公开(公告)号：US06723770B2

公开(公告)日：2004-04-20

申请号：US10346340

申请日：2003-01-16

申请人： Keiichi Kuramoto ,  Hiroaki Izu ,  Koji Yamano ,  Hitoshi Hirano

发明人： Keiichi Kuramoto ,  Hiroaki Izu ,  Koji Yamano ,  Hitoshi Hirano

IPC分类号： C08J532

CPC分类号： C08G83/001 ,  C08K5/05 ,  C09D169/00 ,  Y10T428/24917 ,  Y10T428/265 ,  C08L2666/54

摘要： A method of producing an organic-inorganic composite material formed from an organic polymer and a metal alkoxide, comprising the steps of polycondensating the metal alkoxide through hydrolysis until the unreacted metal alkoxide is reduced to 3 vol. % or less, and mixing it with the organic polymer to form the organic-inorganic composite material. By laminating such organic-inorganic composite materials, the resulting laminate is provided with a concentration gradation wherein the metal element of the metal alkoxide is increased or decreased from one side to the other side of the laminate.

摘要翻译： 一种生产由有机聚合物和金属醇盐形成的有机 - 无机复合材料的方法，包括以下步骤：通过水解将金属醇盐缩聚直到未反应的金属醇盐降至3体积％。 ％以下，并与有机聚合物混合形成有机 - 无机复合材料。 通过层压这种有机 - 无机复合材料，所得到的层压体具有浓度梯度，其中金属醇盐的金属元素从层压体的一侧增加或减小。

公开(公告)号：US06346563B1

公开(公告)日：2002-02-12

申请号：US09348375

申请日：1999-07-07

申请人： Shulong Li ,  Dany Felix Maria Michiels

发明人： Shulong Li ,  Dany Felix Maria Michiels

IPC分类号： C08J532

CPC分类号： C08J5/06 ,  C08J2321/00 ,  C08K5/544 ,  C08K5/548 ,  Y10T428/31663 ,  Y10T428/31667 ,  Y10T442/164 ,  Y10T442/223 ,  Y10T442/2738 ,  Y10T442/2803 ,  Y10T442/2861 ,  Y10T442/2893 ,  Y10T442/2902 ,  Y10T442/2918 ,  Y10T442/2926 ,  Y10T442/2934 ,  Y10T442/2959 ,  Y10T442/2984 ,  Y10T442/2992 ,  Y10T442/3911 ,  Y10T442/60 ,  Y10T442/679 ,  C08L21/00

摘要： A composition for the promotion of adhesion between a rubber formulation and a textile substrate is provided. The inventive composition comprises either a mixture of specific amine functional silanes and organo-functional silanes having reactive groups or groups with an affinity for rubber. The inventive method entails the use of the inventive composition or a silane compound having both an amine moiety and a reactive group having an affinity for rubber formulations, particularly an unsaturated carbon-carbon bond. The composition may be utilized to adhere any standard reinforcement-type textile, such as polyester or polyamide, to a standard rubber composition, such as SBR, NBR, or EPDM. A method for adhering textiles to rubber formulations is also provided involving a pre-dip, -spray, -coat, and the like, of the inventive composition on a reinforcement-type textile surface followed by the contacting of the rubber formulation. Optionally, and preferably, the process involves the extra utilization of resorcinol-formaldehyde latex as an effective bonding agent to improve the adhesion between the two layers. The resulting textile-reinforced rubber product may be utilized as an automobile fan or timing belt, an automobile tire component, and any other rubber article which requires long-lasting, durable textile reinforcement.

摘要翻译： 提供了用于促进橡胶配方和织物基材之间的粘合的组合物。 本发明的组合物包含特定胺官能硅烷和具有对橡胶具有亲和力的反应性基团的有机官能硅烷的混合物。 本发明的方法需要使用本发明的组合物或具有胺部分和对橡胶配方，特别是不饱和碳 - 碳键具有亲和性的反应性基团的硅烷化合物。 组合物可用于将任何标准增强型织物如聚酯或聚酰胺粘合到标准橡胶组合物如SBR，NBR或EPDM上。 还提供了一种将纺织品粘附到橡胶配方上的方法，其涉及本发明组合物的预浸，喷涂，涂层等，在增强型织物表面上，随后橡胶制剂的接触。 任选地，优选地，该方法包括额外利用间苯二酚 - 甲醛胶乳作为有效粘合剂以改善两层之间的粘附性。 所得到的纺织增强橡胶制品可以用作汽车风扇或同步带，汽车轮胎部件以及需要持久耐久的纺织品加强的任何其它橡胶制品。

公开(公告)号：US06686301B2

公开(公告)日：2004-02-03

申请号：US10080050

申请日：2002-02-21

申请人： Shulong Li ,  Dany Felix Maria Michiels

发明人： Shulong Li ,  Dany Felix Maria Michiels

IPC分类号： C08J532

CPC分类号： C08J5/06 ,  C08J2321/00 ,  C08K5/544 ,  C08K5/548 ,  Y10T428/31663 ,  Y10T428/31667 ,  Y10T442/164 ,  Y10T442/223 ,  Y10T442/2738 ,  Y10T442/2803 ,  Y10T442/2861 ,  Y10T442/2893 ,  Y10T442/2902 ,  Y10T442/2918 ,  Y10T442/2926 ,  Y10T442/2934 ,  Y10T442/2959 ,  Y10T442/2984 ,  Y10T442/2992 ,  Y10T442/3911 ,  Y10T442/60 ,  Y10T442/679 ,  C08L21/00

摘要： A composition for the promotion of adhesion between a rubber formulation and a textile substrate is provided. The inventive composition comprises either a mixture of specific amine functional silanes and organo-functional silanes having reactive groups or groups with an affinity for rubber. The inventive method entails the use of the inventive composition or a silane compound having both an amine moiety and a reactive group having an affinity for rubber formulations, particularly an unsaturated carbon-carbon bond. The composition may be utilized to adhere any standard reinforcement-type textile, such as polyester or polyamide, to a standard rubber composition, such as SBR, NBR, or EPDM. A method for adhering textiles to rubber formulations is also provided involving a pre-dip, -spray, -coat, and the like, of the inventive composition on a reinforcement-type textile surface followed by the contacting of the rubber formulation. Optionally, and preferably, the process involves the extra utilization of resorcinol-formaldehyde latex as an effective bonding agent to improve the adhesion between the two layers. The resulting textile-reinforced rubber product may be utilized as an automobile fan or timing belt, an automobile tire component, and any other rubber article which requires long-lasting, durable textile reinforcement.

摘要翻译： 提供了用于促进橡胶配方和织物基材之间的粘合的组合物。 本发明的组合物包含特定胺官能硅烷和具有对橡胶具有亲和力的反应性基团的有机官能硅烷的混合物。 本发明的方法需要使用本发明的组合物或具有胺部分和对橡胶配方，特别是不饱和碳 - 碳键具有亲和性的反应性基团的硅烷化合物。 组合物可用于将任何标准增强型织物如聚酯或聚酰胺粘合到标准橡胶组合物如SBR，NBR或EPDM上。 还提供了一种将纺织品粘附到橡胶配方上的方法，其涉及本发明组合物的预浸，喷涂，涂层等，在增强型织物表面上，随后橡胶制剂的接触。 任选地，优选地，该方法包括额外利用间苯二酚 - 甲醛胶乳作为有效粘合剂以改善两层之间的粘附性。 所得到的纺织增强橡胶制品可以用作汽车风扇或同步带，汽车轮胎部件以及需要持久耐久的纺织品加强的任何其它橡胶制品。

公开(公告)号：US06333281B1

公开(公告)日：2001-12-25

申请号：US09457182

申请日：1999-12-08

申请人： Shulong Li ,  Dany Felix Maria Michiels

发明人： Shulong Li ,  Dany Felix Maria Michiels

IPC分类号： C08J532

CPC分类号： C08J5/06 ,  C08J2321/00 ,  C08K5/544 ,  C08K5/548 ,  Y10T428/31663 ,  Y10T428/31667 ,  Y10T442/164 ,  Y10T442/223 ,  Y10T442/2738 ,  Y10T442/2803 ,  Y10T442/2861 ,  Y10T442/2893 ,  Y10T442/2902 ,  Y10T442/2918 ,  Y10T442/2926 ,  Y10T442/2934 ,  Y10T442/2959 ,  Y10T442/2984 ,  Y10T442/2992 ,  Y10T442/3911 ,  Y10T442/60 ,  Y10T442/679 ,  C08L21/00

摘要： A composition for the promotion of adhesion between a rubber formulation and a textile substrate is provided. The inventive composition comprises either a mixture of specific amine functional silanes and organo-functional silanes having reactive groups or groups with an affinity for rubber. The inventive method entails the use of the inventive composition or a silane compound having both an amine moiety and a reactive group having an affinity for rubber formulations, particularly an unsaturated carbon-carbon bond. The composition may be utilized to adhere any standard reinforcement-type textile, such as polyester or polyamide, to a standard rubber composition, such as SBR, NBR, or EPDM. A method for adhering textiles to rubber formulations is also provided involving a pre-dip, -spray, -coat, and the like, of the inventive composition on a reinforcement-type textile surface followed by the contacting of the rubber formulation. Optionally, and preferably, the process involves the extra utilization of resorcinol-formaldehyde latex as an effective bonding agent to improve the adhesion between the two layers. The resulting textile-reinforced rubber product may be utilized as an automobile fan or timing belt, an automobile tire component, and any other rubber article which requires long-lasting, durable textile reinforcement.

摘要翻译： 提供了用于促进橡胶配方和织物基材之间的粘合的组合物。 本发明的组合物包含特定胺官能硅烷和具有对橡胶具有亲和力的反应性基团的有机官能硅烷的混合物。 本发明的方法需要使用本发明的组合物或具有胺部分和对橡胶配方，特别是不饱和碳 - 碳键具有亲和性的反应性基团的硅烷化合物。 组合物可用于将任何标准增强型织物如聚酯或聚酰胺粘合到标准橡胶组合物如SBR，NBR或EPDM上。 还提供了一种将纺织品粘附到橡胶配方上的方法，其涉及本发明组合物的预浸，喷涂，涂层等，在增强型织物表面上，随后橡胶制剂的接触。 任选地，优选地，该方法包括额外利用间苯二酚 - 甲醛胶乳作为有效粘合剂以改善两层之间的粘附性。 所得到的纺织增强橡胶制品可以用作汽车风扇或同步带，汽车轮胎部件以及需要持久耐久的纺织品加强的任何其它橡胶制品。