有优异的成型性。

公开(公告)号：US06297348B1

公开(公告)日：2001-10-02

申请号：US09644454

申请日：2000-08-22

申请人： John Bernard Rodden ,  Glenn William Elliott

发明人： John Bernard Rodden ,  Glenn William Elliott

IPC分类号： C08G6318

CPC分类号： C08G63/189 ,  B01J23/002 ,  B01J23/44 ,  B01J23/80 ,  B01J27/232 ,  B01J37/088 ,  C07C51/02 ,  C07C51/15 ,  C07C51/265 ,  C07C51/412 ,  C07C51/416 ,  C07C51/42 ,  C07C51/43 ,  C07C51/47 ,  C07C51/487 ,  C07C63/15 ,  C07C63/24 ,  C07C63/16 ,  C07C63/26 ,  C07C63/38 ,  C07C63/36 ,  C07C63/307 ,  C07C63/04

摘要： Disclosed is a method for closely linking a process for producing 2,6-naphthalene dicarboxylic acid (2,6-NDA) with a process for producing polyethylene naphthalate, thus eliminating the need for drying 2,6-NDA, handling solid 2,6-NDA, and optimizing particle size of 2,6-NDA which comprises: a) Adding an aqueous slurry of polymer grade 2,6-NDA directly into a process for making PEN, either by directly adding a stream from a 2,6 NDA process into a PEN process, or by adding water to polymer grade 2-6-NDA prior to adding the resulting slurry to a PEN process. b) Removing the slurry water during the first esterification reaction at the same time the water of reaction is removed.

摘要翻译： 公开了一种将2,6-萘二甲酸（2,6-NDA）的制造方法与生产聚萘二甲酸乙二醇酯的方法紧密连接的方法，因此不需要干燥2,6-NDA，处理固体2,6 --NDA，并优化2,6-NDA的粒径，其包括：a）将聚合物级2,6-NDA的水性浆料直接添加到制备PEN的方法中，通过直接添加来自2,6NDA的流 加工成PEN方法，或者在将所得浆料加入PEN工艺之前，向聚合物级2-6-NDA中加入水。b）在第一次酯化反应期间，同时除去反应水中的浆料水 。