公开(公告)号：US06822055B1

公开(公告)日：2004-11-23

申请号：US10031217

申请日：2002-04-18

申请人： Bernd Fischer ,  Heiko Hamann ,  Hans-Jörg Mauk ,  Miko Ess ,  Bernd Kastl

发明人： Bernd Fischer ,  Heiko Hamann ,  Hans-Jörg Mauk ,  Miko Ess ,  Bernd Kastl

IPC分类号： C08J518

CPC分类号： C08G59/027 ,  B29C43/30 ,  B29K2063/00 ,  Y10T428/31511

摘要： The present invention relates to a method for producing a flat article comprising a material that contains the products of several reactions. The method comprises the following steps: carrying out a pre-cross-linking of a mixture comprising an epoxydation product of a carboxylic acid ester using at least one cross-linking agent in order to form a moldable material; molding the moldable material in the shape of a flat article; and curing the molded material in order to produce a flat article, wherein the pre-cross-linking reaction is separate from the curing reaction. This invention also relates to a moldable material that can be stored and to a flat article that can be obtained from the same.

摘要翻译： 本发明涉及包含含有几种反应产物的材料的扁平制品的制造方法。 该方法包括以下步骤：使用至少一种交联剂进行包含羧酸酯的环氧化产物的混合物的预交联以形成可模制材料; 将可模制材料模制成扁平制品的形状; 并固化成型材料以制备平坦制品，其中预交联反应与固化反应分离。 本发明还涉及一种可以被储存的可模制材料以及可以从其获得的扁平制品。

公开(公告)号：US06417289B1

公开(公告)日：2002-07-09

申请号：US08934192

申请日：1997-09-19

申请人： Pradeep P. Shirodkar

发明人： Pradeep P. Shirodkar

IPC分类号： C08J518

CPC分类号： C08J5/18 ,  C08J2323/08 ,  Y10S264/42 ,  Y10T428/263 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/269 ,  Y10T428/31855

摘要： LLDPE films with superior impact strength are obtained by blowing lightly crosslinked LLDPE resins under film extrusion conditions typically used for blowing HDPE film.

摘要翻译： 通过在通常用于吹塑HDPE薄膜的薄膜挤出条件下吹入轻度交联的LLDPE树脂获得具有优异冲击强度的LLDPE薄膜。

公开(公告)号：US06368534B1

公开(公告)日：2002-04-09

申请号：US09612245

申请日：2000-07-07

申请人： Toshikazu Nakamura ,  Yukihiro Katai

发明人： Toshikazu Nakamura ,  Yukihiro Katai

IPC分类号： C08J518

CPC分类号： C08J5/18 ,  B29C41/28 ,  B29D7/01 ,  B29K2001/00 ,  C08J2301/12

摘要： This invention relates to a solution casting process capable of decreasing uneven coating of a functional layer upon applying the functional layer onto a film surface, which comprises casting a solution of polymer dissolved in organic solvent into a film by extruding from a die onto a support, wherein the length of the film from the die opening to the landing of the film on the support is controlled to 3 to 40 mm.

摘要翻译： 本发明涉及一种在将功能层施加到膜表面上时能够减少功能层不均匀涂覆的溶液流延法，其包括将溶解在有机溶剂中的聚合物溶液通过从模具挤出到载体上而成膜， 其中将膜从模具开口到支撑体上的膜的着陆的长度被控制为3至40mm。

公开(公告)号：US06620903B2

公开(公告)日：2003-09-16

申请号：US10308899

申请日：2002-12-03

申请人： Uy William Cheng

发明人： Uy William Cheng

IPC分类号： C08J518

CPC分类号： D01F6/48 ,  C08L27/18 ,  C08L2205/02 ,  D01F6/32 ,  C08L2666/04

摘要： This invention relates to fluoropolymer fibers and films which can be modified by cationic agents, such as cationic dyes. The fiber or film comprises a blend of a first and a second copolymer, or it comprises a terpolymer, the blend or terpolymer having (1) an acid or ionic functionality provided by a pendant group represented by the formula —(O—CF2CFR)aO—CF2CFR′SO3−Z+, wherein R and R′ are independently selected from F, Cl or a perfluorinated alkyl group having 1 to 10 carbon atoms, a=0, 1 or 2, and Z+ is H+, an alkali metal cation, or a cation derived from a compound selected from the group consisting of a cationic dye, a cationic whitener, a cationic flame retardant, a cationic antistatic agent, and mixtures thereof, and (2) a larger amount of a fluoroalkylvinylether, a fluoroalkene, or ethylene functionality. Such fibers and films are useful in various consumer goods where the product is desirably colored, whitened, antistatic, or flame retardant.

公开(公告)号：US06309739B1

公开(公告)日：2001-10-30

申请号：US09135022

申请日：1998-08-17

申请人： Keishi Koizumi ,  Shigemi Matsumoto ,  Takao Okimi ,  Juuichi Nishimura

发明人： Keishi Koizumi ,  Shigemi Matsumoto ,  Takao Okimi ,  Juuichi Nishimura

IPC分类号： C08J518

CPC分类号： C08J5/18 ,  C08J2333/10 ,  C08L33/10 ,  C08L51/003 ,  Y10T428/254 ,  Y10T428/31931 ,  C08L2666/24

摘要： A methacrylate, resin composition having an excellent processability and capable of providing films having excellent impact resistance, transparency, weatherability, solvent resistance and plasticizer migration resistance, which comprises (A) 5 to 50% by weight of a crosslinked acrylate elastomer having a two layer structure of a crosslinked polymer component (a-1) having a glass transition temperature of −30 to 10° C. and a crosslinked polymer component (a-2) having a glass transition temperature of less than −30° C. wherein the component (a-1) is located on the inner side or the outer side and the component (a-2) is located on the outer side or the inner side, and (B) 95 to 50% by weight of an alkyl methacrylate polymer prepared by polymerizing an acrylic monomer containing 80 to 100% by weight of an alkyl methacrylate and 20 to 0% by weight of an alkyl acrylate in the presence of a chain transfer agent and in the presence or absence of the elastomer (A). The composition may further contain a core-shell polymer prepared by graft-polymerizing a monomer containing a major amount of an alkyl methacrylate onto a crosslinked acrylate polymer, whereby molded articles having a matt surface and an excellent flex whitening resistance are obtained.

摘要翻译： 具有优异的加工性的甲基丙烯酸酯树脂组合物，其能够提供耐冲击性，透明性，耐候性，耐溶剂性和耐增塑剂迁移性优异的膜，其包含（A）5〜50重量％的具有两层的交联丙烯酸酯弹性体 玻璃化转变温度为-30〜10℃的交联聚合物组分（a-1）的结构和玻璃化转变温度低于-30℃的交联聚合物组分（a-2）。其中组分 （a-1）位于内侧或外侧，成分（a-2）位于外侧或内侧，（B）95〜50重量％的制备的甲基丙烯酸烷基酯聚合物 通过在链转移剂的存在下和在弹性体（A）的存在或不存在下聚合含有80至100重量％的甲基丙烯酸烷基酯和20至0重量％的丙烯酸烷基酯的丙烯酸类单体。 组合物还可以含有通过将含有主要量的甲基丙烯酸烷基酯的单体接枝聚合到丙交酯交联聚合物上制备的核 - 壳聚合物，由此获得具有无光泽表面和优异的抗弯白美白性的模塑制品。

公开(公告)号：US06815503B2

公开(公告)日：2004-11-09

申请号：US10104303

申请日：2002-03-20

申请人： Shinji Nakata ,  Yasuhiro Shiraishi ,  Takanori Nakashima ,  Shinichi Akitaya

发明人： Shinji Nakata ,  Yasuhiro Shiraishi ,  Takanori Nakashima ,  Shinichi Akitaya

IPC分类号： C08J518

CPC分类号： C08L23/10 ,  C08L23/16 ,  C08L2666/04

摘要： Provided are a novel polypropylene resin composition, a gas permeable film comprising the same and provided with satisfactory optical characteristics (transparency, gloss and see throughness) as well as an excellent gas permeability (water vapor, oxygen and ethylene gas) without damaging a rigidity and a vegetable and fruit freshness long term-maintaining method using the above gas permeable film for a wrapping film. The polypropylene resin composition described above comprises 40 to 95% by weight of a propylene polymer (A) and 5 to 60% by weight of an ethylene/propylene/butene random copolymer (B) having a butene content of 3 to 40% by weight and an ethylene content of 10 to 30% by weight, wherein a ratio (&eegr;B/&eegr;A) of an intrinsic viscosity &eegr;B of the component (B) described above to an intrinsic viscosity &eegr;A of the component (A) described above falls in a range of 0.5 to 1.3; and the &eegr;B described above falls in a range of 0.5 to 3.0 dl/g. The gas permeable film described above is a single layer or multilayer film comprising at least one layer of a film of the polypropylene resin composition described above and having a thickness of 10 to 100 &mgr;m, and it has the following characteristics: (1) a permeability TH2O of water vapor is 9 to 50 g/m2·24 h (based on JIS Z 0208), (2) a permeability TO2 of oxygen is 600 to 12500 nmol/m2·s·100 kPa (based on JIS K 7126-A) and (3) a permeability Tethylene of ethylene gas is 600 to 22500 nmol/m2·s·100 kPa (based on JIS K 7126-A).

公开(公告)号：US06590037B1

公开(公告)日：2003-07-08

申请号：US08440366

申请日：1995-05-12

申请人： Michael Friedman ,  Louis Laucirica

发明人： Michael Friedman ,  Louis Laucirica

IPC分类号： C08J518

CPC分类号： C08J5/18 ,  B32B17/10688 ,  B32B17/10743 ,  B32B27/30 ,  C08J2333/08 ,  C08L23/0869 ,  C08L2205/02 ,  Y10T428/31645 ,  Y10T428/31649 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31935 ,  C08L2666/06

摘要： The present invention is a film formed from an acrylate blend. The preferred blend is a film comprising components (a) and (b), component (a) being an ethylene butyl acrylate copolymer (EBAC) which is less than about 95 percent percent by weight of a total weight of components (a) and (b), wherein the EBAC has a content of acrylate groups from about 8 to about 36 percent by weight of the total weight of the EBAC; and component (b) being an ethylene methyl acrylate copolymer (EMAC) which is greater than about 5 percent by weight of the total weight of components (a) and (b), wherein the EMAC has a content of acrylate groups from about 8 to about 42 percent by weight of the total weight of the EMAC. The invention further includes a process for manufacturing this film for use as an interlayer in laminates comprising the steps of mixing the melt of thermoplastic polymer resins to form an ethylene butyl acrylate/ethylene methyl acrylate blend and forming the ethylene butyl acrylate/ethylene methyl acrylate blend of thermoplastic resins into a film for use as an interlayer in laminates. The invention still further includes a laminate comprising at least two sheets and at least one interlayer, the interlayer(s) being in between the sheets and wherein the interlayer is comprised of the film described above. The invention still further includes a laminate comprising an acrylate film laminated between two lamina wherein the film and the laminate have properties similar to PVB and laminates made with PVB, respectively.

摘要翻译： 本发明是由丙烯酸酯共混物形成的膜。 优选的共混物是包含组分（a）和（b）的组合物，组分（a）是乙烯丙烯酸丁酯共聚物（EBAC），其小于组分（a）和（a）的总重量的约95重量％ b），其中EBAC的丙烯酸酯基含量为EBAC总重量的约8至约36重量％; 和组分（b）是乙烯丙烯酸甲酯共​​聚物（EMAC），其大于组分（a）和（b）的总重量的约5重量％，其中所述EMAC的丙烯酸酯基含量为约8至 约占该EMAC总重量的42％（重量）。本发明还包括一种用于制造该薄膜的方法，该薄膜用作层压材料的中间层，包括以下步骤：将热塑性聚合物树脂的熔体混合，形成乙烯丙烯酸丁酯/乙烯甲基 丙烯酸酯共混物，并将热塑性树脂的乙烯丙烯酸丁酯/乙烯丙烯酸甲酯共​​混物形成用作层压材料中间层的膜。 本发明还包括包含至少两个片材和至少一个中间层的层压体，所述中间层在所述片材之间，并且其中所述中间层由上述膜构成。 本发明还包括层压在两层之间的层压板，其中膜和层压板分别具有与PVB相似的性能和用PVB制成的层压板。