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    Process to prepare paraffins and waxes
    1.
    发明授权
    Process to prepare paraffins and waxes 有权

    公开(公告)号：US10227533B2

    公开(公告)日：2019-03-12

    申请号：US15756202

    申请日：2016-09-01

    申请人： SHELL OIL COMPANY

    发明人： Gerrit Leendert Bezemer ,  Harold Boerrigter ,  Hai Ming Tan

    IPC分类号： C10G2/00 ,  C10G45/00 ,  C10G65/04 ,  C10G73/44 ,  C10G45/02 ,  B01D3/14

    摘要： Paraffins and waxes are produced from a gaseous feed stream comprising hydrogen and carbon monoxide in a Fischer-Tropsch reactor using a fixed bed of reduced Fischer-Tropsch catalyst having cobalt as catalytically active metal. A nitrogen-containing compound is added to the gaseous feed stream in a concentration of up to 10 ppmV and the mixture if fed to the reactor to obtain paraffins having from 5 to 300 carbon atoms. The product is subjected to a hydrogenation step, to obtain a hydrogenated fraction comprising 5 to 300 carbon atoms. The hydrogenated product is separated into C5-C9, C10-C17, and C18-300 fractions. The C18-C300 fraction is separated to obtain one or more first light waxes having a congealing point in the range of 30 to 75° C. and a second heavy wax having a congealing point in the range of 75 to 120° C.

    PROCESS FOR PREPARING A HYDROWAX
    2.
    发明申请
    PROCESS FOR PREPARING A HYDROWAX 审中-公开
    制备HYDROWAX的方法

    公开(公告)号：US20150322364A1

    公开(公告)日：2015-11-12

    申请号：US14652224

    申请日：2013-12-17

    申请人： SHELL OIL COMPANY

    发明人： John Joseph BARIC ,  Nicolaas VAN DIJK ,  Laurent Georges HUVE

    IPC分类号： C10M101/02 ,  C10G73/44 ,  C10G65/12

    摘要： The invention provides a process for preparing a hydrowax comprising the steps of: (a) providing a hydrocarbonaceous feedstock which contains more than 4% by weight of hydrocarbons boiling in the range of from 550 to 800° C.; (b) hydrotreating the hydrocarbonaceous feedstock with a hydrotreating catalyst in the presence of a hydrogen-containing gas under hydrotreating conditions to obtain a hydrotreated product; (c) hydrocracking at least part of the hydrotreated product as obtained in step (b) with a hydrocracking catalyst in the presence of a hydrogen-containing gas under hydrocracking conditions to obtain a hydrocracked product, which hydrocracking catalyst contains a zeolitic component which is present in an amount of at least 14 wt %, based on the total weight of the hydrocracking catalyst, and wherein the volume ratio of the hydrotreating catalyst as used in step (b) and the hydrocracking catalyst is more than 1; and (d) recovering from the hydrocracked product as obtained in step (c) the hydrowax.

    摘要翻译： 本发明提供了一种制备水合烃的方法，包括以下步骤：（a）提供含有大于4重量％沸点为550-800℃的烃的烃质原料; （b）在加氢处理条件下，在含氢气体存在下，用加氢处理催化剂对含烃原料进行加氢处理，得到加氢处理物; （c）在加氢裂化条件下，在含氢气体存在下，用加氢裂化催化剂加氢裂化步骤（b）中得到的加氢处理产物的至少一部分，得到加氢裂化催化剂，该催化剂含有存在的沸石组分 相对于加氢裂化催化剂的总重量为至少14重量％，其中步骤（b）中使用的加氢处理催化剂与加氢裂化催化剂的体积比大于1; 和（d）从在步骤（c）获得的加氢裂化产物中回收氢氟烃。

    Lubricant base oil having improved oxidative stability
    3.
    发明授权
    Lubricant base oil having improved oxidative stability 有权
    具有改善氧化稳定性的润滑油基础油

    公开(公告)号：US6008164A

    公开(公告)日：1999-12-28

    申请号：US130523

    申请日：1998-08-04

    申请人： Haven Scott Aldrich ,  Robert Jay Wittenbrink

    发明人： Haven Scott Aldrich ,  Robert Jay Wittenbrink

    IPC分类号： C10G2/00 ,  C10G45/58 ,  C10G71/00 ,  C10M105/04 ,  C10N20/00 ,  C10N20/02 ,  C10N20/04 ,  C10N30/02 ,  C10N30/10 ,  C10N70/00 ,  C10M101/02 ,  C07C5/13 ,  C10G73/44

    CPC分类号： C10G2/30 ,  C10M107/02 ,  C10M177/00 ,  C10G2400/10 ,  C10M2205/003 ,  C10N2220/022 ,  C10N2220/028 ,  C10N2230/10 ,  C10N2270/00

    摘要： The instant invention is directed to a method for producing a lubricating base stock having a preselected oxidative stability comprising the steps of: (a) separating, into a plurality of fractions based on molecular shape, a hydroisomerized hydrocarbon wax, (b) collecting the fractions of step (a) which have the preselected oxidative stability for use as a lubricating base stock, wherein the fractions to be collected are determined by measuring the oxidative stability of each of said fractions of said plurality of fractions to determine which fractions have said preselected oxidative stability. The invention is also directed to an improved lubricating base oil and a formulated lubricating composition using said lubricating base oil.

    摘要翻译： 本发明涉及一种用于生产具有预选氧化稳定性的润滑基料的方法，其包括以下步骤：（a）将基于分子形状的多个馏分分离成加氢异构化的烃蜡，（b）收集馏分 具有预选的用作润滑基料的氧化稳定性的步骤（a），其中通过测量所述多个级分的每个所述级分的氧化稳定性来确定要收集的级分，以确定哪些级分具有所述预选的氧化性 稳定性。 本发明还涉及改进的润滑油基础油和使用所述润滑基础油的配制的润滑组合物。

    Reactivation of hydrotreating catalyst by operating at a temperature in excess of normal operating temperature
    4.
    发明授权
    Reactivation of hydrotreating catalyst by operating at a temperature in excess of normal operating temperature 失效
    通过在超过正常工作温度的温度下操作来加氢处理催化剂的再活化

    公开(公告)号：US4048094A

    公开(公告)日：1977-09-13

    申请号：US716716

    申请日：1976-08-23

    申请人： Roland L. Menzl ,  P. Donald Hopkins

    发明人： Roland L. Menzl ,  P. Donald Hopkins

    IPC分类号： B01J23/94 ,  C10G73/44 ,  C10G23/02 ,  C10G43/02

    CPC分类号： C10G73/44 ,  B01J23/94

    摘要： A method for reactivating the catalyst used in the mild hydrotreating of petroleum crude scale wax comprises contacting the catalyst with the feedstream at a temperature in excess of the normal operating temperature for the particular feedstream for a time sufficient to reactivate the catalyst and produce effluent having satisfactory color and stability characteristics. Operation at a temperature in excess of the normal operating temperature may follow conventional air-stream catalyst regeneration.

    摘要翻译： 用于重新催化用于石油原油标准蜡的轻度加氢处理的催化剂的方法包括使催化剂与进料流在特定原料流的超过正常操作温度的温度下接触足够的时间以使催化剂再活化并产生令人满意的流出物 颜色和稳定特性。 在超过正常工作温度的温度下操作可以遵循常规的气流催化剂再生。

    Process for preparing a hydrowax
    10.
    发明授权
    Process for preparing a hydrowax 有权

    公开(公告)号：US10590361B2

    公开(公告)日：2020-03-17

    申请号：US14652224

    申请日：2013-12-17

    申请人： SHELL OIL COMPANY

    发明人： John Joseph Baric ,  Nicolaas Van Dijk ,  Laurent Georges Huve

    IPC分类号： C10G65/12 ,  C10M101/02 ,  C10G73/44 ,  C10G47/16 ,  B01J29/076 ,  B01J23/882 ,  B01J29/16

    摘要： The invention provides a process for preparing a hydrowax comprising the steps of: (a) providing a hydrocarbonaceous feedstock which contains more than 4% by weight of hydrocarbons boiling in the range of from 550 to 800° C.; (b) hydrotreating the hydrocarbonaceous feedstock with a hydrotreating catalyst in the presence of a hydrogen-containing gas under hydrotreating conditions to obtain a hydrotreated product; (c) hydrocracking at least part of the hydrotreated product as obtained in step (b) with a hydrocracking catalyst in the presence of a hydrogen-containing gas under hydrocracking conditions to obtain a hydrocracked product, which hydrocracking catalyst contains a zeolitic component which is present in an amount of at least 14 wt %, based on the total weight of the hydrocracking catalyst, and wherein the volume ratio of the hydrotreating catalyst as used in step (b) and the hydrocracking catalyst is more than 1; and (d) recovering from the hydrocracked product as obtained in step (c) the hydrowax.